Design, synthesis and characterization of the advanced tritium breeder: Li sub(4+x)Si sub(1-x)Al sub(x)O sub(4) ceramics
Li sub(4+x)Si sub(1-x)Al sub(x)O sub(4) solid solutions which were designed as the advanced tritium breeder were obtained by solid state reactions. Samples were systematically characterized by various techniques. XRD, neutron diffraction and Raman results showed that the Aluminum substituted silicon...
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Veröffentlicht in: | Journal of nuclear materials 2015-12, Vol.467 (Part 2), p.911-916 |
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container_issue | Part 2 |
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container_title | Journal of nuclear materials |
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creator | Zhao, Linjie Long, Xinggui Chen, Xiaojun Xiao, Chengjian Gong, Yu Guan, Qiushi Li, Jiamao Xie, Lei Chen, Xiping Peng, Shuming |
description | Li sub(4+x)Si sub(1-x)Al sub(x)O sub(4) solid solutions which were designed as the advanced tritium breeder were obtained by solid state reactions. Samples were systematically characterized by various techniques. XRD, neutron diffraction and Raman results showed that the Aluminum substituted silicon into the Li sub(4)SiO sub(4) lattice and Li super(+) interstitials formed as a result of charge compensation. Rietveld refinements of neutron diffraction showed that the crystalline structure had been expanded as Al-doped. Moreover, the lithium atom density, thermal conductivity and the mechanical property of the Li sub(4+x)Si sub(1-x)Al sub(x)O sub(4) ceramics were improved relative to the Li sub(4)SiO sub(4). |
doi_str_mv | 10.1016/j.jnucmat.2015.10.010 |
format | Article |
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Samples were systematically characterized by various techniques. XRD, neutron diffraction and Raman results showed that the Aluminum substituted silicon into the Li sub(4)SiO sub(4) lattice and Li super(+) interstitials formed as a result of charge compensation. Rietveld refinements of neutron diffraction showed that the crystalline structure had been expanded as Al-doped. Moreover, the lithium atom density, thermal conductivity and the mechanical property of the Li sub(4+x)Si sub(1-x)Al sub(x)O sub(4) ceramics were improved relative to the Li sub(4)SiO sub(4).</description><identifier>ISSN: 0022-3115</identifier><identifier>DOI: 10.1016/j.jnucmat.2015.10.010</identifier><language>eng</language><subject>Aluminum ; Breeder reactors ; Ceramics ; Compensation ; Lithium ; Neutron diffraction ; Thermal conductivity ; Tritium</subject><ispartof>Journal of nuclear materials, 2015-12, Vol.467 (Part 2), p.911-916</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Zhao, Linjie</creatorcontrib><creatorcontrib>Long, Xinggui</creatorcontrib><creatorcontrib>Chen, Xiaojun</creatorcontrib><creatorcontrib>Xiao, Chengjian</creatorcontrib><creatorcontrib>Gong, Yu</creatorcontrib><creatorcontrib>Guan, Qiushi</creatorcontrib><creatorcontrib>Li, Jiamao</creatorcontrib><creatorcontrib>Xie, Lei</creatorcontrib><creatorcontrib>Chen, Xiping</creatorcontrib><creatorcontrib>Peng, Shuming</creatorcontrib><title>Design, synthesis and characterization of the advanced tritium breeder: Li sub(4+x)Si sub(1-x)Al sub(x)O sub(4) ceramics</title><title>Journal of nuclear materials</title><description>Li sub(4+x)Si sub(1-x)Al sub(x)O sub(4) solid solutions which were designed as the advanced tritium breeder were obtained by solid state reactions. Samples were systematically characterized by various techniques. XRD, neutron diffraction and Raman results showed that the Aluminum substituted silicon into the Li sub(4)SiO sub(4) lattice and Li super(+) interstitials formed as a result of charge compensation. Rietveld refinements of neutron diffraction showed that the crystalline structure had been expanded as Al-doped. Moreover, the lithium atom density, thermal conductivity and the mechanical property of the Li sub(4+x)Si sub(1-x)Al sub(x)O sub(4) ceramics were improved relative to the Li sub(4)SiO sub(4).</description><subject>Aluminum</subject><subject>Breeder reactors</subject><subject>Ceramics</subject><subject>Compensation</subject><subject>Lithium</subject><subject>Neutron diffraction</subject><subject>Thermal conductivity</subject><subject>Tritium</subject><issn>0022-3115</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><recordid>eNqNj8tOwzAURLMAifL4BCQvG0HCvY7jxOyq8pQqdUH3lR-31FUeJU5Q4OupKB_Aao5mRiNNFF0jpAgo73bprhlsrfuUA-YHLwWEk2gCwHmSIeZn0XkIOwDIFeSTaHyg4N-bWxa-mn574MB045jd6k7bnjr_rXvfNqzdsEPMtPvUjSXH-s73fqiZ6Ygcdfds4VkYzFTcjPHbETEZ41n1i2O8PKYxs9Tp2ttwGZ1udBXo6k8votXT42r-kiyWz6_z2SLZS6kSieSMo5KAUFktCmVtefgJOQpjBSp0HLKci8yRkxyNwaIsNkZIU_AMbXYRTY-z-679GCj069oHS1WlG2qHsMaS50IWKlP_qEIplRIlZD8nC20N</recordid><startdate>20151201</startdate><enddate>20151201</enddate><creator>Zhao, Linjie</creator><creator>Long, Xinggui</creator><creator>Chen, Xiaojun</creator><creator>Xiao, Chengjian</creator><creator>Gong, Yu</creator><creator>Guan, Qiushi</creator><creator>Li, Jiamao</creator><creator>Xie, Lei</creator><creator>Chen, Xiping</creator><creator>Peng, Shuming</creator><scope>7ST</scope><scope>C1K</scope><scope>SOI</scope><scope>7QF</scope><scope>7QQ</scope><scope>7SR</scope><scope>7TB</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>FR3</scope><scope>H8D</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20151201</creationdate><title>Design, synthesis and characterization of the advanced tritium breeder: Li sub(4+x)Si sub(1-x)Al sub(x)O sub(4) ceramics</title><author>Zhao, Linjie ; Long, Xinggui ; Chen, Xiaojun ; Xiao, Chengjian ; Gong, Yu ; Guan, Qiushi ; Li, Jiamao ; Xie, Lei ; Chen, Xiping ; Peng, Shuming</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-p669-61edbde8e0e19ca479cc80160514bc4191d2035243ded621bb1787fb46b7231c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>Aluminum</topic><topic>Breeder reactors</topic><topic>Ceramics</topic><topic>Compensation</topic><topic>Lithium</topic><topic>Neutron diffraction</topic><topic>Thermal conductivity</topic><topic>Tritium</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhao, Linjie</creatorcontrib><creatorcontrib>Long, Xinggui</creatorcontrib><creatorcontrib>Chen, Xiaojun</creatorcontrib><creatorcontrib>Xiao, Chengjian</creatorcontrib><creatorcontrib>Gong, Yu</creatorcontrib><creatorcontrib>Guan, Qiushi</creatorcontrib><creatorcontrib>Li, Jiamao</creatorcontrib><creatorcontrib>Xie, Lei</creatorcontrib><creatorcontrib>Chen, Xiping</creatorcontrib><creatorcontrib>Peng, Shuming</creatorcontrib><collection>Environment Abstracts</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Environment Abstracts</collection><collection>Aluminium Industry Abstracts</collection><collection>Ceramic Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Engineering Research Database</collection><collection>Aerospace Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Journal of nuclear materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhao, Linjie</au><au>Long, Xinggui</au><au>Chen, Xiaojun</au><au>Xiao, Chengjian</au><au>Gong, Yu</au><au>Guan, Qiushi</au><au>Li, Jiamao</au><au>Xie, Lei</au><au>Chen, Xiping</au><au>Peng, Shuming</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Design, synthesis and characterization of the advanced tritium breeder: Li sub(4+x)Si sub(1-x)Al sub(x)O sub(4) ceramics</atitle><jtitle>Journal of nuclear materials</jtitle><date>2015-12-01</date><risdate>2015</risdate><volume>467</volume><issue>Part 2</issue><spage>911</spage><epage>916</epage><pages>911-916</pages><issn>0022-3115</issn><abstract>Li sub(4+x)Si sub(1-x)Al sub(x)O sub(4) solid solutions which were designed as the advanced tritium breeder were obtained by solid state reactions. Samples were systematically characterized by various techniques. XRD, neutron diffraction and Raman results showed that the Aluminum substituted silicon into the Li sub(4)SiO sub(4) lattice and Li super(+) interstitials formed as a result of charge compensation. Rietveld refinements of neutron diffraction showed that the crystalline structure had been expanded as Al-doped. Moreover, the lithium atom density, thermal conductivity and the mechanical property of the Li sub(4+x)Si sub(1-x)Al sub(x)O sub(4) ceramics were improved relative to the Li sub(4)SiO sub(4).</abstract><doi>10.1016/j.jnucmat.2015.10.010</doi><tpages>6</tpages></addata></record> |
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source | ScienceDirect Journals (5 years ago - present) |
subjects | Aluminum Breeder reactors Ceramics Compensation Lithium Neutron diffraction Thermal conductivity Tritium |
title | Design, synthesis and characterization of the advanced tritium breeder: Li sub(4+x)Si sub(1-x)Al sub(x)O sub(4) ceramics |
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