Spatial variability of throughfall in a stand of Scots pine (Pinus sylvestris L.) with deciduous admixture as influenced by canopy cover and stem distance

•Spatio-temporal variability of throughfall in Scots pine stand was studied.•Spatial variability was larger for each throughfall component than for water amount.•Stability of spatial distribution was high, especially in leafed period.•Distribution of water amount was not influenced by canopy characteristics.•Deposition of throughfall components was related mainly to winter canopy structure. Vegetation cover affects the amount of precipitation, its chemical composition and its spatial distribution, and this may have implications for the distribution of water, nutrients and contaminants in the subsurface soil layer. The aim of this study was a detailed diagnosis of the spatio-temporal variability in the amount of throughfall (TF) and its chemical components in a 72-year-old pine stand with an admixture of oak and birch. The spatio-temporal variability in the amount of TF water and the concentrations and deposition of the TF components were studied. The components that are exchanged in canopy (H+, K, Mg, Mn, DOC, NH4+) were more variable than the components whose TF deposition is the sum of wet and dry (including gas) deposition and which undergo little exchange in the canopy (Na, Cl, NO3−, SO42−). The spatial distribution was temporally stable, especially during the leafed period. This study also investigated the effect of the selected pine stand characteristics on the spatial distribution of throughfall and its chemical components; the characteristics included leaf area index (LAI), the proportion of the canopy covered by deciduous species and pine crowns, and the distance from the nearest tree trunk. The LAI measured during the leafed and leafless periods had the greatest effect on the spatial distribution of TF deposition. No relationship was found between the spatial distribution of the amount of TF water and (i) the LAI; (ii) the canopy cover of broadleaf species or pines; or (iii) the distance from the trunks.