Are the current theories of electron transfer applicable to reactions in ionic liquids? An ESR-study on the TCNE/TCNE super(-)&z.rad; couple

Chemical reactivity is profoundly affected by solvent properties. Room temperature ionic liquids (RTILs) obtain molecular environments that differ vastly from those established using molecular solvents with comparable macroscopic properties. In particular, charges are expected to be completely shiel...

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Veröffentlicht in:	Physical chemistry chemical physics : PCCP 2016-05, Vol.18 (21), p.14442-14448
Hauptverfasser:	Mladenova, B Y, Kattnig, DR, Sudy, B, Choto, P, Grampp, G
Format:	Artikel
Sprache:	eng
Schlagworte:	Activation Activation energy Electron transfer Ion exchange Ionic liquids Mathematical models Rate constants Solvents
Online-Zugang:	Volltext
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