Selective recognition of fluoride salts by vasarenes: a key role of a self-assembled in situ dimeric entity via an exceptionally short [O-H-O] super(-) H-bond

A self-assembled supramolecular dimeric entity via an exceptionally short (2.404 Aa) and strong (22.9 kcal mol super(-1)) [O-H-O] super(-) hydrogen bond is the key to the special reactivity of vasarenes with fluoride salts. Vasarene is a self-assembled, vase-shaped compound, obtained by the reaction...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2016-05, Vol.45 (21), p.8734-8739
Hauptverfasser:	Bengiat, R, Gil, M, Klein, A, Bogoslavsky, B, Cohen, S, Dubnikova, F, Yardeni, G, Zilbermann, I, Almog, J
Format:	Artikel
Sprache:	eng
Schlagworte:	Affinity Cations Fluorides Hydrogen bonds Ninhydrin Phloroglucinol Recognition Releasing
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!