Ag/AgCl ion-selective electrodes in neutral and alkaline environments containing interfering ions
Chloride ingress can lead to serious degradation of various materials and structures. Continuous measurements of local chloride concentrations is thus of uttermost importance for laboratory research, monitoring of structures, and predictions of the residual life span for the most common building mat...
Gespeichert in:
| Veröffentlicht in: | Materials and structures 2016-07, Vol.49 (7), p.2637-2651 |
|---|---|
| Hauptverfasser: | , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 2651 |
|---|---|
| container_issue | 7 |
| container_start_page | 2637 |
| container_title | Materials and structures |
| container_volume | 49 |
| creator | Seguí Femenias, Yurena Angst, Ueli Caruso, Francesco Elsener, Bernhard |
| description | Chloride ingress can lead to serious degradation of various materials and structures. Continuous measurements of local chloride concentrations is thus of uttermost importance for laboratory research, monitoring of structures, and predictions of the residual life span for the most common building materials. This work investigates the applicability of Ag/AgCl ion-selective electrodes for the non-destructive continuous measurement of local chloride concentrations in concrete and stone when exposed to chloride-bearing environments such as seawater. The work studies the stability of Ag/AgCl ion-selective electrodes in neutral and alkaline solutions and the sensitivity to the main interfering ions coming from the environment and from the material itself. The results indicate negligible interference from fluoride, sulfate, and hydroxyl but considerable from bromide and sulfide. In chloride-free alkaline solutions, Ag/AgCl ion-selective electrodes are not stable over time, but—upon chloride arrival—they permit again reliable measurements of the chloride concentration. The results concerning interference are discussed by taking into account typical exposure environments and it is concluded that the ion-selective electrodes can satisfactorily be used to monitor chloride concentrations in built structures made out of concrete or stone. |
| doi_str_mv | 10.1617/s11527-015-0673-8 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1825453080</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>4065084301</sourcerecordid><originalsourceid>FETCH-LOGICAL-c506t-963eed5ed6aa3f5334d1beff85987afef68479965a013c1ecf170d2af1b2e5dd3</originalsourceid><addsrcrecordid>eNp1kEtLAzEUhQdRsFZ_gLsBN25icyfNa1mKLyi40XVIZ25K6jSpybTgvze1LkRwdc_iO4fLV1XXQO9AgJxkAN5IQoETKiQj6qQagZJAhJLstGTGNeFay_PqIuc1pUwDNKPKzlaT2Wre1z4GkrHHdvB7rL9Dih3m2oc64G5Itq9t6Grbv9veh4KEvU8xbDAMuW5jGKwPPqwKP2BymL5zDPmyOnO2z3j1c8fV28P96_yJLF4en-ezBWk5FQPRgiF2HDthLXOcsWkHS3ROca2kdeiEmkqtBbcUWAvYOpC0a6yDZYO869i4uj3ublP82GEezMbnFvveBoy7bEA1fMoZVbSgN3_QddylUL4zIDXlokhrCgVHqk0x54TObJPf2PRpgJqDdHOUbop0c5BuVOk0x07eHgRg-rX8b-kLN2mGFw</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1790566872</pqid></control><display><type>article</type><title>Ag/AgCl ion-selective electrodes in neutral and alkaline environments containing interfering ions</title><source>Springer Nature - Complete Springer Journals</source><creator>Seguí Femenias, Yurena ; Angst, Ueli ; Caruso, Francesco ; Elsener, Bernhard</creator><creatorcontrib>Seguí Femenias, Yurena ; Angst, Ueli ; Caruso, Francesco ; Elsener, Bernhard</creatorcontrib><description>Chloride ingress can lead to serious degradation of various materials and structures. Continuous measurements of local chloride concentrations is thus of uttermost importance for laboratory research, monitoring of structures, and predictions of the residual life span for the most common building materials. This work investigates the applicability of Ag/AgCl ion-selective electrodes for the non-destructive continuous measurement of local chloride concentrations in concrete and stone when exposed to chloride-bearing environments such as seawater. The work studies the stability of Ag/AgCl ion-selective electrodes in neutral and alkaline solutions and the sensitivity to the main interfering ions coming from the environment and from the material itself. The results indicate negligible interference from fluoride, sulfate, and hydroxyl but considerable from bromide and sulfide. In chloride-free alkaline solutions, Ag/AgCl ion-selective electrodes are not stable over time, but—upon chloride arrival—they permit again reliable measurements of the chloride concentration. The results concerning interference are discussed by taking into account typical exposure environments and it is concluded that the ion-selective electrodes can satisfactorily be used to monitor chloride concentrations in built structures made out of concrete or stone.</description><identifier>ISSN: 1359-5997</identifier><identifier>EISSN: 1871-6873</identifier><identifier>DOI: 10.1617/s11527-015-0673-8</identifier><language>eng</language><publisher>Dordrecht: Springer Netherlands</publisher><subject>Building construction ; Building Materials ; Chlorides ; Civil Engineering ; Concretes ; Electrodes ; Engineering ; Exposure ; Interference ; Machines ; Manufacturing ; Materials Science ; Monitors ; Original Artice ; Processes ; Solid Mechanics ; Stone ; Sulfates ; Theoretical and Applied Mechanics</subject><ispartof>Materials and structures, 2016-07, Vol.49 (7), p.2637-2651</ispartof><rights>RILEM 2015</rights><rights>RILEM 2016</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c506t-963eed5ed6aa3f5334d1beff85987afef68479965a013c1ecf170d2af1b2e5dd3</citedby><cites>FETCH-LOGICAL-c506t-963eed5ed6aa3f5334d1beff85987afef68479965a013c1ecf170d2af1b2e5dd3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1617/s11527-015-0673-8$$EPDF$$P50$$Gspringer$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1617/s11527-015-0673-8$$EHTML$$P50$$Gspringer$$Hfree_for_read</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Seguí Femenias, Yurena</creatorcontrib><creatorcontrib>Angst, Ueli</creatorcontrib><creatorcontrib>Caruso, Francesco</creatorcontrib><creatorcontrib>Elsener, Bernhard</creatorcontrib><title>Ag/AgCl ion-selective electrodes in neutral and alkaline environments containing interfering ions</title><title>Materials and structures</title><addtitle>Mater Struct</addtitle><description>Chloride ingress can lead to serious degradation of various materials and structures. Continuous measurements of local chloride concentrations is thus of uttermost importance for laboratory research, monitoring of structures, and predictions of the residual life span for the most common building materials. This work investigates the applicability of Ag/AgCl ion-selective electrodes for the non-destructive continuous measurement of local chloride concentrations in concrete and stone when exposed to chloride-bearing environments such as seawater. The work studies the stability of Ag/AgCl ion-selective electrodes in neutral and alkaline solutions and the sensitivity to the main interfering ions coming from the environment and from the material itself. The results indicate negligible interference from fluoride, sulfate, and hydroxyl but considerable from bromide and sulfide. In chloride-free alkaline solutions, Ag/AgCl ion-selective electrodes are not stable over time, but—upon chloride arrival—they permit again reliable measurements of the chloride concentration. The results concerning interference are discussed by taking into account typical exposure environments and it is concluded that the ion-selective electrodes can satisfactorily be used to monitor chloride concentrations in built structures made out of concrete or stone.</description><subject>Building construction</subject><subject>Building Materials</subject><subject>Chlorides</subject><subject>Civil Engineering</subject><subject>Concretes</subject><subject>Electrodes</subject><subject>Engineering</subject><subject>Exposure</subject><subject>Interference</subject><subject>Machines</subject><subject>Manufacturing</subject><subject>Materials Science</subject><subject>Monitors</subject><subject>Original Artice</subject><subject>Processes</subject><subject>Solid Mechanics</subject><subject>Stone</subject><subject>Sulfates</subject><subject>Theoretical and Applied Mechanics</subject><issn>1359-5997</issn><issn>1871-6873</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><sourceid>C6C</sourceid><sourceid>BENPR</sourceid><recordid>eNp1kEtLAzEUhQdRsFZ_gLsBN25icyfNa1mKLyi40XVIZ25K6jSpybTgvze1LkRwdc_iO4fLV1XXQO9AgJxkAN5IQoETKiQj6qQagZJAhJLstGTGNeFay_PqIuc1pUwDNKPKzlaT2Wre1z4GkrHHdvB7rL9Dih3m2oc64G5Itq9t6Grbv9veh4KEvU8xbDAMuW5jGKwPPqwKP2BymL5zDPmyOnO2z3j1c8fV28P96_yJLF4en-ezBWk5FQPRgiF2HDthLXOcsWkHS3ROca2kdeiEmkqtBbcUWAvYOpC0a6yDZYO869i4uj3ublP82GEezMbnFvveBoy7bEA1fMoZVbSgN3_QddylUL4zIDXlokhrCgVHqk0x54TObJPf2PRpgJqDdHOUbop0c5BuVOk0x07eHgRg-rX8b-kLN2mGFw</recordid><startdate>20160701</startdate><enddate>20160701</enddate><creator>Seguí Femenias, Yurena</creator><creator>Angst, Ueli</creator><creator>Caruso, Francesco</creator><creator>Elsener, Bernhard</creator><general>Springer Netherlands</general><general>Springer Nature B.V</general><scope>C6C</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>FR3</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>KR7</scope><scope>PDBOC</scope><scope>PHGZM</scope><scope>PHGZT</scope><scope>PKEHL</scope><scope>PQEST</scope><scope>PQGLB</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope></search><sort><creationdate>20160701</creationdate><title>Ag/AgCl ion-selective electrodes in neutral and alkaline environments containing interfering ions</title><author>Seguí Femenias, Yurena ; Angst, Ueli ; Caruso, Francesco ; Elsener, Bernhard</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c506t-963eed5ed6aa3f5334d1beff85987afef68479965a013c1ecf170d2af1b2e5dd3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Building construction</topic><topic>Building Materials</topic><topic>Chlorides</topic><topic>Civil Engineering</topic><topic>Concretes</topic><topic>Electrodes</topic><topic>Engineering</topic><topic>Exposure</topic><topic>Interference</topic><topic>Machines</topic><topic>Manufacturing</topic><topic>Materials Science</topic><topic>Monitors</topic><topic>Original Artice</topic><topic>Processes</topic><topic>Solid Mechanics</topic><topic>Stone</topic><topic>Sulfates</topic><topic>Theoretical and Applied Mechanics</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Seguí Femenias, Yurena</creatorcontrib><creatorcontrib>Angst, Ueli</creatorcontrib><creatorcontrib>Caruso, Francesco</creatorcontrib><creatorcontrib>Elsener, Bernhard</creatorcontrib><collection>Springer Nature OA Free Journals</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection (ProQuest)</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>Engineering Research Database</collection><collection>SciTech Premium Collection</collection><collection>Materials Research Database</collection><collection>Materials Science Database</collection><collection>Civil Engineering Abstracts</collection><collection>Materials Science Collection</collection><collection>ProQuest Central (New)</collection><collection>ProQuest One Academic (New)</collection><collection>ProQuest One Academic Middle East (New)</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Applied & Life Sciences</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><jtitle>Materials and structures</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Seguí Femenias, Yurena</au><au>Angst, Ueli</au><au>Caruso, Francesco</au><au>Elsener, Bernhard</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Ag/AgCl ion-selective electrodes in neutral and alkaline environments containing interfering ions</atitle><jtitle>Materials and structures</jtitle><stitle>Mater Struct</stitle><date>2016-07-01</date><risdate>2016</risdate><volume>49</volume><issue>7</issue><spage>2637</spage><epage>2651</epage><pages>2637-2651</pages><issn>1359-5997</issn><eissn>1871-6873</eissn><abstract>Chloride ingress can lead to serious degradation of various materials and structures. Continuous measurements of local chloride concentrations is thus of uttermost importance for laboratory research, monitoring of structures, and predictions of the residual life span for the most common building materials. This work investigates the applicability of Ag/AgCl ion-selective electrodes for the non-destructive continuous measurement of local chloride concentrations in concrete and stone when exposed to chloride-bearing environments such as seawater. The work studies the stability of Ag/AgCl ion-selective electrodes in neutral and alkaline solutions and the sensitivity to the main interfering ions coming from the environment and from the material itself. The results indicate negligible interference from fluoride, sulfate, and hydroxyl but considerable from bromide and sulfide. In chloride-free alkaline solutions, Ag/AgCl ion-selective electrodes are not stable over time, but—upon chloride arrival—they permit again reliable measurements of the chloride concentration. The results concerning interference are discussed by taking into account typical exposure environments and it is concluded that the ion-selective electrodes can satisfactorily be used to monitor chloride concentrations in built structures made out of concrete or stone.</abstract><cop>Dordrecht</cop><pub>Springer Netherlands</pub><doi>10.1617/s11527-015-0673-8</doi><tpages>15</tpages><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1359-5997 |
| ispartof | Materials and structures, 2016-07, Vol.49 (7), p.2637-2651 |
| issn | 1359-5997 1871-6873 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1825453080 |
| source | Springer Nature - Complete Springer Journals |
| subjects | Building construction Building Materials Chlorides Civil Engineering Concretes Electrodes Engineering Exposure Interference Machines Manufacturing Materials Science Monitors Original Artice Processes Solid Mechanics Stone Sulfates Theoretical and Applied Mechanics |
| title | Ag/AgCl ion-selective electrodes in neutral and alkaline environments containing interfering ions |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-21T15%3A44%3A05IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Ag/AgCl%20ion-selective%20electrodes%20in%20neutral%20and%20alkaline%20environments%20containing%20interfering%20ions&rft.jtitle=Materials%20and%20structures&rft.au=Segu%C3%AD%20Femenias,%20Yurena&rft.date=2016-07-01&rft.volume=49&rft.issue=7&rft.spage=2637&rft.epage=2651&rft.pages=2637-2651&rft.issn=1359-5997&rft.eissn=1871-6873&rft_id=info:doi/10.1617/s11527-015-0673-8&rft_dat=%3Cproquest_cross%3E4065084301%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1790566872&rft_id=info:pmid/&rfr_iscdi=true |