Unexpected “reverse” cyclization of 2-mercaptobenzimidazole with chlorotrifluoroethylene and hexafluoropropene

[Display omitted] •The unusual behavior of fluorinated alkenes was observed.•New fluorinated hererocycles - benzimidazo[4,5b]thiazoles-1,3 were isolated.•The structures were supported by X-ray diffraction.•The possible reaction route was proposed. The unusual cyclization mode of 2-mercaptobenzimidaz...

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Veröffentlicht in:	Journal of fluorine chemistry 2016-05, Vol.185, p.168-172
Hauptverfasser:	Petko, Kirill I., Vlasenko, Yurii G., Kachkovskii, Oleksii D.
Format:	Artikel
Sprache:	eng
Schlagworte:	2-Mercaptobenzimidazole Chlorotrifluoroethylene Diffraction Fluorine Hexafluoropropene Single crystal X-ray diffraction analysis Single crystals X-rays
Online-Zugang:	Volltext
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