Nickel Catalysis Enables Oxidative C(sp2)-H/C(sp2)-H Cross-Coupling Reactions between Two Heteroarenes
Nickel can be used to promote oxidative C(sp2)−H/C(sp2)−H cross‐coupling between two heteroarenes. The reaction scope can be extended to aromatic carboxamides as the coupling partner. The reaction exhibits high functional‐group compatibility and broad substrate scope. The silver oxidant can be recyc...
Gespeichert in:
| Veröffentlicht in: | Angewandte Chemie International Edition 2016-09, Vol.55 (40), p.12275-12279 |
|---|---|
| Hauptverfasser: | , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 12279 |
|---|---|
| container_issue | 40 |
| container_start_page | 12275 |
| container_title | Angewandte Chemie International Edition |
| container_volume | 55 |
| creator | Cheng, Yangyang Wu, Yimin Tan, Guangyin You, Jingsong |
| description | Nickel can be used to promote oxidative C(sp2)−H/C(sp2)−H cross‐coupling between two heteroarenes. The reaction scope can be extended to aromatic carboxamides as the coupling partner. The reaction exhibits high functional‐group compatibility and broad substrate scope. The silver oxidant can be recycled to reduce costs and waste, which is very useful for practical applications.
An odd couple: The title reaction with the aid of the 8‐aminoquinoline group gives biheteroaryl structural motifs. The reaction exhibits high functional‐group compatibility and broad substrate scope, and the silver oxidant can be recycled to reduce costs and waste. |
| doi_str_mv | 10.1002/anie.201606529 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1822112919</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>4186578581</sourcerecordid><originalsourceid>FETCH-LOGICAL-c5429-c18d345c61fb0b0ca00bef0b913e95e91d4f5818724b1a6d8edc1e639611a9d73</originalsourceid><addsrcrecordid>eNqFkU1v00AQhi0EoqVw5YhW4lIOTnd2vV_HyoSmUKUSFDiu1usx2taxw65Nmn-Po7QR4gCnmcPzvhrNk2Wvgc6AUnbmuoAzRkFSKZh5kh2DYJBzpfjTaS84z5UWcJS9SOl24rWm8nl2xJQwkklxnDXL4O-wJaUbXLtNIZF556oWE7m-D7Ubwi8k5Wlas3f54uxxIWXsU8rLfly3oftBPqPzQ-i7RCocNogdudn0ZIEDxt5F7DC9zJ41rk346mGeZF8_zG_KRX51fXFZnl_lXhTM5B50zQvhJTQVrah3lFbY0MoARyPQQF00QoNWrKjAyVpj7QElNxLAmVrxk-x037uO_c8R02BXIXlsW9dhPyYLmjEAZsBM6Nu_0Nt-jN10nQVDZUEF1eKflGZUck0Nn6jZnvK7x0Rs7DqGlYtbC9TuPNmdJ3vwNAXePNSO1QrrA_4oZgLMHtiEFrf_qbPny8v5n-X5PhvSgPeHrIt3ViquhP2-vLB6Wb7_8k19sh_5b8boq2g</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1820638093</pqid></control><display><type>article</type><title>Nickel Catalysis Enables Oxidative C(sp2)-H/C(sp2)-H Cross-Coupling Reactions between Two Heteroarenes</title><source>Wiley Online Library Journals Frontfile Complete</source><creator>Cheng, Yangyang ; Wu, Yimin ; Tan, Guangyin ; You, Jingsong</creator><creatorcontrib>Cheng, Yangyang ; Wu, Yimin ; Tan, Guangyin ; You, Jingsong</creatorcontrib><description>Nickel can be used to promote oxidative C(sp2)−H/C(sp2)−H cross‐coupling between two heteroarenes. The reaction scope can be extended to aromatic carboxamides as the coupling partner. The reaction exhibits high functional‐group compatibility and broad substrate scope. The silver oxidant can be recycled to reduce costs and waste, which is very useful for practical applications.
An odd couple: The title reaction with the aid of the 8‐aminoquinoline group gives biheteroaryl structural motifs. The reaction exhibits high functional‐group compatibility and broad substrate scope, and the silver oxidant can be recycled to reduce costs and waste.</description><edition>International ed. in English</edition><identifier>ISSN: 1433-7851</identifier><identifier>EISSN: 1521-3773</identifier><identifier>DOI: 10.1002/anie.201606529</identifier><identifier>PMID: 27596265</identifier><identifier>CODEN: ACIEAY</identifier><language>eng</language><publisher>Germany: Blackwell Publishing Ltd</publisher><subject>Catalysis ; Chemical reactions ; Compatibility ; Cost engineering ; Costs ; Coupling ; Cross coupling ; Functional anatomy ; heteroarenes ; homogeneous catalysis ; Nickel ; oxidative cross-coupling ; Silver ; synthetic methods</subject><ispartof>Angewandte Chemie International Edition, 2016-09, Vol.55 (40), p.12275-12279</ispartof><rights>2016 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.</rights><rights>2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c5429-c18d345c61fb0b0ca00bef0b913e95e91d4f5818724b1a6d8edc1e639611a9d73</citedby><cites>FETCH-LOGICAL-c5429-c18d345c61fb0b0ca00bef0b913e95e91d4f5818724b1a6d8edc1e639611a9d73</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fanie.201606529$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fanie.201606529$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27901,27902,45550,45551</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/27596265$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Cheng, Yangyang</creatorcontrib><creatorcontrib>Wu, Yimin</creatorcontrib><creatorcontrib>Tan, Guangyin</creatorcontrib><creatorcontrib>You, Jingsong</creatorcontrib><title>Nickel Catalysis Enables Oxidative C(sp2)-H/C(sp2)-H Cross-Coupling Reactions between Two Heteroarenes</title><title>Angewandte Chemie International Edition</title><addtitle>Angew. Chem. Int. Ed</addtitle><description>Nickel can be used to promote oxidative C(sp2)−H/C(sp2)−H cross‐coupling between two heteroarenes. The reaction scope can be extended to aromatic carboxamides as the coupling partner. The reaction exhibits high functional‐group compatibility and broad substrate scope. The silver oxidant can be recycled to reduce costs and waste, which is very useful for practical applications.
An odd couple: The title reaction with the aid of the 8‐aminoquinoline group gives biheteroaryl structural motifs. The reaction exhibits high functional‐group compatibility and broad substrate scope, and the silver oxidant can be recycled to reduce costs and waste.</description><subject>Catalysis</subject><subject>Chemical reactions</subject><subject>Compatibility</subject><subject>Cost engineering</subject><subject>Costs</subject><subject>Coupling</subject><subject>Cross coupling</subject><subject>Functional anatomy</subject><subject>heteroarenes</subject><subject>homogeneous catalysis</subject><subject>Nickel</subject><subject>oxidative cross-coupling</subject><subject>Silver</subject><subject>synthetic methods</subject><issn>1433-7851</issn><issn>1521-3773</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNqFkU1v00AQhi0EoqVw5YhW4lIOTnd2vV_HyoSmUKUSFDiu1usx2taxw65Nmn-Po7QR4gCnmcPzvhrNk2Wvgc6AUnbmuoAzRkFSKZh5kh2DYJBzpfjTaS84z5UWcJS9SOl24rWm8nl2xJQwkklxnDXL4O-wJaUbXLtNIZF556oWE7m-D7Ubwi8k5Wlas3f54uxxIWXsU8rLfly3oftBPqPzQ-i7RCocNogdudn0ZIEDxt5F7DC9zJ41rk346mGeZF8_zG_KRX51fXFZnl_lXhTM5B50zQvhJTQVrah3lFbY0MoARyPQQF00QoNWrKjAyVpj7QElNxLAmVrxk-x037uO_c8R02BXIXlsW9dhPyYLmjEAZsBM6Nu_0Nt-jN10nQVDZUEF1eKflGZUck0Nn6jZnvK7x0Rs7DqGlYtbC9TuPNmdJ3vwNAXePNSO1QrrA_4oZgLMHtiEFrf_qbPny8v5n-X5PhvSgPeHrIt3ViquhP2-vLB6Wb7_8k19sh_5b8boq2g</recordid><startdate>20160926</startdate><enddate>20160926</enddate><creator>Cheng, Yangyang</creator><creator>Wu, Yimin</creator><creator>Tan, Guangyin</creator><creator>You, Jingsong</creator><general>Blackwell Publishing Ltd</general><general>Wiley Subscription Services, Inc</general><scope>BSCLL</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7TM</scope><scope>K9.</scope><scope>7X8</scope></search><sort><creationdate>20160926</creationdate><title>Nickel Catalysis Enables Oxidative C(sp2)-H/C(sp2)-H Cross-Coupling Reactions between Two Heteroarenes</title><author>Cheng, Yangyang ; Wu, Yimin ; Tan, Guangyin ; You, Jingsong</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c5429-c18d345c61fb0b0ca00bef0b913e95e91d4f5818724b1a6d8edc1e639611a9d73</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Catalysis</topic><topic>Chemical reactions</topic><topic>Compatibility</topic><topic>Cost engineering</topic><topic>Costs</topic><topic>Coupling</topic><topic>Cross coupling</topic><topic>Functional anatomy</topic><topic>heteroarenes</topic><topic>homogeneous catalysis</topic><topic>Nickel</topic><topic>oxidative cross-coupling</topic><topic>Silver</topic><topic>synthetic methods</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Cheng, Yangyang</creatorcontrib><creatorcontrib>Wu, Yimin</creatorcontrib><creatorcontrib>Tan, Guangyin</creatorcontrib><creatorcontrib>You, Jingsong</creatorcontrib><collection>Istex</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Nucleic Acids Abstracts</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>MEDLINE - Academic</collection><jtitle>Angewandte Chemie International Edition</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Cheng, Yangyang</au><au>Wu, Yimin</au><au>Tan, Guangyin</au><au>You, Jingsong</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Nickel Catalysis Enables Oxidative C(sp2)-H/C(sp2)-H Cross-Coupling Reactions between Two Heteroarenes</atitle><jtitle>Angewandte Chemie International Edition</jtitle><addtitle>Angew. Chem. Int. Ed</addtitle><date>2016-09-26</date><risdate>2016</risdate><volume>55</volume><issue>40</issue><spage>12275</spage><epage>12279</epage><pages>12275-12279</pages><issn>1433-7851</issn><eissn>1521-3773</eissn><coden>ACIEAY</coden><abstract>Nickel can be used to promote oxidative C(sp2)−H/C(sp2)−H cross‐coupling between two heteroarenes. The reaction scope can be extended to aromatic carboxamides as the coupling partner. The reaction exhibits high functional‐group compatibility and broad substrate scope. The silver oxidant can be recycled to reduce costs and waste, which is very useful for practical applications.
An odd couple: The title reaction with the aid of the 8‐aminoquinoline group gives biheteroaryl structural motifs. The reaction exhibits high functional‐group compatibility and broad substrate scope, and the silver oxidant can be recycled to reduce costs and waste.</abstract><cop>Germany</cop><pub>Blackwell Publishing Ltd</pub><pmid>27596265</pmid><doi>10.1002/anie.201606529</doi><tpages>5</tpages><edition>International ed. in English</edition></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1433-7851 |
| ispartof | Angewandte Chemie International Edition, 2016-09, Vol.55 (40), p.12275-12279 |
| issn | 1433-7851 1521-3773 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1822112919 |
| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Catalysis Chemical reactions Compatibility Cost engineering Costs Coupling Cross coupling Functional anatomy heteroarenes homogeneous catalysis Nickel oxidative cross-coupling Silver synthetic methods |
| title | Nickel Catalysis Enables Oxidative C(sp2)-H/C(sp2)-H Cross-Coupling Reactions between Two Heteroarenes |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-13T05%3A18%3A44IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Nickel%20Catalysis%20Enables%20Oxidative%20C(sp2)-H/C(sp2)-H%20Cross-Coupling%20Reactions%20between%20Two%20Heteroarenes&rft.jtitle=Angewandte%20Chemie%20International%20Edition&rft.au=Cheng,%20Yangyang&rft.date=2016-09-26&rft.volume=55&rft.issue=40&rft.spage=12275&rft.epage=12279&rft.pages=12275-12279&rft.issn=1433-7851&rft.eissn=1521-3773&rft.coden=ACIEAY&rft_id=info:doi/10.1002/anie.201606529&rft_dat=%3Cproquest_cross%3E4186578581%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1820638093&rft_id=info:pmid/27596265&rfr_iscdi=true |