A Bispidine Iron(IV)-Oxo Complex in the Entatic State

For a series of FeIV=O complexes with tetra‐ and pentadentate bispidine ligands, the correlation of their redox potentials with reactivity, involving a variety of substrates for alkane hydroxylation (HAT), alkene epoxidation, and phosphine and thioether oxidation (OAT) are reported. The redox potent...

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Veröffentlicht in:	Angewandte Chemie International Edition 2016-09, Vol.55 (37), p.11129-11133
Hauptverfasser:	Comba, Peter, Fukuzumi, Shunichi, Koke, Carsten, Martin, Bodo, Löhr, Anna-Maria, Straub, Johannes
Format:	Artikel
Sprache:	eng
Schlagworte:	coordination chemistry density functional calculations homogeneous catalysis iron bispidine complexes Ligands redox potentials
Online-Zugang:	Volltext
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