Preference of Ruthenium-Based Metathesis Catalysts toward Z- and E‑Alkenes as a Guide for Selective Reactions to Alkene Stereoisomers

As a guide for selective reactions toward either Z- or E-alkene in a metathesis reaction, the relative preference of metathesis Ru catalysts for each stereoisomer was determined by a method using time-dependent fluorescence quenching. We found that Ru-1 prefers the Z-isomer over the E-isomer, wherea...

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Veröffentlicht in:Journal of organic chemistry 2016-09, Vol.81 (17), p.7591-7596
Hauptverfasser: Lee, Jihong, Kim, Kyung Hwan, Lee, Ok Suk, Choi, Tae-Lim, Lee, Hee-Seung, Ihee, Hyotcherl, Sohn, Jeong-Hun
Format: Artikel
Sprache:eng
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