Measurements of stratospheric chlorine monoxide (ClO) from groundbased FTIR observations

Stratospheric chlorine monoxide was measured at a site near sea level at Aberdeen, UK, using ground-based Fourier-transform infrared (FTIR) spectroscopy. Measurements were made based on the identification of 13 ClO adsorption lines. The instrumentation is described. The ClO column was measured at 3....

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Veröffentlicht in:Journal of atmospheric chemistry 1996, Vol.24 (3), p.285-297
Hauptverfasser: BELL, W, PATON-WALSH, C, GARDINER, T. D, WOODS, P. T, SWANN, N. R, MARTIN, N. A, DONOHOE, L, CHIPPERFIELD, M. P
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container_issue 3
container_start_page 285
container_title Journal of atmospheric chemistry
container_volume 24
creator BELL, W
PATON-WALSH, C
GARDINER, T. D
WOODS, P. T
SWANN, N. R
MARTIN, N. A
DONOHOE, L
CHIPPERFIELD, M. P
description Stratospheric chlorine monoxide was measured at a site near sea level at Aberdeen, UK, using ground-based Fourier-transform infrared (FTIR) spectroscopy. Measurements were made based on the identification of 13 ClO adsorption lines. The instrumentation is described. The ClO column was measured at 3.42 10 super(15) molecules/cm super(2), which was consistent with very high ClO mixing ratios in the lower stratosphere. These high levels were related to significant ozone depletion. The total inorganic Cl column, when summed from the concentrations of ClO, hydrogen chloride, and ClONO sub(2), was found to be lower than that estimated from previous ground-based infrared measurements.
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subjects Atmospheric composition. Chemical and photochemical reactions
Earth, ocean, space
Exact sciences and technology
External geophysics
Physics of the high neutral atmosphere
title Measurements of stratospheric chlorine monoxide (ClO) from groundbased FTIR observations
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