Determination of methylene bridge crosslinking in chloromethylated PS‐DVB resins
We present the development of a method for the determination of methylene bridge crosslinking in ¹³C‐labeled chloromethylated polystyrene‐divinylbenzene resins. Our system uses a new room temperature reduction of the chloromethyl groups that circumvents the possible challenges associated with additi...
Gespeichert in:
| Veröffentlicht in: | Journal of polymer science. Part A, Polymer chemistry Polymer chemistry, 2016-07, Vol.54 (13), p.1955-1960 |
|---|---|
| Hauptverfasser: | , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 1960 |
|---|---|
| container_issue | 13 |
| container_start_page | 1955 |
| container_title | Journal of polymer science. Part A, Polymer chemistry |
| container_volume | 54 |
| creator | Burnett, G. Leslie Rohanna, John C. Rosenberg, Steve Schultz, Alfred K. Read de Alaniz, Javier |
| description | We present the development of a method for the determination of methylene bridge crosslinking in ¹³C‐labeled chloromethylated polystyrene‐divinylbenzene resins. Our system uses a new room temperature reduction of the chloromethyl groups that circumvents the possible challenges associated with additional crosslinking. We demonstrate how the reduction of the chloromethyl groups allowed for the determination of methylene bridging, derived from the methylenebis(ethenylbenzene) crosslinker, based on the integration of the methylene signal in the ¹³C NMR spectra. Utilizing this method, the total crosslinking within the chloromethylated resin generated at 35 °C was determined to be upward of 10 wt %, which increased from 6 wt % in the unfunctionalized resin. © 2016 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2016, 54, 1955–1960 |
| doi_str_mv | 10.1002/pola.28054 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1816088387</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>4053979511</sourcerecordid><originalsourceid>FETCH-LOGICAL-c4664-29f52c8a5db1137f823713919004ee83c93d16d346ed4fc5f8a4c00b0111be443</originalsourceid><addsrcrecordid>eNp90MFu1DAUBVALgcRQ2PADRGKDkFLeix3bWZYOLYiBVpRCd5YneZm6zdiDnRHMjk_gG_kS3AZYsGDlhc-1fC9jjxH2EaB6sQmD3a801OIOmyE0TQk16rtsBlqrUlbi4j57kNIVQL6r9Yx9mNNIce28HV3wReiLNY2Xu4E8FcvouhUVbQwpDc5fO78qnC_ayyHEMDE7Ulecnv38_mP-6WURKTmfHrJ7vR0SPfp97rHzo1cfD1-Xi5PjN4cHi7IVUoqyavq6arWtuyUiV72uuELeYAMgiDRvG96h7LiQ1Im-rXttRQuwBERckhB8jz2b3t3E8GVLaTRrl1oaBuspbJNBjTLX5lpl-vQfehW20effGVRaC95IrLJ6PqnbxpF6s4lubePOIJibec3NvOZ23oxxwl_dQLv_SHN6sjj4kymnjEsjffubsfHaSMVVbT6_Pzbv5FzjxZEyb7N_MvneBmNX0SVzflZBrgWo8oic_wID45Va</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1788439612</pqid></control><display><type>article</type><title>Determination of methylene bridge crosslinking in chloromethylated PS‐DVB resins</title><source>Wiley Online Library Journals Frontfile Complete</source><creator>Burnett, G. Leslie ; Rohanna, John C. ; Rosenberg, Steve ; Schultz, Alfred K. ; Read de Alaniz, Javier</creator><creatorcontrib>Burnett, G. Leslie ; Rohanna, John C. ; Rosenberg, Steve ; Schultz, Alfred K. ; Read de Alaniz, Javier</creatorcontrib><description>We present the development of a method for the determination of methylene bridge crosslinking in ¹³C‐labeled chloromethylated polystyrene‐divinylbenzene resins. Our system uses a new room temperature reduction of the chloromethyl groups that circumvents the possible challenges associated with additional crosslinking. We demonstrate how the reduction of the chloromethyl groups allowed for the determination of methylene bridging, derived from the methylenebis(ethenylbenzene) crosslinker, based on the integration of the methylene signal in the ¹³C NMR spectra. Utilizing this method, the total crosslinking within the chloromethylated resin generated at 35 °C was determined to be upward of 10 wt %, which increased from 6 wt % in the unfunctionalized resin. © 2016 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2016, 54, 1955–1960</description><identifier>ISSN: 0887-624X</identifier><identifier>EISSN: 1099-0518</identifier><identifier>DOI: 10.1002/pola.28054</identifier><identifier>CODEN: JPACEC</identifier><language>eng</language><publisher>Hoboken: John Wiley & Sons, Ltd</publisher><subject>Bridging ; chloromethylated polystyrene-divinylbenzene ; Crosslinking ; Methylene ; methylene bridge ; NMR ; Polymer chemistry ; Polymers ; Reduction ; Resins ; Spectra</subject><ispartof>Journal of polymer science. Part A, Polymer chemistry, 2016-07, Vol.54 (13), p.1955-1960</ispartof><rights>2016 Wiley Periodicals, Inc.</rights><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4664-29f52c8a5db1137f823713919004ee83c93d16d346ed4fc5f8a4c00b0111be443</citedby><cites>FETCH-LOGICAL-c4664-29f52c8a5db1137f823713919004ee83c93d16d346ed4fc5f8a4c00b0111be443</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fpola.28054$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fpola.28054$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27901,27902,45550,45551</link.rule.ids></links><search><creatorcontrib>Burnett, G. Leslie</creatorcontrib><creatorcontrib>Rohanna, John C.</creatorcontrib><creatorcontrib>Rosenberg, Steve</creatorcontrib><creatorcontrib>Schultz, Alfred K.</creatorcontrib><creatorcontrib>Read de Alaniz, Javier</creatorcontrib><title>Determination of methylene bridge crosslinking in chloromethylated PS‐DVB resins</title><title>Journal of polymer science. Part A, Polymer chemistry</title><addtitle>J. Polym. Sci. Part A: Polym. Chem</addtitle><description>We present the development of a method for the determination of methylene bridge crosslinking in ¹³C‐labeled chloromethylated polystyrene‐divinylbenzene resins. Our system uses a new room temperature reduction of the chloromethyl groups that circumvents the possible challenges associated with additional crosslinking. We demonstrate how the reduction of the chloromethyl groups allowed for the determination of methylene bridging, derived from the methylenebis(ethenylbenzene) crosslinker, based on the integration of the methylene signal in the ¹³C NMR spectra. Utilizing this method, the total crosslinking within the chloromethylated resin generated at 35 °C was determined to be upward of 10 wt %, which increased from 6 wt % in the unfunctionalized resin. © 2016 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2016, 54, 1955–1960</description><subject>Bridging</subject><subject>chloromethylated polystyrene-divinylbenzene</subject><subject>Crosslinking</subject><subject>Methylene</subject><subject>methylene bridge</subject><subject>NMR</subject><subject>Polymer chemistry</subject><subject>Polymers</subject><subject>Reduction</subject><subject>Resins</subject><subject>Spectra</subject><issn>0887-624X</issn><issn>1099-0518</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNp90MFu1DAUBVALgcRQ2PADRGKDkFLeix3bWZYOLYiBVpRCd5YneZm6zdiDnRHMjk_gG_kS3AZYsGDlhc-1fC9jjxH2EaB6sQmD3a801OIOmyE0TQk16rtsBlqrUlbi4j57kNIVQL6r9Yx9mNNIce28HV3wReiLNY2Xu4E8FcvouhUVbQwpDc5fO78qnC_ayyHEMDE7Ulecnv38_mP-6WURKTmfHrJ7vR0SPfp97rHzo1cfD1-Xi5PjN4cHi7IVUoqyavq6arWtuyUiV72uuELeYAMgiDRvG96h7LiQ1Im-rXttRQuwBERckhB8jz2b3t3E8GVLaTRrl1oaBuspbJNBjTLX5lpl-vQfehW20effGVRaC95IrLJ6PqnbxpF6s4lubePOIJibec3NvOZ23oxxwl_dQLv_SHN6sjj4kymnjEsjffubsfHaSMVVbT6_Pzbv5FzjxZEyb7N_MvneBmNX0SVzflZBrgWo8oic_wID45Va</recordid><startdate>20160701</startdate><enddate>20160701</enddate><creator>Burnett, G. Leslie</creator><creator>Rohanna, John C.</creator><creator>Rosenberg, Steve</creator><creator>Schultz, Alfred K.</creator><creator>Read de Alaniz, Javier</creator><general>John Wiley & Sons, Ltd</general><general>Blackwell Publishing Ltd</general><general>Wiley Subscription Services, Inc</general><scope>FBQ</scope><scope>BSCLL</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20160701</creationdate><title>Determination of methylene bridge crosslinking in chloromethylated PS‐DVB resins</title><author>Burnett, G. Leslie ; Rohanna, John C. ; Rosenberg, Steve ; Schultz, Alfred K. ; Read de Alaniz, Javier</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4664-29f52c8a5db1137f823713919004ee83c93d16d346ed4fc5f8a4c00b0111be443</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Bridging</topic><topic>chloromethylated polystyrene-divinylbenzene</topic><topic>Crosslinking</topic><topic>Methylene</topic><topic>methylene bridge</topic><topic>NMR</topic><topic>Polymer chemistry</topic><topic>Polymers</topic><topic>Reduction</topic><topic>Resins</topic><topic>Spectra</topic><toplevel>online_resources</toplevel><creatorcontrib>Burnett, G. Leslie</creatorcontrib><creatorcontrib>Rohanna, John C.</creatorcontrib><creatorcontrib>Rosenberg, Steve</creatorcontrib><creatorcontrib>Schultz, Alfred K.</creatorcontrib><creatorcontrib>Read de Alaniz, Javier</creatorcontrib><collection>AGRIS</collection><collection>Istex</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of polymer science. Part A, Polymer chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Burnett, G. Leslie</au><au>Rohanna, John C.</au><au>Rosenberg, Steve</au><au>Schultz, Alfred K.</au><au>Read de Alaniz, Javier</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Determination of methylene bridge crosslinking in chloromethylated PS‐DVB resins</atitle><jtitle>Journal of polymer science. Part A, Polymer chemistry</jtitle><addtitle>J. Polym. Sci. Part A: Polym. Chem</addtitle><date>2016-07-01</date><risdate>2016</risdate><volume>54</volume><issue>13</issue><spage>1955</spage><epage>1960</epage><pages>1955-1960</pages><issn>0887-624X</issn><eissn>1099-0518</eissn><coden>JPACEC</coden><abstract>We present the development of a method for the determination of methylene bridge crosslinking in ¹³C‐labeled chloromethylated polystyrene‐divinylbenzene resins. Our system uses a new room temperature reduction of the chloromethyl groups that circumvents the possible challenges associated with additional crosslinking. We demonstrate how the reduction of the chloromethyl groups allowed for the determination of methylene bridging, derived from the methylenebis(ethenylbenzene) crosslinker, based on the integration of the methylene signal in the ¹³C NMR spectra. Utilizing this method, the total crosslinking within the chloromethylated resin generated at 35 °C was determined to be upward of 10 wt %, which increased from 6 wt % in the unfunctionalized resin. © 2016 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2016, 54, 1955–1960</abstract><cop>Hoboken</cop><pub>John Wiley & Sons, Ltd</pub><doi>10.1002/pola.28054</doi><tpages>6</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0887-624X |
| ispartof | Journal of polymer science. Part A, Polymer chemistry, 2016-07, Vol.54 (13), p.1955-1960 |
| issn | 0887-624X 1099-0518 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1816088387 |
| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Bridging chloromethylated polystyrene-divinylbenzene Crosslinking Methylene methylene bridge NMR Polymer chemistry Polymers Reduction Resins Spectra |
| title | Determination of methylene bridge crosslinking in chloromethylated PS‐DVB resins |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-08T19%3A35%3A09IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Determination%20of%20methylene%20bridge%20crosslinking%20in%20chloromethylated%20PS%E2%80%90DVB%20resins&rft.jtitle=Journal%20of%20polymer%20science.%20Part%20A,%20Polymer%20chemistry&rft.au=Burnett,%20G.%20Leslie&rft.date=2016-07-01&rft.volume=54&rft.issue=13&rft.spage=1955&rft.epage=1960&rft.pages=1955-1960&rft.issn=0887-624X&rft.eissn=1099-0518&rft.coden=JPACEC&rft_id=info:doi/10.1002/pola.28054&rft_dat=%3Cproquest_cross%3E4053979511%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1788439612&rft_id=info:pmid/&rfr_iscdi=true |