External stimuli controlled multiferroic charge-transfer crystals
Multiferroic charge-transfer crystals have drawn significant interest due to their simultaneous dipolar and spin ordering. Numerous theoretical and experimental studies have shown that the molecular stacking between donor and acceptor complexes plays an important role in tuning charge-transfer enabl...
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| Veröffentlicht in: | Nano research 2016-04, Vol.9 (4), p.925-932 |
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| container_title | Nano research |
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| creator | Qin, Wei Chen, Xiaomin Lohrman, Jessica Gong, Maogang Yuan, Guoliang Wuttig, Manfred Ren, Shenqiang |
| description | Multiferroic charge-transfer crystals have drawn significant interest due to their simultaneous dipolar and spin ordering. Numerous theoretical and experimental studies have shown that the molecular stacking between donor and acceptor complexes plays an important role in tuning charge-transfer enabled multifunctionality. Herein, we show that the charge-transfer interactions can be controlled by the segregated stack, consisting of polythiophene donor- and fuUerene acceptor-based all-conjugated block copolymers. Room temperature magnetic field effects, ferroelectricity, and anisotropic magnetism are observed in charge-transfer crystals, which can be further controlled by photoexcitation and charge doping. Furthermore, the charge-transfer segregated stack crystals demonstrate external stimuli controlled polarization and magnetization, which opens up their multifunctional applications for all-organic multiferroics. |
| doi_str_mv | 10.1007/s12274-015-0975-8 |
| format | Article |
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Numerous theoretical and experimental studies have shown that the molecular stacking between donor and acceptor complexes plays an important role in tuning charge-transfer enabled multifunctionality. Herein, we show that the charge-transfer interactions can be controlled by the segregated stack, consisting of polythiophene donor- and fuUerene acceptor-based all-conjugated block copolymers. Room temperature magnetic field effects, ferroelectricity, and anisotropic magnetism are observed in charge-transfer crystals, which can be further controlled by photoexcitation and charge doping. Furthermore, the charge-transfer segregated stack crystals demonstrate external stimuli controlled polarization and magnetization, which opens up their multifunctional applications for all-organic multiferroics.</description><identifier>ISSN: 1998-0124</identifier><identifier>EISSN: 1998-0000</identifier><identifier>DOI: 10.1007/s12274-015-0975-8</identifier><language>eng</language><publisher>Beijing: Tsinghua University Press</publisher><subject>Atomic/Molecular Structure and Spectra ; Biomedicine ; Biotechnology ; Block copolymers ; Charge transfer ; Chemistry and Materials Science ; Condensed Matter Physics ; Coordination compounds ; Crystals ; External stimuli ; Ferroelectricity ; Fullerenes ; Magnetic fields ; Magnetism ; Magnetization ; Materials Science ; Multiferroic materials ; Nanostructure ; Nanotechnology ; Order disorder ; Photoexcitation ; Polythiophene ; Research Article ; Stacks ; Stimuli ; Tuning ; 分子堆积 ; 多功能应用 ; 多功能性 ; 嵌段共聚物 ; 控制 ; 晶体 ; 电荷转移 ; 铁电性</subject><ispartof>Nano research, 2016-04, Vol.9 (4), p.925-932</ispartof><rights>Tsinghua University Press and Springer-Verlag Berlin Heidelberg 2015</rights><rights>Nano Research is a copyright of Springer, (2015). All Rights Reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c376t-d7a88e994e51c6d3cba77acd5bb99e77096201f76e996760481955835052fa8b3</citedby><cites>FETCH-LOGICAL-c376t-d7a88e994e51c6d3cba77acd5bb99e77096201f76e996760481955835052fa8b3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Uhttp://image.cqvip.com/vip1000/qk/71233X/71233X.jpg</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s12274-015-0975-8$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s12274-015-0975-8$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>315,782,786,27933,27934,41497,42566,51328</link.rule.ids></links><search><creatorcontrib>Qin, Wei</creatorcontrib><creatorcontrib>Chen, Xiaomin</creatorcontrib><creatorcontrib>Lohrman, Jessica</creatorcontrib><creatorcontrib>Gong, Maogang</creatorcontrib><creatorcontrib>Yuan, Guoliang</creatorcontrib><creatorcontrib>Wuttig, Manfred</creatorcontrib><creatorcontrib>Ren, Shenqiang</creatorcontrib><title>External stimuli controlled multiferroic charge-transfer crystals</title><title>Nano research</title><addtitle>Nano Res</addtitle><addtitle>Nano Research</addtitle><description>Multiferroic charge-transfer crystals have drawn significant interest due to their simultaneous dipolar and spin ordering. Numerous theoretical and experimental studies have shown that the molecular stacking between donor and acceptor complexes plays an important role in tuning charge-transfer enabled multifunctionality. Herein, we show that the charge-transfer interactions can be controlled by the segregated stack, consisting of polythiophene donor- and fuUerene acceptor-based all-conjugated block copolymers. Room temperature magnetic field effects, ferroelectricity, and anisotropic magnetism are observed in charge-transfer crystals, which can be further controlled by photoexcitation and charge doping. 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| fulltext | fulltext |
| identifier | ISSN: 1998-0124 |
| ispartof | Nano research, 2016-04, Vol.9 (4), p.925-932 |
| issn | 1998-0124 1998-0000 |
| language | eng |
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| source | SpringerNature Journals |
| subjects | Atomic/Molecular Structure and Spectra Biomedicine Biotechnology Block copolymers Charge transfer Chemistry and Materials Science Condensed Matter Physics Coordination compounds Crystals External stimuli Ferroelectricity Fullerenes Magnetic fields Magnetism Magnetization Materials Science Multiferroic materials Nanostructure Nanotechnology Order disorder Photoexcitation Polythiophene Research Article Stacks Stimuli Tuning 分子堆积 多功能应用 多功能性 嵌段共聚物 控制 晶体 电荷转移 铁电性 |
| title | External stimuli controlled multiferroic charge-transfer crystals |
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