Hybrid Silver Mesh Electrode for ITO-Free Flexible Polymer Solar Cells with Good Mechanical Stability

Herein, we report a tailored Ag mesh electrode coated with poly(3,4‐ethylenedioxythiophene) (PEDOT) polymer on a flexible polyethylene terephthalate (PET) substrate. The introduction of this highly conductive polymer solves the existing problems of Ag mesh‐type transparent conductive electrodes, such as high pitch, roughness, current inhomogeneity, and adhesion problems between the Ag mesh grid and PEDOT polymer or PET substrate, to result in excellent electron spreading from the discrete Ag mesh onto the entire surface without sacrificing sheet conductivity and optical transparency. Based on this hybrid anode, we demonstrate highly efficient flexible polymer solar cells (PSCs) with a high fill factor of 67.11 %, which results in a power conversion efficiency (PCE) of 6.9 % based on a poly({4,8‐bis[(2‐ethylhexyl)oxy]benzo[1,2‐b:4,5‐b′] dithiophene‐2,6‐diyl}{3‐fluoro‐2‐[(2‐ethylhexyl) carbonyl]thieno[3,4‐b]thiophenediyl}):[6,6]‐phenyl‐C71‐butyric acid methyl ester bulk heterojunction device. Furthermore, the PSC device with the Ag mesh electrode also exhibits a good mechanical bending stability, as indicated by a 70 % retention of the initial PCE after 500 bending cycles compared with the PSC device with a PET/indium tin oxide electrode, which retained 0 % of the initial PCE after 300 bending cycles. Highly conductive, flexible hybrid electrode: Herein, we report a highly conductive, flexible hybrid Ag mesh electrode on a flexible polyethylene terephthalate (PET) substrate. The introduction of a highly conductive polymer solves the existing problems of Ag mesh‐type transparent conductive electrodes, and highly efficient flexible polymer solar cells (PSCs) are demonstrated.