A Single-Crystalline Mesoporous Quartz Superlattice
There has been significant interest in the crystallization of nanostructured silica into α‐quartz because of its physicochemical properties. We demonstrate a single‐crystalline mesoporous quartz superlattice, a silica polymorph with unprecedentedly ordered hierarchical structures on both the several...
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| Veröffentlicht in: | Angewandte Chemie 2016-05, Vol.128 (20), p.6112-6116 |
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| container_title | Angewandte Chemie |
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| creator | Matsuno, Takamichi Kuroda, Yoshiyuki Kitahara, Masaki Shimojima, Atsushi Wada, Hiroaki Kuroda, Kazuyuki |
| description | There has been significant interest in the crystallization of nanostructured silica into α‐quartz because of its physicochemical properties. We demonstrate a single‐crystalline mesoporous quartz superlattice, a silica polymorph with unprecedentedly ordered hierarchical structures on both the several tens of nanometers scale and the atomic one. The mesoporous quartz superlattice consists of periodically arranged α‐quartz nanospheres whose crystalline axes are mostly oriented in an assembly. The superlattice is prepared by thermal crystallization of amorphous silica nanospheres constituting a colloidal crystal. We found that the deposition of a strong flux of Li+ only on the surface of silica nanospheres is effective for crystallization.
Doppelt geordnet: Ein mesoporöses, auf Nanometer‐ und Atomebene periodisches Quarz‐Übergitter entsteht durch die Kristallisation der amorphen Siliciumoxid‐Nanokügelchen eines Kolloidkristalls. Die Anordnung der Siliciumoxid‐Nanokügelchen bleibt trotz der Anwendung von Li+‐Ionen erhalten. |
| doi_str_mv | 10.1002/ange.201600675 |
| format | Article |
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Doppelt geordnet: Ein mesoporöses, auf Nanometer‐ und Atomebene periodisches Quarz‐Übergitter entsteht durch die Kristallisation der amorphen Siliciumoxid‐Nanokügelchen eines Kolloidkristalls. Die Anordnung der Siliciumoxid‐Nanokügelchen bleibt trotz der Anwendung von Li+‐Ionen erhalten.</description><identifier>ISSN: 0044-8249</identifier><identifier>EISSN: 1521-3757</identifier><identifier>DOI: 10.1002/ange.201600675</identifier><language>eng</language><publisher>Weinheim: Blackwell Publishing Ltd</publisher><subject>Atomic structure ; Chemistry ; Crystal structure ; Crystallinity ; Crystallization ; Einkristalle ; Kolloidkristalle ; Mesoporöses Siliciumdioxid ; Nanospheres ; Nanostructure ; Physicochemical properties ; Quartz ; Silica ; Silicon dioxide ; Single crystals ; Structural hierarchy ; Superlattices ; Übergitter ; α-Quarz</subject><ispartof>Angewandte Chemie, 2016-05, Vol.128 (20), p.6112-6116</ispartof><rights>2016 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3275-5c3d7b2e5b1a70f546cd476e27502d37d0cb0ef22a2e5ba900fca7caf660716e3</citedby><cites>FETCH-LOGICAL-c3275-5c3d7b2e5b1a70f546cd476e27502d37d0cb0ef22a2e5ba900fca7caf660716e3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fange.201600675$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fange.201600675$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1417,27924,27925,45574,45575</link.rule.ids></links><search><creatorcontrib>Matsuno, Takamichi</creatorcontrib><creatorcontrib>Kuroda, Yoshiyuki</creatorcontrib><creatorcontrib>Kitahara, Masaki</creatorcontrib><creatorcontrib>Shimojima, Atsushi</creatorcontrib><creatorcontrib>Wada, Hiroaki</creatorcontrib><creatorcontrib>Kuroda, Kazuyuki</creatorcontrib><title>A Single-Crystalline Mesoporous Quartz Superlattice</title><title>Angewandte Chemie</title><addtitle>Angew. Chem</addtitle><description>There has been significant interest in the crystallization of nanostructured silica into α‐quartz because of its physicochemical properties. We demonstrate a single‐crystalline mesoporous quartz superlattice, a silica polymorph with unprecedentedly ordered hierarchical structures on both the several tens of nanometers scale and the atomic one. The mesoporous quartz superlattice consists of periodically arranged α‐quartz nanospheres whose crystalline axes are mostly oriented in an assembly. The superlattice is prepared by thermal crystallization of amorphous silica nanospheres constituting a colloidal crystal. We found that the deposition of a strong flux of Li+ only on the surface of silica nanospheres is effective for crystallization.
Doppelt geordnet: Ein mesoporöses, auf Nanometer‐ und Atomebene periodisches Quarz‐Übergitter entsteht durch die Kristallisation der amorphen Siliciumoxid‐Nanokügelchen eines Kolloidkristalls. Die Anordnung der Siliciumoxid‐Nanokügelchen bleibt trotz der Anwendung von Li+‐Ionen erhalten.</description><subject>Atomic structure</subject><subject>Chemistry</subject><subject>Crystal structure</subject><subject>Crystallinity</subject><subject>Crystallization</subject><subject>Einkristalle</subject><subject>Kolloidkristalle</subject><subject>Mesoporöses Siliciumdioxid</subject><subject>Nanospheres</subject><subject>Nanostructure</subject><subject>Physicochemical properties</subject><subject>Quartz</subject><subject>Silica</subject><subject>Silicon dioxide</subject><subject>Single crystals</subject><subject>Structural hierarchy</subject><subject>Superlattices</subject><subject>Übergitter</subject><subject>α-Quarz</subject><issn>0044-8249</issn><issn>1521-3757</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNqFkU1PwzAMhiMEEmNw5TyJC5cOJ03j7TgNGAgYGh-CW5RlLuro2pG0gvHryVQ0IQ5w8sHPY9mvGTvk0OUA4sQUL9QVwBWAwmSLtXgieBRjgtusBSBl1BOyv8v2vJ9DYAT2WywedO6z4iWnaOhWvjJ5nhXUuSFfLktX1r4zqY2rPjv39ZJcbqoqs7TPdlKTezr4rm32eH72MLyIrm9Hl8PBdWRjgUmU2HiGU0HJlBuENJHKziQqCj0QsxhnYKdAqRBmzZg-QGoNWpMqBcgVxW123MxduvKtJl_pReYt5bkpKKymeS_cGqswOKBHv9B5WbsibKcFJAgyBMT_ojj2UEqUPRGobkNZV3rvKNVLly2MW2kOep20XietN0kHod8I71lOq39oPRiPzn66UeNmvqKPjWvcq1YYfqefxiN9JZ6v7k4nqMfxFzfUj1M</recordid><startdate>20160510</startdate><enddate>20160510</enddate><creator>Matsuno, Takamichi</creator><creator>Kuroda, Yoshiyuki</creator><creator>Kitahara, Masaki</creator><creator>Shimojima, Atsushi</creator><creator>Wada, Hiroaki</creator><creator>Kuroda, Kazuyuki</creator><general>Blackwell Publishing Ltd</general><general>Wiley Subscription Services, Inc</general><scope>BSCLL</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20160510</creationdate><title>A Single-Crystalline Mesoporous Quartz Superlattice</title><author>Matsuno, Takamichi ; Kuroda, Yoshiyuki ; Kitahara, Masaki ; Shimojima, Atsushi ; Wada, Hiroaki ; Kuroda, Kazuyuki</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3275-5c3d7b2e5b1a70f546cd476e27502d37d0cb0ef22a2e5ba900fca7caf660716e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Atomic structure</topic><topic>Chemistry</topic><topic>Crystal structure</topic><topic>Crystallinity</topic><topic>Crystallization</topic><topic>Einkristalle</topic><topic>Kolloidkristalle</topic><topic>Mesoporöses Siliciumdioxid</topic><topic>Nanospheres</topic><topic>Nanostructure</topic><topic>Physicochemical properties</topic><topic>Quartz</topic><topic>Silica</topic><topic>Silicon dioxide</topic><topic>Single crystals</topic><topic>Structural hierarchy</topic><topic>Superlattices</topic><topic>Übergitter</topic><topic>α-Quarz</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Matsuno, Takamichi</creatorcontrib><creatorcontrib>Kuroda, Yoshiyuki</creatorcontrib><creatorcontrib>Kitahara, Masaki</creatorcontrib><creatorcontrib>Shimojima, Atsushi</creatorcontrib><creatorcontrib>Wada, Hiroaki</creatorcontrib><creatorcontrib>Kuroda, Kazuyuki</creatorcontrib><collection>Istex</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Angewandte Chemie</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Matsuno, Takamichi</au><au>Kuroda, Yoshiyuki</au><au>Kitahara, Masaki</au><au>Shimojima, Atsushi</au><au>Wada, Hiroaki</au><au>Kuroda, Kazuyuki</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A Single-Crystalline Mesoporous Quartz Superlattice</atitle><jtitle>Angewandte Chemie</jtitle><addtitle>Angew. Chem</addtitle><date>2016-05-10</date><risdate>2016</risdate><volume>128</volume><issue>20</issue><spage>6112</spage><epage>6116</epage><pages>6112-6116</pages><issn>0044-8249</issn><eissn>1521-3757</eissn><abstract>There has been significant interest in the crystallization of nanostructured silica into α‐quartz because of its physicochemical properties. We demonstrate a single‐crystalline mesoporous quartz superlattice, a silica polymorph with unprecedentedly ordered hierarchical structures on both the several tens of nanometers scale and the atomic one. The mesoporous quartz superlattice consists of periodically arranged α‐quartz nanospheres whose crystalline axes are mostly oriented in an assembly. The superlattice is prepared by thermal crystallization of amorphous silica nanospheres constituting a colloidal crystal. We found that the deposition of a strong flux of Li+ only on the surface of silica nanospheres is effective for crystallization.
Doppelt geordnet: Ein mesoporöses, auf Nanometer‐ und Atomebene periodisches Quarz‐Übergitter entsteht durch die Kristallisation der amorphen Siliciumoxid‐Nanokügelchen eines Kolloidkristalls. Die Anordnung der Siliciumoxid‐Nanokügelchen bleibt trotz der Anwendung von Li+‐Ionen erhalten.</abstract><cop>Weinheim</cop><pub>Blackwell Publishing Ltd</pub><doi>10.1002/ange.201600675</doi><tpages>5</tpages></addata></record> |
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| source | Wiley Online Library All Journals |
| subjects | Atomic structure Chemistry Crystal structure Crystallinity Crystallization Einkristalle Kolloidkristalle Mesoporöses Siliciumdioxid Nanospheres Nanostructure Physicochemical properties Quartz Silica Silicon dioxide Single crystals Structural hierarchy Superlattices Übergitter α-Quarz |
| title | A Single-Crystalline Mesoporous Quartz Superlattice |
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