Switching between cisand transanions of 2-(2'-hydroxyphenyl)benzimidazole: a molecular rotation perturbed by chemical stabilization

Despite the fact that 2-(2'-hydroxyphenyl)benzimidazole (HPBI) exists as the cisand transenol in neutral form, it was reported to exist only in the transform upon deprotonation in an aqueous medium. It was also shown that the dianion formed in the ground state can be re-protonated to form the t...

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Veröffentlicht in:	Physical chemistry chemical physics : PCCP 2016-04, Vol.18 (16), p.11081-11090
Hauptverfasser:	Sahu, Saugata, Das, Minati, Krishnamoorthy, G
Format:	Artikel
Sprache:	eng
Schlagworte:	Ground state Mathematical analysis Molecular rotation Physical chemistry Solvents Stabilization Switching Transforms
Online-Zugang:	Volltext
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