Scalable, easy synthesis, and efficient isolation of arylnitromethanes: a revival of the Victor Meyer reaction

A modified approach to synthesize and isolate arylnitromethanes is described. The method takes advantage of the significant difference in acidity between the arylnitromethane and the major impurity of the reaction, the nitrite ester. The arylnitromethanes resulting from this process are obtained in...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Tetrahedron 2016-03, Vol.72 (10), p.1337-1341
Hauptverfasser:	Alaime, Thibaud, Delots, Audrey, Pasquinet, Eric, Suzenet, Franck, Guillaumet, Gérald
Format:	Artikel
Sprache:	eng
Schlagworte:	Aliphatic nitro compound Arylnitromethane Benzylic nitro compound Distillation Esters Impurities Mathematical analysis Meyer reaction Nef reaction Nitrites Purification Synthesis (chemistry) Tetrahedrons
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!