Fabrication of nanodiamond-based composite monolithic column and its application in separation of small molecules
ABSTRACT A nanodiamond‐based composite monolithic column was fabricated by redox initiation for high‐performance liquid chromatography. In the fabrication process, functionalized nanodiamond was used as the functional monomer, dipentaerythritol hexaacrylate and 1,10‐decanediol diacrylate as cross‐li...
Gespeichert in:
| Veröffentlicht in: | Journal of applied polymer science 2016-08, Vol.133 (31), p.np-n/a |
|---|---|
| Hauptverfasser: | , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | n/a |
|---|---|
| container_issue | 31 |
| container_start_page | np |
| container_title | Journal of applied polymer science |
| container_volume | 133 |
| creator | Wei, A. L. Liu, H. Y. Wang, F. Q. Li, X. Y. Yan, H. Y. |
| description | ABSTRACT
A nanodiamond‐based composite monolithic column was fabricated by redox initiation for high‐performance liquid chromatography. In the fabrication process, functionalized nanodiamond was used as the functional monomer, dipentaerythritol hexaacrylate and 1,10‐decanediol diacrylate as cross‐linking agents, polyethylene glycol 400 and 1‐propanol as coporogens, and dibenzoyl peroxide and N,N‐dimethyl aniline as initiators. Compared to polymer monolithic columns without nanodiamond, a nanodiamond‐based composite monolithic column prepared under the same conditions exhibited relatively high resolution and efficiency. Characterizations of the resulting nanocomposite were carried out, including scanning electron microscopy, mercury intrusion porosimetry, nitrogen adsorption–desorption isotherm measurement, and thermogravimetric analysis. The ND‐based composite monolith exhibited a uniform and reticular skeleton microstructure, thermal stability, and mechanical stability. In addition, the nanodiamond‐based composite monolithic column was used to separate a series of small molecules with good resolution and reproducibility in high‐performance liquid chromatography. © 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016, 133, 43776. |
| doi_str_mv | 10.1002/app.43776 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1815999520</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>4054213211</sourcerecordid><originalsourceid>FETCH-LOGICAL-c4056-7105407b581d8e5a9293b1a86e23185b99b7497fd01fb51b3b42dec2b9f03a933</originalsourceid><addsrcrecordid>eNp1kMtKxjAQhYMo-HtZ-AYFN7qoJk3SJEsRbygqXsFNSNoUo2lSkxb17Y3-6kJwNXDmO2eGA8AGgjsIwmpXDcMOwYzVC2CGoGAlqSu-CGZ5h0ouBF0GKyk9QYgQhfUMvBwqHW2jRht8EbrCKx9aq_rg21KrZNqiCf0Qkh1NkcXg7Phomyy6qfeF8m1hx1Tkq-4nxPoimUHF38jUK-ey2ZlmciatgaVOuWTWv-cquD08uNk_Ls8ujk72987KhkBalwxBSiDTlKOWG6pEJbBGitemwohTLYRmRLCuhajTFGmsSdWaptKig1gJjFfB1jx3iOFlMmmUvU2NcU55E6YkEUdU5EIqmNHNP-hTmKLP30nEOCe8JrjK1PacamJIKZpODtH2Kr5LBOVn-TLXIL_Kz-zunH21zrz_D8q9y8sfRzl32DSat1-His-yZphReX9-JE-vyR2n5EFe4Q_lqpXt</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1788486432</pqid></control><display><type>article</type><title>Fabrication of nanodiamond-based composite monolithic column and its application in separation of small molecules</title><source>Wiley Online Library Journals Frontfile Complete</source><creator>Wei, A. L. ; Liu, H. Y. ; Wang, F. Q. ; Li, X. Y. ; Yan, H. Y.</creator><creatorcontrib>Wei, A. L. ; Liu, H. Y. ; Wang, F. Q. ; Li, X. Y. ; Yan, H. Y.</creatorcontrib><description>ABSTRACT
A nanodiamond‐based composite monolithic column was fabricated by redox initiation for high‐performance liquid chromatography. In the fabrication process, functionalized nanodiamond was used as the functional monomer, dipentaerythritol hexaacrylate and 1,10‐decanediol diacrylate as cross‐linking agents, polyethylene glycol 400 and 1‐propanol as coporogens, and dibenzoyl peroxide and N,N‐dimethyl aniline as initiators. Compared to polymer monolithic columns without nanodiamond, a nanodiamond‐based composite monolithic column prepared under the same conditions exhibited relatively high resolution and efficiency. Characterizations of the resulting nanocomposite were carried out, including scanning electron microscopy, mercury intrusion porosimetry, nitrogen adsorption–desorption isotherm measurement, and thermogravimetric analysis. The ND‐based composite monolith exhibited a uniform and reticular skeleton microstructure, thermal stability, and mechanical stability. In addition, the nanodiamond‐based composite monolithic column was used to separate a series of small molecules with good resolution and reproducibility in high‐performance liquid chromatography. © 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016, 133, 43776.</description><identifier>ISSN: 0021-8995</identifier><identifier>EISSN: 1097-4628</identifier><identifier>DOI: 10.1002/app.43776</identifier><identifier>CODEN: JAPNAB</identifier><language>eng</language><publisher>Hoboken: Blackwell Publishing Ltd</publisher><subject>Aniline ; Columns (process) ; composites ; Crosslinking ; Dibenzoyl peroxide ; High performance liquid chromatography ; Materials science ; nanoparticles ; Nanostructure ; nanowires and nanocrystals ; Polyethylene glycol ; Polymers ; porous materials ; properties and characterization ; separation techniques ; Thermogravimetric analysis</subject><ispartof>Journal of applied polymer science, 2016-08, Vol.133 (31), p.np-n/a</ispartof><rights>2016 Wiley Periodicals, Inc.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4056-7105407b581d8e5a9293b1a86e23185b99b7497fd01fb51b3b42dec2b9f03a933</citedby><cites>FETCH-LOGICAL-c4056-7105407b581d8e5a9293b1a86e23185b99b7497fd01fb51b3b42dec2b9f03a933</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fapp.43776$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fapp.43776$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27903,27904,45553,45554</link.rule.ids></links><search><creatorcontrib>Wei, A. L.</creatorcontrib><creatorcontrib>Liu, H. Y.</creatorcontrib><creatorcontrib>Wang, F. Q.</creatorcontrib><creatorcontrib>Li, X. Y.</creatorcontrib><creatorcontrib>Yan, H. Y.</creatorcontrib><title>Fabrication of nanodiamond-based composite monolithic column and its application in separation of small molecules</title><title>Journal of applied polymer science</title><addtitle>J. Appl. Polym. Sci</addtitle><description>ABSTRACT
A nanodiamond‐based composite monolithic column was fabricated by redox initiation for high‐performance liquid chromatography. In the fabrication process, functionalized nanodiamond was used as the functional monomer, dipentaerythritol hexaacrylate and 1,10‐decanediol diacrylate as cross‐linking agents, polyethylene glycol 400 and 1‐propanol as coporogens, and dibenzoyl peroxide and N,N‐dimethyl aniline as initiators. Compared to polymer monolithic columns without nanodiamond, a nanodiamond‐based composite monolithic column prepared under the same conditions exhibited relatively high resolution and efficiency. Characterizations of the resulting nanocomposite were carried out, including scanning electron microscopy, mercury intrusion porosimetry, nitrogen adsorption–desorption isotherm measurement, and thermogravimetric analysis. The ND‐based composite monolith exhibited a uniform and reticular skeleton microstructure, thermal stability, and mechanical stability. In addition, the nanodiamond‐based composite monolithic column was used to separate a series of small molecules with good resolution and reproducibility in high‐performance liquid chromatography. © 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016, 133, 43776.</description><subject>Aniline</subject><subject>Columns (process)</subject><subject>composites</subject><subject>Crosslinking</subject><subject>Dibenzoyl peroxide</subject><subject>High performance liquid chromatography</subject><subject>Materials science</subject><subject>nanoparticles</subject><subject>Nanostructure</subject><subject>nanowires and nanocrystals</subject><subject>Polyethylene glycol</subject><subject>Polymers</subject><subject>porous materials</subject><subject>properties and characterization</subject><subject>separation techniques</subject><subject>Thermogravimetric analysis</subject><issn>0021-8995</issn><issn>1097-4628</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNp1kMtKxjAQhYMo-HtZ-AYFN7qoJk3SJEsRbygqXsFNSNoUo2lSkxb17Y3-6kJwNXDmO2eGA8AGgjsIwmpXDcMOwYzVC2CGoGAlqSu-CGZ5h0ouBF0GKyk9QYgQhfUMvBwqHW2jRht8EbrCKx9aq_rg21KrZNqiCf0Qkh1NkcXg7Phomyy6qfeF8m1hx1Tkq-4nxPoimUHF38jUK-ey2ZlmciatgaVOuWTWv-cquD08uNk_Ls8ujk72987KhkBalwxBSiDTlKOWG6pEJbBGitemwohTLYRmRLCuhajTFGmsSdWaptKig1gJjFfB1jx3iOFlMmmUvU2NcU55E6YkEUdU5EIqmNHNP-hTmKLP30nEOCe8JrjK1PacamJIKZpODtH2Kr5LBOVn-TLXIL_Kz-zunH21zrz_D8q9y8sfRzl32DSat1-His-yZphReX9-JE-vyR2n5EFe4Q_lqpXt</recordid><startdate>20160815</startdate><enddate>20160815</enddate><creator>Wei, A. L.</creator><creator>Liu, H. Y.</creator><creator>Wang, F. Q.</creator><creator>Li, X. Y.</creator><creator>Yan, H. Y.</creator><general>Blackwell Publishing Ltd</general><general>Wiley Subscription Services, Inc</general><scope>BSCLL</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20160815</creationdate><title>Fabrication of nanodiamond-based composite monolithic column and its application in separation of small molecules</title><author>Wei, A. L. ; Liu, H. Y. ; Wang, F. Q. ; Li, X. Y. ; Yan, H. Y.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4056-7105407b581d8e5a9293b1a86e23185b99b7497fd01fb51b3b42dec2b9f03a933</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Aniline</topic><topic>Columns (process)</topic><topic>composites</topic><topic>Crosslinking</topic><topic>Dibenzoyl peroxide</topic><topic>High performance liquid chromatography</topic><topic>Materials science</topic><topic>nanoparticles</topic><topic>Nanostructure</topic><topic>nanowires and nanocrystals</topic><topic>Polyethylene glycol</topic><topic>Polymers</topic><topic>porous materials</topic><topic>properties and characterization</topic><topic>separation techniques</topic><topic>Thermogravimetric analysis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Wei, A. L.</creatorcontrib><creatorcontrib>Liu, H. Y.</creatorcontrib><creatorcontrib>Wang, F. Q.</creatorcontrib><creatorcontrib>Li, X. Y.</creatorcontrib><creatorcontrib>Yan, H. Y.</creatorcontrib><collection>Istex</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of applied polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wei, A. L.</au><au>Liu, H. Y.</au><au>Wang, F. Q.</au><au>Li, X. Y.</au><au>Yan, H. Y.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Fabrication of nanodiamond-based composite monolithic column and its application in separation of small molecules</atitle><jtitle>Journal of applied polymer science</jtitle><addtitle>J. Appl. Polym. Sci</addtitle><date>2016-08-15</date><risdate>2016</risdate><volume>133</volume><issue>31</issue><spage>np</spage><epage>n/a</epage><pages>np-n/a</pages><issn>0021-8995</issn><eissn>1097-4628</eissn><coden>JAPNAB</coden><abstract>ABSTRACT
A nanodiamond‐based composite monolithic column was fabricated by redox initiation for high‐performance liquid chromatography. In the fabrication process, functionalized nanodiamond was used as the functional monomer, dipentaerythritol hexaacrylate and 1,10‐decanediol diacrylate as cross‐linking agents, polyethylene glycol 400 and 1‐propanol as coporogens, and dibenzoyl peroxide and N,N‐dimethyl aniline as initiators. Compared to polymer monolithic columns without nanodiamond, a nanodiamond‐based composite monolithic column prepared under the same conditions exhibited relatively high resolution and efficiency. Characterizations of the resulting nanocomposite were carried out, including scanning electron microscopy, mercury intrusion porosimetry, nitrogen adsorption–desorption isotherm measurement, and thermogravimetric analysis. The ND‐based composite monolith exhibited a uniform and reticular skeleton microstructure, thermal stability, and mechanical stability. In addition, the nanodiamond‐based composite monolithic column was used to separate a series of small molecules with good resolution and reproducibility in high‐performance liquid chromatography. © 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016, 133, 43776.</abstract><cop>Hoboken</cop><pub>Blackwell Publishing Ltd</pub><doi>10.1002/app.43776</doi><tpages>7</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0021-8995 |
| ispartof | Journal of applied polymer science, 2016-08, Vol.133 (31), p.np-n/a |
| issn | 0021-8995 1097-4628 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1815999520 |
| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Aniline Columns (process) composites Crosslinking Dibenzoyl peroxide High performance liquid chromatography Materials science nanoparticles Nanostructure nanowires and nanocrystals Polyethylene glycol Polymers porous materials properties and characterization separation techniques Thermogravimetric analysis |
| title | Fabrication of nanodiamond-based composite monolithic column and its application in separation of small molecules |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-22T23%3A26%3A55IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Fabrication%20of%20nanodiamond-based%20composite%20monolithic%20column%20and%20its%20application%20in%20separation%20of%20small%20molecules&rft.jtitle=Journal%20of%20applied%20polymer%20science&rft.au=Wei,%20A.%20L.&rft.date=2016-08-15&rft.volume=133&rft.issue=31&rft.spage=np&rft.epage=n/a&rft.pages=np-n/a&rft.issn=0021-8995&rft.eissn=1097-4628&rft.coden=JAPNAB&rft_id=info:doi/10.1002/app.43776&rft_dat=%3Cproquest_cross%3E4054213211%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1788486432&rft_id=info:pmid/&rfr_iscdi=true |