A tandem dye-sensitized photoelectrochemical cell for light driven hydrogen production

Combining a dye-sensitized photoelectrochemical cell for hydrogen production based on a SnO 2 photoanode in series with a dye-sensitized photovoltaic solar cell using a TiO 2 photoanode yields a tandem system for the generation of H 2 from hydroquinone using only light energy and no applied electric...

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Veröffentlicht in:Energy & environmental science 2016-05, Vol.9 (5), p.1812-1817
Hauptverfasser: Sherman, Benjamin D, Bergkamp, Jesse J, Brown, Chelsea L, Moore, Ana L, Gust, Devens, Moore, Thomas A
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container_end_page 1817
container_issue 5
container_start_page 1812
container_title Energy & environmental science
container_volume 9
creator Sherman, Benjamin D
Bergkamp, Jesse J
Brown, Chelsea L
Moore, Ana L
Gust, Devens
Moore, Thomas A
description Combining a dye-sensitized photoelectrochemical cell for hydrogen production based on a SnO 2 photoanode in series with a dye-sensitized photovoltaic solar cell using a TiO 2 photoanode yields a tandem system for the generation of H 2 from hydroquinone using only light energy and no applied electrical bias. To target distinct portions of the solar spectrum, a more blue-absorbing free base porphyrin and a more red-absorbing Si phthalocyanine chromophore are used at the two photoelectrodes. With incorporation of a suitable water oxidation catalyst, a similar approach could enable tandem photochemical water splitting without the need for p-type semiconductors. A tandem cell incorporating two dye-sensitized photoanodes produces H 2 from hydroquinone using only light energy and no applied electrical bias.
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source Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects Catalysts
Energy use
Hydrogen production
Photoelectrochemical devices
Photovoltaic cells
Solar cells
Tin dioxide
Titanium dioxide
title A tandem dye-sensitized photoelectrochemical cell for light driven hydrogen production
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