The enhancement of chain rigidity and gas transport performance of polymers of intrinsic microporosity via intramolecular locking of the spiro-carbon
Here, we present a new strategy to improve the rigidity of through the introduction of 8-membered ring locking into the flexible spiro-carbon pivot point to produce an interlocked polycyclic structure. This locked version of shows simultaneous increases in both permeability and selectivity that plac...
Gespeichert in:
| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2016-01, Vol.52 (39), p.6553-6556 |
|---|---|
| Hauptverfasser: | , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 6556 |
|---|---|
| container_issue | 39 |
| container_start_page | 6553 |
| container_title | Chemical communications (Cambridge, England) |
| container_volume | 52 |
| creator | Zhang, Jian Kang, Hong Martin, Jacob Zhang, Shouhai Thomas, Sylvie Merkel, Tim C Jin, Jianyong |
| description | Here, we present a new strategy to improve the rigidity of through the introduction of 8-membered ring locking into the flexible spiro-carbon pivot point to produce an interlocked polycyclic structure. This locked version of shows simultaneous increases in both permeability and selectivity that place it well above the Robeson upper bound for a number of important gas pairs. Molecular modelling demonstrates that the locked version of is much more rigid. |
| doi_str_mv | 10.1039/c6cc02308h |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1815995756</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1815995756</sourcerecordid><originalsourceid>FETCH-LOGICAL-c386t-6b6b4a8875997f1903656d13b02afdd562f07e90075563e63443aacbb21e50233</originalsourceid><addsrcrecordid>eNqFkc1KxDAUhYMozviz8QEkSxGqSfPbpRR1hAE3Cu5KmqYz0TapSUeYB_F9TR11693cC_c7h8s9AJxhdIURKa411xrlBMn1HphjwmnGqHzZn2ZWZIJQNgNHMb6iVJjJQzDLRRLmjM7B59PaQOPWymnTGzdC30K9VtbBYFe2seMWKtfAlYpwDMrFwYcRDia0PvSTZuIH3217E-I0WzcG66LVsLc6-IT7OJl8WPW9U73vjN50KsDO6zfrVpNqTEfEwQafaRVq707AQau6aE5_-jF4vrt9KhfZ8vH-obxZZppIPma85jVVUgpWFKLFBSKc8QaTGuWqbRrG8xYJUyAkGOPEcEIpUUrXdY4NSx8jx-Bi5zsE_74xcax6G7XpOuWM38QKS5ysmUjqf1EhBRWSMpbQyx2aHhBjMG01BNursK0wqqbEqpKX5XdiiwSf__hu6t40f-hvROQLs9KTdA</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1787478455</pqid></control><display><type>article</type><title>The enhancement of chain rigidity and gas transport performance of polymers of intrinsic microporosity via intramolecular locking of the spiro-carbon</title><source>Royal Society Of Chemistry Journals 2008-</source><source>Alma/SFX Local Collection</source><creator>Zhang, Jian ; Kang, Hong ; Martin, Jacob ; Zhang, Shouhai ; Thomas, Sylvie ; Merkel, Tim C ; Jin, Jianyong</creator><creatorcontrib>Zhang, Jian ; Kang, Hong ; Martin, Jacob ; Zhang, Shouhai ; Thomas, Sylvie ; Merkel, Tim C ; Jin, Jianyong</creatorcontrib><description>Here, we present a new strategy to improve the rigidity of through the introduction of 8-membered ring locking into the flexible spiro-carbon pivot point to produce an interlocked polycyclic structure. This locked version of shows simultaneous increases in both permeability and selectivity that place it well above the Robeson upper bound for a number of important gas pairs. Molecular modelling demonstrates that the locked version of is much more rigid.</description><identifier>ISSN: 1359-7345</identifier><identifier>EISSN: 1364-548X</identifier><identifier>DOI: 10.1039/c6cc02308h</identifier><identifier>PMID: 27103254</identifier><language>eng</language><publisher>England</publisher><subject>Gas transport ; Locking ; Molecular structure ; Pivots ; Polymers ; Rigidity ; Strategy ; Upper bounds</subject><ispartof>Chemical communications (Cambridge, England), 2016-01, Vol.52 (39), p.6553-6556</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c386t-6b6b4a8875997f1903656d13b02afdd562f07e90075563e63443aacbb21e50233</citedby><cites>FETCH-LOGICAL-c386t-6b6b4a8875997f1903656d13b02afdd562f07e90075563e63443aacbb21e50233</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>315,781,785,27928,27929</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/27103254$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Zhang, Jian</creatorcontrib><creatorcontrib>Kang, Hong</creatorcontrib><creatorcontrib>Martin, Jacob</creatorcontrib><creatorcontrib>Zhang, Shouhai</creatorcontrib><creatorcontrib>Thomas, Sylvie</creatorcontrib><creatorcontrib>Merkel, Tim C</creatorcontrib><creatorcontrib>Jin, Jianyong</creatorcontrib><title>The enhancement of chain rigidity and gas transport performance of polymers of intrinsic microporosity via intramolecular locking of the spiro-carbon</title><title>Chemical communications (Cambridge, England)</title><addtitle>Chem Commun (Camb)</addtitle><description>Here, we present a new strategy to improve the rigidity of through the introduction of 8-membered ring locking into the flexible spiro-carbon pivot point to produce an interlocked polycyclic structure. This locked version of shows simultaneous increases in both permeability and selectivity that place it well above the Robeson upper bound for a number of important gas pairs. Molecular modelling demonstrates that the locked version of is much more rigid.</description><subject>Gas transport</subject><subject>Locking</subject><subject>Molecular structure</subject><subject>Pivots</subject><subject>Polymers</subject><subject>Rigidity</subject><subject>Strategy</subject><subject>Upper bounds</subject><issn>1359-7345</issn><issn>1364-548X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNqFkc1KxDAUhYMozviz8QEkSxGqSfPbpRR1hAE3Cu5KmqYz0TapSUeYB_F9TR11693cC_c7h8s9AJxhdIURKa411xrlBMn1HphjwmnGqHzZn2ZWZIJQNgNHMb6iVJjJQzDLRRLmjM7B59PaQOPWymnTGzdC30K9VtbBYFe2seMWKtfAlYpwDMrFwYcRDia0PvSTZuIH3217E-I0WzcG66LVsLc6-IT7OJl8WPW9U73vjN50KsDO6zfrVpNqTEfEwQafaRVq707AQau6aE5_-jF4vrt9KhfZ8vH-obxZZppIPma85jVVUgpWFKLFBSKc8QaTGuWqbRrG8xYJUyAkGOPEcEIpUUrXdY4NSx8jx-Bi5zsE_74xcax6G7XpOuWM38QKS5ysmUjqf1EhBRWSMpbQyx2aHhBjMG01BNursK0wqqbEqpKX5XdiiwSf__hu6t40f-hvROQLs9KTdA</recordid><startdate>20160101</startdate><enddate>20160101</enddate><creator>Zhang, Jian</creator><creator>Kang, Hong</creator><creator>Martin, Jacob</creator><creator>Zhang, Shouhai</creator><creator>Thomas, Sylvie</creator><creator>Merkel, Tim C</creator><creator>Jin, Jianyong</creator><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20160101</creationdate><title>The enhancement of chain rigidity and gas transport performance of polymers of intrinsic microporosity via intramolecular locking of the spiro-carbon</title><author>Zhang, Jian ; Kang, Hong ; Martin, Jacob ; Zhang, Shouhai ; Thomas, Sylvie ; Merkel, Tim C ; Jin, Jianyong</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c386t-6b6b4a8875997f1903656d13b02afdd562f07e90075563e63443aacbb21e50233</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Gas transport</topic><topic>Locking</topic><topic>Molecular structure</topic><topic>Pivots</topic><topic>Polymers</topic><topic>Rigidity</topic><topic>Strategy</topic><topic>Upper bounds</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhang, Jian</creatorcontrib><creatorcontrib>Kang, Hong</creatorcontrib><creatorcontrib>Martin, Jacob</creatorcontrib><creatorcontrib>Zhang, Shouhai</creatorcontrib><creatorcontrib>Thomas, Sylvie</creatorcontrib><creatorcontrib>Merkel, Tim C</creatorcontrib><creatorcontrib>Jin, Jianyong</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Chemical communications (Cambridge, England)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhang, Jian</au><au>Kang, Hong</au><au>Martin, Jacob</au><au>Zhang, Shouhai</au><au>Thomas, Sylvie</au><au>Merkel, Tim C</au><au>Jin, Jianyong</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>The enhancement of chain rigidity and gas transport performance of polymers of intrinsic microporosity via intramolecular locking of the spiro-carbon</atitle><jtitle>Chemical communications (Cambridge, England)</jtitle><addtitle>Chem Commun (Camb)</addtitle><date>2016-01-01</date><risdate>2016</risdate><volume>52</volume><issue>39</issue><spage>6553</spage><epage>6556</epage><pages>6553-6556</pages><issn>1359-7345</issn><eissn>1364-548X</eissn><abstract>Here, we present a new strategy to improve the rigidity of through the introduction of 8-membered ring locking into the flexible spiro-carbon pivot point to produce an interlocked polycyclic structure. This locked version of shows simultaneous increases in both permeability and selectivity that place it well above the Robeson upper bound for a number of important gas pairs. Molecular modelling demonstrates that the locked version of is much more rigid.</abstract><cop>England</cop><pmid>27103254</pmid><doi>10.1039/c6cc02308h</doi><tpages>4</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1359-7345 |
| ispartof | Chemical communications (Cambridge, England), 2016-01, Vol.52 (39), p.6553-6556 |
| issn | 1359-7345 1364-548X |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1815995756 |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Gas transport Locking Molecular structure Pivots Polymers Rigidity Strategy Upper bounds |
| title | The enhancement of chain rigidity and gas transport performance of polymers of intrinsic microporosity via intramolecular locking of the spiro-carbon |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-17T03%3A32%3A04IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=The%20enhancement%20of%20chain%20rigidity%20and%20gas%20transport%20performance%20of%20polymers%20of%20intrinsic%20microporosity%20via%20intramolecular%20locking%20of%20the%20spiro-carbon&rft.jtitle=Chemical%20communications%20(Cambridge,%20England)&rft.au=Zhang,%20Jian&rft.date=2016-01-01&rft.volume=52&rft.issue=39&rft.spage=6553&rft.epage=6556&rft.pages=6553-6556&rft.issn=1359-7345&rft.eissn=1364-548X&rft_id=info:doi/10.1039/c6cc02308h&rft_dat=%3Cproquest_cross%3E1815995756%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1787478455&rft_id=info:pmid/27103254&rfr_iscdi=true |