Palladium-catalyzed Branch-selective Decarboxylative Allylation Using Ion-paired Ligands

A Pd-catalyzed branch-selective decarboxylative allylation of ketone-derived monosubstituted allylic enol carbonates is reported. The use of an ammonium–phosphine hybrid ligand bearing a non-coordinating anion is crucial for obtaining a branched isomer with high regioselectivity.

Bibliographische Detailangaben

Veröffentlicht in:	Chemistry letters 2016-05, Vol.45 (5), p.552-554
Hauptverfasser:	Hara, Yoshiyuki, Kusano, Yuya, Ohmatsu, Kohsuke, Ooi, Takashi
Format:	Artikel
Sprache:	eng
Schlagworte:	Allyl compounds Anions Bearing Branched Carbonates Chemical reactions Isomers Ligands
Online-Zugang:	Volltext
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