Probing the Biexponential Dynamics of Ring-Opening in 7‑Dehydrocholesterol

Our prior discovery of a novel biexponential photochemical ring-opening in 7-dehydrocholesterol (DHC) to previtamin D3 [ Tang J. Chem. Phys. 2011, 134, 104503 ] is further explored with ultrafast transient absorption spectroscopy, and the results are compared with recently reported high-level theore...

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Veröffentlicht in:	The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory Molecules, spectroscopy, kinetics, environment, & general theory, 2016-08, Vol.120 (33), p.6575-6581
Hauptverfasser:	Smith, Broc D, Spears, Kenneth G, Sension, Roseanne J
Format:	Artikel
Sprache:	eng
Schlagworte:	Dehydrocholesterols - chemistry Molecular Conformation Photochemical Processes Quantum Theory
Online-Zugang:	Volltext
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