Facile Incorporation of Pd(PPh3)2Hal Substituents into Polymethines, Merocyanines, and Perylene Diimides as a Means of Suppressing Intermolecular Interactions

Compounds with polarizable π systems that are susceptible to attack with nucleophiles at C–Hal (Hal = Cl, Br) bonds react with Pd­(PPh3)4 to yield net oxidative addition. X-ray structures show that the resulting Pd­(PPh3)2Hal groups greatly reduce intermolecular π–π interactions. The Pd-functionaliz...

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Veröffentlicht in:	Journal of the American Chemical Society 2016-08, Vol.138 (32), p.10112-10115
Hauptverfasser:	Davydenko, Iryna, Barlow, Stephen, Sharma, Rajesh, Benis, Sepehr, Simon, Janos, Allen, Taylor G, Cooper, Matthew W, Khrustalev, Victor, Jucov, Evgheni V, Castañeda, Raúl, Ordonez, Carlos, Li, Zhong’an, Chi, San-Hui, Jang, Sei-Hum, Parker, Timothy C, Timofeeva, Tatiana V, Perry, Joseph W, Jen, Alex K.-Y, Hagan, David J, Van Stryland, Eric W, Marder, Seth R
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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