Steric and Electronic Influence on Proton-Coupled Electron-Transfer Reactivity of a Mononuclear Mn(III)-Hydroxo Complex

A mononuclear hydroxomanganese­(III) complex was synthesized utilizing the N5 amide-containing ligand 2-[bis­(pyridin-2-ylmethyl)]­amino-N-2-methyl-quinolin-8-yl-acetamidate (dpaq2Me ). This complex is similar to previously reported [MnIII(OH)­(dpaqH)]+ [Inorg. Chem. 2014, 53, 7622–7634] but contain...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Inorganic chemistry 2016-08, Vol.55 (16), p.8110-8120
Hauptverfasser:	Rice, Derek B, Wijeratne, Gayan B, Burr, Andrew D, Parham, Joshua D, Day, Victor W, Jackson, Timothy A
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!