Chitosan-derived carbonaceous material for highly efficient adsorption of chromium (VI) from aqueous solution

A carbonaceous adsorbent for effectively removing Cr(VI) was synthesized by facile hydrothermal carbonization of chitosan (HTC-chitosan). The prepared HTC-chitosan exhibited good stability in acid solution while the amine groups were retained completely after simple and green hydrothermal carbonizat...

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Veröffentlicht in:International journal of biological macromolecules 2016-10, Vol.91, p.443-449
Hauptverfasser: Shen, Feng, Su, Jialei, Zhang, Xiao, Zhang, Keqiang, Qi, Xinhua
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container_title International journal of biological macromolecules
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creator Shen, Feng
Su, Jialei
Zhang, Xiao
Zhang, Keqiang
Qi, Xinhua
description A carbonaceous adsorbent for effectively removing Cr(VI) was synthesized by facile hydrothermal carbonization of chitosan (HTC-chitosan). The prepared HTC-chitosan exhibited good stability in acid solution while the amine groups were retained completely after simple and green hydrothermal carbonization treatment. Structure characteristics of the HTC-chitosan as well as its adsorption behaviors for Cr(VI) in aqueous solution were investigated. Under optimal conditions, the adsorption capacity of the HTC-chitosan for Cr(VI) reached as high as 388.60mgg⿿1, which was much higher than that of other materials reported previously. The prepared HTC-chitosan adsorbent could be reused at least five times with adsorption efficiency more than 92%. These results indicate that HTC-chitosan exhibited great superiority for Cr(VI) adsoption from aqueous solution both in terms of the preparation process and adsorption performance.
doi_str_mv 10.1016/j.ijbiomac.2016.05.103
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subjects Adsorption
Chitosan
Chitosan - chemistry
Chromium - chemistry
Cr(VI)
Hydrothermal carbonization
Water Purification - methods
title Chitosan-derived carbonaceous material for highly efficient adsorption of chromium (VI) from aqueous solution
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