Asymmetric Transfer Hydrogenation of Imines using Alcohol: Efficiency and Selectivity are Influenced by the Hydrogen Donor

The influence of the alcohol, as the hydrogen donor, on the efficiency and selectivity of the asymmetric transfer hydrogenation (ATH) of imines is reported for the first time. This discovery not only leads to a highly enantioselective access to N‐aryl and N‐alkyl amines, but also provides new insigh...

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Veröffentlicht in:	Angewandte Chemie International Edition 2016-08, Vol.55 (33), p.9615-9619
Hauptverfasser:	Pan, Hui-Jie, Zhang, Yao, Shan, Chunhui, Yu, Zhaoyuan, Lan, Yu, Zhao, Yu
Format:	Artikel
Sprache:	eng
Schlagworte:	Alcohol Alcohols Amines Aromatic compounds Computer applications cooperative effects Efficiency Enantiomers enantioselectivity Hydrogen storage Hydrogenation Imines Iridium Selectivity
Online-Zugang:	Volltext
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