Radical Cage Effects: Comparison of Solvent Bulk Viscosity and Microviscosity in Predicting the Recombination Efficiencies of Radical Cage Pairs

This study reports the results of experiments that probed how solvents affect the recombination efficiency (F cP) of geminate radical cage pairs. The macroviscosity of solvents has traditionally been used to make quantitative predictions about F cP, but experiments reported here show that F cP varie...

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Veröffentlicht in:	Journal of the American Chemical Society 2016-08, Vol.138 (30), p.9389-9392
Hauptverfasser:	Barry, Justin T, Berg, Daniel J, Tyler, David R
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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