Comparison of UV photolysis, nanofiltration, and their combination to remove hormones from a drinking water source and reduce endocrine disrupting activity

A sequential water treatment combining low pressure ultraviolet direct photolysis with nanofiltration was evaluated to remove hormones from water, reduce endocrine disrupting activity, and overcome the drawbacks associated with the individual processes (production of a nanofiltration-concentrated re...

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Veröffentlicht in:Environmental science and pollution research international 2016-06, Vol.23 (11), p.11279-11288
Hauptverfasser: Sanches, Sandra, Rodrigues, Alexandre, Cardoso, Vitor V., Benoliel, Maria J., Crespo, João G., Pereira, Vanessa J.
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container_issue 11
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container_title Environmental science and pollution research international
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creator Sanches, Sandra
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Benoliel, Maria J.
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Pereira, Vanessa J.
description A sequential water treatment combining low pressure ultraviolet direct photolysis with nanofiltration was evaluated to remove hormones from water, reduce endocrine disrupting activity, and overcome the drawbacks associated with the individual processes (production of a nanofiltration-concentrated retentate and formation of toxic by-products). 17β-Estradiol, 17α-ethinylestradiol, estrone, estriol, and progesterone were spiked into a real water sample collected after the sedimentation process of a drinking water treatment plant. Even though the nanofiltration process alone showed similar results to the combined treatment in terms of the water quality produced, the combined treatment offered advantage in terms of the load of the retentate and decrease in the endocrine-disrupting activity of the samples. Moreover, the photolysis by-products produced, with higher endocrine disrupting activity than the parent compounds, were effectively retained by the membrane. The combination of direct LP/UV photolysis with nanofiltration is promising for a drinking water utility that needs to cope with sudden punctual discharges or deterioration of the water quality and wants to decrease the levels of chemicals in the nanofiltration retentate.
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subjects Aquatic Pollution
Atmospheric Protection/Air Quality Control/Air Pollution
By products
Chromatography
Combined treatment
Drinking water
Drinking Water - analysis
Drinking Water - standards
Earth and Environmental Science
Ecotoxicology
Endocrine disruptors
Endocrine Disruptors - analysis
Endocrine Disruptors - radiation effects
Endocrine system
Environment
Environmental Chemistry
Environmental Health
Environmental science
Estrogens
Filtration
Hormones
Hormones - analysis
Hormones - radiation effects
Molecular weight
Nanofiltration
Nanotechnology
Oxidation
Photocatalysis
Photolysis
Research Article
Sedimentation & deposition
Studies
Surface water
Ultraviolet radiation
Ultraviolet Rays
Waste Water Technology
Water analysis
Water Management
Water Pollutants, Chemical - analysis
Water Pollutants, Chemical - radiation effects
Water Pollution Control
Water Purification - methods
Water Quality
Water sampling
Water treatment
Water treatment plants
title Comparison of UV photolysis, nanofiltration, and their combination to remove hormones from a drinking water source and reduce endocrine disrupting activity
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