Improving the synthesis of phenolic polymer using Coprinus cinereus peroxidase mutant Phe230Ala

•The radical-stable mutant of CiP (F230A) was applied to the phenol polymerization.•The F230A mutant produced a 5.6 fold-higher molecular weight of phenol polymer.•The organic solvents affected the polymerization yield of CiP proteins.•The F230A mutant exhibited lower stability in organic solvents t...

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