Effect of soil type and organic manure on adsorption–desorption of flubendiamide
Laboratory study on adsorption–desorption of flubendiamide was conducted in two soil types, varying in their physical and chemical properties, by batch equilibrium method. After 4 h of equilibrium time, adsorption of flubendiamide on soil matrix exhibited moderately low rate of accumulation with 4.5...
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| Veröffentlicht in: | Environmental monitoring and assessment 2015-07, Vol.187 (7), p.403-403, Article 403 |
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| description | Laboratory study on adsorption–desorption of flubendiamide was conducted in two soil types, varying in their physical and chemical properties, by batch equilibrium method. After 4 h of equilibrium time, adsorption of flubendiamide on soil matrix exhibited moderately low rate of accumulation with 4.52 ± 0.21 % in red soil and low rate with 3.55 ± 0.21 % in black soil. After amending soils with organic manure, adsorption percentage increased to 6.42 ± 0.21 % in red soil and (4.18 ± 0.21 %) in black soil indicating that amendment significantly increased sorption. Variation in sorption affinities of the soils as indicated by distribution coefficient (
K
d
) for sorption was in the range of 2.98–4.32, 4.91–6.64, 1.04–1.45 and 1.92–2.81 ml/g for red soil, organic manure-treated red soil, black soil and organic manure-treated black soil, respectively. Desorption was slightly slower than adsorption indicating a hysteresis effect having hysteresis coefficient ranges between 0.023 and 0.149 in two test soils. The adsorption data for the insecticide fitted well the Freundlich equation. Results revealed that adsorption–desorption was influenced by soil types and showed that the maximum sorption and minimum desorption of the insecticide was observed in soils with higher organic carbon and clay content. It can be inferred that crystal lattice of the clay soil plays a significant role in flubendiamide adsorption and desorption. Adsorption was lower at acidic pH and gradually increased towards alkaline pH. As this insecticide is poorly sorbed in the two Indian soil types, there may be a possibility of their leaching to lower soil profiles. |
| doi_str_mv | 10.1007/s10661-015-4623-2 |
| format | Article |
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K
d
) for sorption was in the range of 2.98–4.32, 4.91–6.64, 1.04–1.45 and 1.92–2.81 ml/g for red soil, organic manure-treated red soil, black soil and organic manure-treated black soil, respectively. Desorption was slightly slower than adsorption indicating a hysteresis effect having hysteresis coefficient ranges between 0.023 and 0.149 in two test soils. The adsorption data for the insecticide fitted well the Freundlich equation. Results revealed that adsorption–desorption was influenced by soil types and showed that the maximum sorption and minimum desorption of the insecticide was observed in soils with higher organic carbon and clay content. It can be inferred that crystal lattice of the clay soil plays a significant role in flubendiamide adsorption and desorption. Adsorption was lower at acidic pH and gradually increased towards alkaline pH. As this insecticide is poorly sorbed in the two Indian soil types, there may be a possibility of their leaching to lower soil profiles.</description><identifier>ISSN: 0167-6369</identifier><identifier>EISSN: 1573-2959</identifier><identifier>DOI: 10.1007/s10661-015-4623-2</identifier><identifier>PMID: 26041063</identifier><language>eng</language><publisher>Cham: Springer International Publishing</publisher><subject>Acidic soils ; Acids ; Adsorption ; Alkaline soils ; Aluminum Silicates - chemistry ; Atmospheric Protection/Air Quality Control/Air Pollution ; Benzamides - chemistry ; Carbon ; Carbon - chemistry ; Chemical properties ; Clay ; Crop science ; Desorption ; Earth and Environmental Science ; Ecology ; Ecotoxicology ; Environment ; Environmental Management ; Environmental monitoring ; Hysteresis ; India ; Insecticides ; Insecticides - chemistry ; Laboratories ; Leaching ; Manure ; Manures ; Monitoring/Environmental Analysis ; Organic carbon ; Organic fertilizers ; Organic soils ; Organic wastes ; Pesticides ; Soil - chemistry ; Soil Pollutants - chemistry ; Soil profiles ; Soil testing ; Soil types ; Soils ; Sorption ; Sulfones - chemistry</subject><ispartof>Environmental monitoring and assessment, 2015-07, Vol.187 (7), p.403-403, Article 403</ispartof><rights>Springer International Publishing Switzerland 2015</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c405t-62cbde77ffbd7dbb209374cc963ffeb14ddf7e2dd19443300a509228fe93773a3</citedby><cites>FETCH-LOGICAL-c405t-62cbde77ffbd7dbb209374cc963ffeb14ddf7e2dd19443300a509228fe93773a3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10661-015-4623-2$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10661-015-4623-2$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/26041063$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Das, Shaon Kumar</creatorcontrib><creatorcontrib>Mukherjee, Irani</creatorcontrib><creatorcontrib>Kumar, Aman</creatorcontrib><title>Effect of soil type and organic manure on adsorption–desorption of flubendiamide</title><title>Environmental monitoring and assessment</title><addtitle>Environ Monit Assess</addtitle><addtitle>Environ Monit Assess</addtitle><description>Laboratory study on adsorption–desorption of flubendiamide was conducted in two soil types, varying in their physical and chemical properties, by batch equilibrium method. After 4 h of equilibrium time, adsorption of flubendiamide on soil matrix exhibited moderately low rate of accumulation with 4.52 ± 0.21 % in red soil and low rate with 3.55 ± 0.21 % in black soil. After amending soils with organic manure, adsorption percentage increased to 6.42 ± 0.21 % in red soil and (4.18 ± 0.21 %) in black soil indicating that amendment significantly increased sorption. Variation in sorption affinities of the soils as indicated by distribution coefficient (
K
d
) for sorption was in the range of 2.98–4.32, 4.91–6.64, 1.04–1.45 and 1.92–2.81 ml/g for red soil, organic manure-treated red soil, black soil and organic manure-treated black soil, respectively. Desorption was slightly slower than adsorption indicating a hysteresis effect having hysteresis coefficient ranges between 0.023 and 0.149 in two test soils. The adsorption data for the insecticide fitted well the Freundlich equation. Results revealed that adsorption–desorption was influenced by soil types and showed that the maximum sorption and minimum desorption of the insecticide was observed in soils with higher organic carbon and clay content. It can be inferred that crystal lattice of the clay soil plays a significant role in flubendiamide adsorption and desorption. Adsorption was lower at acidic pH and gradually increased towards alkaline pH. As this insecticide is poorly sorbed in the two Indian soil types, there may be a possibility of their leaching to lower soil profiles.</description><subject>Acidic soils</subject><subject>Acids</subject><subject>Adsorption</subject><subject>Alkaline soils</subject><subject>Aluminum Silicates - chemistry</subject><subject>Atmospheric Protection/Air Quality Control/Air Pollution</subject><subject>Benzamides - chemistry</subject><subject>Carbon</subject><subject>Carbon - chemistry</subject><subject>Chemical properties</subject><subject>Clay</subject><subject>Crop science</subject><subject>Desorption</subject><subject>Earth and Environmental Science</subject><subject>Ecology</subject><subject>Ecotoxicology</subject><subject>Environment</subject><subject>Environmental Management</subject><subject>Environmental monitoring</subject><subject>Hysteresis</subject><subject>India</subject><subject>Insecticides</subject><subject>Insecticides - chemistry</subject><subject>Laboratories</subject><subject>Leaching</subject><subject>Manure</subject><subject>Manures</subject><subject>Monitoring/Environmental Analysis</subject><subject>Organic carbon</subject><subject>Organic fertilizers</subject><subject>Organic soils</subject><subject>Organic wastes</subject><subject>Pesticides</subject><subject>Soil - chemistry</subject><subject>Soil Pollutants - chemistry</subject><subject>Soil profiles</subject><subject>Soil testing</subject><subject>Soil types</subject><subject>Soils</subject><subject>Sorption</subject><subject>Sulfones - chemistry</subject><issn>0167-6369</issn><issn>1573-2959</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><sourceid>GNUQQ</sourceid><recordid>eNqFkctKxDAYhYMoOo4-gBspuHFT_XNpMlmKjBcQBNF1SJtk6NAmY9Iu3PkOvqFPYoZREUFcJSHfOX9yDkJHGM4wgDhPGDjHJeCqZJzQkmyhCa5E3shKbqMJYC5KTrncQ_spLQFACiZ30R7hwLKWTtDD3DnbDEVwRQptVwwvK1tob4oQF9q3TdFrP0ZbBF9ok0JcDW3w769vxn4d1lLXjbX1ptV9a-wB2nG6S_bwc52ip6v54-VNeXd_fXt5cVc2DKqh5KSpjRXCudoIU9cEJBWsaSSn-Uk1ZsY4YYkxWDJGKYCuQBIyczZzgmo6Racb31UMz6NNg-rb1Niu096GMSk8gxkVlODqf5TPOMvh5BCn6OQXugxj9PkjmcqxckYYzhTeUE0MKUXr1Cq2vY4vCoNad6M23ajcjVp3o9bOx5_OY91b8634KiMDZAOkfOUXNv4Y_afrB5hmmdU</recordid><startdate>20150701</startdate><enddate>20150701</enddate><creator>Das, Shaon Kumar</creator><creator>Mukherjee, Irani</creator><creator>Kumar, Aman</creator><general>Springer International Publishing</general><general>Springer Nature B.V</general><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>7QH</scope><scope>7QL</scope><scope>7SN</scope><scope>7ST</scope><scope>7T7</scope><scope>7TG</scope><scope>7TN</scope><scope>7U7</scope><scope>7UA</scope><scope>7WY</scope><scope>7WZ</scope><scope>7X7</scope><scope>7XB</scope><scope>87Z</scope><scope>88E</scope><scope>88I</scope><scope>8AO</scope><scope>8C1</scope><scope>8FD</scope><scope>8FI</scope><scope>8FJ</scope><scope>8FK</scope><scope>8FL</scope><scope>ABUWG</scope><scope>AEUYN</scope><scope>AFKRA</scope><scope>ATCPS</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BEZIV</scope><scope>BHPHI</scope><scope>C1K</scope><scope>CCPQU</scope><scope>DWQXO</scope><scope>F1W</scope><scope>FR3</scope><scope>FRNLG</scope><scope>FYUFA</scope><scope>F~G</scope><scope>GHDGH</scope><scope>GNUQQ</scope><scope>H97</scope><scope>HCIFZ</scope><scope>K60</scope><scope>K6~</scope><scope>K9.</scope><scope>KL.</scope><scope>L.-</scope><scope>L.G</scope><scope>M0C</scope><scope>M0S</scope><scope>M1P</scope><scope>M2P</scope><scope>M7N</scope><scope>P64</scope><scope>PATMY</scope><scope>PQBIZ</scope><scope>PQBZA</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PYCSY</scope><scope>Q9U</scope><scope>SOI</scope><scope>7X8</scope><scope>7TV</scope></search><sort><creationdate>20150701</creationdate><title>Effect of soil type and organic manure on adsorption–desorption of flubendiamide</title><author>Das, Shaon Kumar ; Mukherjee, Irani ; Kumar, Aman</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c405t-62cbde77ffbd7dbb209374cc963ffeb14ddf7e2dd19443300a509228fe93773a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>Acidic soils</topic><topic>Acids</topic><topic>Adsorption</topic><topic>Alkaline soils</topic><topic>Aluminum Silicates - chemistry</topic><topic>Atmospheric Protection/Air Quality Control/Air Pollution</topic><topic>Benzamides - chemistry</topic><topic>Carbon</topic><topic>Carbon - chemistry</topic><topic>Chemical properties</topic><topic>Clay</topic><topic>Crop science</topic><topic>Desorption</topic><topic>Earth and Environmental Science</topic><topic>Ecology</topic><topic>Ecotoxicology</topic><topic>Environment</topic><topic>Environmental Management</topic><topic>Environmental monitoring</topic><topic>Hysteresis</topic><topic>India</topic><topic>Insecticides</topic><topic>Insecticides - chemistry</topic><topic>Laboratories</topic><topic>Leaching</topic><topic>Manure</topic><topic>Manures</topic><topic>Monitoring/Environmental Analysis</topic><topic>Organic carbon</topic><topic>Organic fertilizers</topic><topic>Organic soils</topic><topic>Organic wastes</topic><topic>Pesticides</topic><topic>Soil - chemistry</topic><topic>Soil Pollutants - chemistry</topic><topic>Soil profiles</topic><topic>Soil testing</topic><topic>Soil types</topic><topic>Soils</topic><topic>Sorption</topic><topic>Sulfones - 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Academic</collection><collection>Pollution Abstracts</collection><jtitle>Environmental monitoring and assessment</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Das, Shaon Kumar</au><au>Mukherjee, Irani</au><au>Kumar, Aman</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Effect of soil type and organic manure on adsorption–desorption of flubendiamide</atitle><jtitle>Environmental monitoring and assessment</jtitle><stitle>Environ Monit Assess</stitle><addtitle>Environ Monit Assess</addtitle><date>2015-07-01</date><risdate>2015</risdate><volume>187</volume><issue>7</issue><spage>403</spage><epage>403</epage><pages>403-403</pages><artnum>403</artnum><issn>0167-6369</issn><eissn>1573-2959</eissn><abstract>Laboratory study on adsorption–desorption of flubendiamide was conducted in two soil types, varying in their physical and chemical properties, by batch equilibrium method. After 4 h of equilibrium time, adsorption of flubendiamide on soil matrix exhibited moderately low rate of accumulation with 4.52 ± 0.21 % in red soil and low rate with 3.55 ± 0.21 % in black soil. After amending soils with organic manure, adsorption percentage increased to 6.42 ± 0.21 % in red soil and (4.18 ± 0.21 %) in black soil indicating that amendment significantly increased sorption. Variation in sorption affinities of the soils as indicated by distribution coefficient (
K
d
) for sorption was in the range of 2.98–4.32, 4.91–6.64, 1.04–1.45 and 1.92–2.81 ml/g for red soil, organic manure-treated red soil, black soil and organic manure-treated black soil, respectively. Desorption was slightly slower than adsorption indicating a hysteresis effect having hysteresis coefficient ranges between 0.023 and 0.149 in two test soils. The adsorption data for the insecticide fitted well the Freundlich equation. Results revealed that adsorption–desorption was influenced by soil types and showed that the maximum sorption and minimum desorption of the insecticide was observed in soils with higher organic carbon and clay content. It can be inferred that crystal lattice of the clay soil plays a significant role in flubendiamide adsorption and desorption. Adsorption was lower at acidic pH and gradually increased towards alkaline pH. As this insecticide is poorly sorbed in the two Indian soil types, there may be a possibility of their leaching to lower soil profiles.</abstract><cop>Cham</cop><pub>Springer International Publishing</pub><pmid>26041063</pmid><doi>10.1007/s10661-015-4623-2</doi><tpages>1</tpages></addata></record> |
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| subjects | Acidic soils Acids Adsorption Alkaline soils Aluminum Silicates - chemistry Atmospheric Protection/Air Quality Control/Air Pollution Benzamides - chemistry Carbon Carbon - chemistry Chemical properties Clay Crop science Desorption Earth and Environmental Science Ecology Ecotoxicology Environment Environmental Management Environmental monitoring Hysteresis India Insecticides Insecticides - chemistry Laboratories Leaching Manure Manures Monitoring/Environmental Analysis Organic carbon Organic fertilizers Organic soils Organic wastes Pesticides Soil - chemistry Soil Pollutants - chemistry Soil profiles Soil testing Soil types Soils Sorption Sulfones - chemistry |
| title | Effect of soil type and organic manure on adsorption–desorption of flubendiamide |
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