Distribution of polycyclic aromatic hydrocarbons in sediments of Akaki River, Lake Awassa, and Lake Ziway, Ethiopia
The quantification of 14 polycyclic aromatic hydrocarbons (PAHs) was carried out in sediment samples collected from Akaki River, Lake Awassa, and Lake Ziway, Ethiopia. The concentration of PAHs in the samples was determined using gas chromatography-mass spectrometry (GC-MS) in selected ion monitorin...
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creator | Mekonnen, Kebede Nigussie Chandravanshi, Bhagwan Singh Redi-Abshiro, Mesfin Ambushe, Abayneh Ataro McCrindle, Robert Ian Moyo, Stanley |
description | The quantification of 14 polycyclic aromatic hydrocarbons (PAHs) was carried out in sediment samples collected from Akaki River, Lake Awassa, and Lake Ziway, Ethiopia. The concentration of PAHs in the samples was determined using gas chromatography-mass spectrometry (GC-MS) in selected ion monitoring (SIM) mode, after microwave-assisted extraction (MAE), using acetone/
n
-hexane (1:1,
v
/
v
) mixture. The accuracy of the method was determined by extracting and analyzing New York/New Jersey waterway sediment standard reference material (SRM 1944). The measured concentrations of PAHs in SRM 1944 agreed well with the certified values. In samples from Akaki River, Lake Awassa, and Lake Ziway, the total content of PAHs determined ranged from 0 to 3070 ng/g (average 534 ng/g), 24.9 to 413 ng/g (average 169 ng/g), and 15.0 to 305 ng/g (average 175 ng/g), respectively. Source ratios indicated that the PAHs were mainly from petrogenic origin. Sediments from all sampling sites indicated negligible levels of toxicity with no risk of adverse biological effects. |
doi_str_mv | 10.1007/s10661-015-4669-1 |
format | Article |
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n
-hexane (1:1,
v
/
v
) mixture. The accuracy of the method was determined by extracting and analyzing New York/New Jersey waterway sediment standard reference material (SRM 1944). The measured concentrations of PAHs in SRM 1944 agreed well with the certified values. In samples from Akaki River, Lake Awassa, and Lake Ziway, the total content of PAHs determined ranged from 0 to 3070 ng/g (average 534 ng/g), 24.9 to 413 ng/g (average 169 ng/g), and 15.0 to 305 ng/g (average 175 ng/g), respectively. Source ratios indicated that the PAHs were mainly from petrogenic origin. Sediments from all sampling sites indicated negligible levels of toxicity with no risk of adverse biological effects.</description><identifier>ISSN: 0167-6369</identifier><identifier>EISSN: 1573-2959</identifier><identifier>DOI: 10.1007/s10661-015-4669-1</identifier><identifier>PMID: 26122125</identifier><language>eng</language><publisher>Cham: Springer International Publishing</publisher><subject>Atmospheric Protection/Air Quality Control/Air Pollution ; Biological effects ; Chemical Fractionation - methods ; Chemistry ; Chromatography ; Earth and Environmental Science ; Ecology ; Ecotoxicology ; Environment ; Environmental cleanup ; Environmental Management ; Environmental Monitoring ; Ethiopia ; Gas chromatography ; Gas Chromatography-Mass Spectrometry ; Geologic Sediments - analysis ; Hexanes ; Lakes ; Lakes - analysis ; Mass Spectrometry ; Mass spectroscopy ; Microwaves ; Monitoring/Environmental Analysis ; n-Hexane ; Polycyclic aromatic hydrocarbons ; Polycyclic Aromatic Hydrocarbons - analysis ; Polycyclic Aromatic Hydrocarbons - toxicity ; Rivers ; Scientific imaging ; Sediment samplers ; Sediments ; Toxicity ; Water analysis ; Water Pollutants, Chemical - analysis</subject><ispartof>Environmental monitoring and assessment, 2015-07, Vol.187 (7), p.474-13, Article 474</ispartof><rights>Springer International Publishing Switzerland 2015</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c405t-37b4ce4f82115a4b1ca96fea87583dd7128d4e720c06bc0dddf5fbcfbbc749013</citedby><cites>FETCH-LOGICAL-c405t-37b4ce4f82115a4b1ca96fea87583dd7128d4e720c06bc0dddf5fbcfbbc749013</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10661-015-4669-1$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10661-015-4669-1$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/26122125$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Mekonnen, Kebede Nigussie</creatorcontrib><creatorcontrib>Chandravanshi, Bhagwan Singh</creatorcontrib><creatorcontrib>Redi-Abshiro, Mesfin</creatorcontrib><creatorcontrib>Ambushe, Abayneh Ataro</creatorcontrib><creatorcontrib>McCrindle, Robert Ian</creatorcontrib><creatorcontrib>Moyo, Stanley</creatorcontrib><title>Distribution of polycyclic aromatic hydrocarbons in sediments of Akaki River, Lake Awassa, and Lake Ziway, Ethiopia</title><title>Environmental monitoring and assessment</title><addtitle>Environ Monit Assess</addtitle><addtitle>Environ Monit Assess</addtitle><description>The quantification of 14 polycyclic aromatic hydrocarbons (PAHs) was carried out in sediment samples collected from Akaki River, Lake Awassa, and Lake Ziway, Ethiopia. The concentration of PAHs in the samples was determined using gas chromatography-mass spectrometry (GC-MS) in selected ion monitoring (SIM) mode, after microwave-assisted extraction (MAE), using acetone/
n
-hexane (1:1,
v
/
v
) mixture. The accuracy of the method was determined by extracting and analyzing New York/New Jersey waterway sediment standard reference material (SRM 1944). The measured concentrations of PAHs in SRM 1944 agreed well with the certified values. In samples from Akaki River, Lake Awassa, and Lake Ziway, the total content of PAHs determined ranged from 0 to 3070 ng/g (average 534 ng/g), 24.9 to 413 ng/g (average 169 ng/g), and 15.0 to 305 ng/g (average 175 ng/g), respectively. Source ratios indicated that the PAHs were mainly from petrogenic origin. Sediments from all sampling sites indicated negligible levels of toxicity with no risk of adverse biological effects.</description><subject>Atmospheric Protection/Air Quality Control/Air Pollution</subject><subject>Biological effects</subject><subject>Chemical Fractionation - methods</subject><subject>Chemistry</subject><subject>Chromatography</subject><subject>Earth and Environmental Science</subject><subject>Ecology</subject><subject>Ecotoxicology</subject><subject>Environment</subject><subject>Environmental cleanup</subject><subject>Environmental Management</subject><subject>Environmental Monitoring</subject><subject>Ethiopia</subject><subject>Gas chromatography</subject><subject>Gas Chromatography-Mass Spectrometry</subject><subject>Geologic Sediments - analysis</subject><subject>Hexanes</subject><subject>Lakes</subject><subject>Lakes - analysis</subject><subject>Mass Spectrometry</subject><subject>Mass spectroscopy</subject><subject>Microwaves</subject><subject>Monitoring/Environmental Analysis</subject><subject>n-Hexane</subject><subject>Polycyclic aromatic hydrocarbons</subject><subject>Polycyclic Aromatic Hydrocarbons - 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The concentration of PAHs in the samples was determined using gas chromatography-mass spectrometry (GC-MS) in selected ion monitoring (SIM) mode, after microwave-assisted extraction (MAE), using acetone/
n
-hexane (1:1,
v
/
v
) mixture. The accuracy of the method was determined by extracting and analyzing New York/New Jersey waterway sediment standard reference material (SRM 1944). The measured concentrations of PAHs in SRM 1944 agreed well with the certified values. In samples from Akaki River, Lake Awassa, and Lake Ziway, the total content of PAHs determined ranged from 0 to 3070 ng/g (average 534 ng/g), 24.9 to 413 ng/g (average 169 ng/g), and 15.0 to 305 ng/g (average 175 ng/g), respectively. Source ratios indicated that the PAHs were mainly from petrogenic origin. Sediments from all sampling sites indicated negligible levels of toxicity with no risk of adverse biological effects.</abstract><cop>Cham</cop><pub>Springer International Publishing</pub><pmid>26122125</pmid><doi>10.1007/s10661-015-4669-1</doi><tpages>13</tpages></addata></record> |
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subjects | Atmospheric Protection/Air Quality Control/Air Pollution Biological effects Chemical Fractionation - methods Chemistry Chromatography Earth and Environmental Science Ecology Ecotoxicology Environment Environmental cleanup Environmental Management Environmental Monitoring Ethiopia Gas chromatography Gas Chromatography-Mass Spectrometry Geologic Sediments - analysis Hexanes Lakes Lakes - analysis Mass Spectrometry Mass spectroscopy Microwaves Monitoring/Environmental Analysis n-Hexane Polycyclic aromatic hydrocarbons Polycyclic Aromatic Hydrocarbons - analysis Polycyclic Aromatic Hydrocarbons - toxicity Rivers Scientific imaging Sediment samplers Sediments Toxicity Water analysis Water Pollutants, Chemical - analysis |
title | Distribution of polycyclic aromatic hydrocarbons in sediments of Akaki River, Lake Awassa, and Lake Ziway, Ethiopia |
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