Distribution of polycyclic aromatic hydrocarbons in sediments of Akaki River, Lake Awassa, and Lake Ziway, Ethiopia

The quantification of 14 polycyclic aromatic hydrocarbons (PAHs) was carried out in sediment samples collected from Akaki River, Lake Awassa, and Lake Ziway, Ethiopia. The concentration of PAHs in the samples was determined using gas chromatography-mass spectrometry (GC-MS) in selected ion monitorin...

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Veröffentlicht in:Environmental monitoring and assessment 2015-07, Vol.187 (7), p.474-13, Article 474
Hauptverfasser: Mekonnen, Kebede Nigussie, Chandravanshi, Bhagwan Singh, Redi-Abshiro, Mesfin, Ambushe, Abayneh Ataro, McCrindle, Robert Ian, Moyo, Stanley
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container_end_page 13
container_issue 7
container_start_page 474
container_title Environmental monitoring and assessment
container_volume 187
creator Mekonnen, Kebede Nigussie
Chandravanshi, Bhagwan Singh
Redi-Abshiro, Mesfin
Ambushe, Abayneh Ataro
McCrindle, Robert Ian
Moyo, Stanley
description The quantification of 14 polycyclic aromatic hydrocarbons (PAHs) was carried out in sediment samples collected from Akaki River, Lake Awassa, and Lake Ziway, Ethiopia. The concentration of PAHs in the samples was determined using gas chromatography-mass spectrometry (GC-MS) in selected ion monitoring (SIM) mode, after microwave-assisted extraction (MAE), using acetone/ n -hexane (1:1, v / v ) mixture. The accuracy of the method was determined by extracting and analyzing New York/New Jersey waterway sediment standard reference material (SRM 1944). The measured concentrations of PAHs in SRM 1944 agreed well with the certified values. In samples from Akaki River, Lake Awassa, and Lake Ziway, the total content of PAHs determined ranged from 0 to 3070 ng/g (average 534 ng/g), 24.9 to 413 ng/g (average 169 ng/g), and 15.0 to 305 ng/g (average 175 ng/g), respectively. Source ratios indicated that the PAHs were mainly from petrogenic origin. Sediments from all sampling sites indicated negligible levels of toxicity with no risk of adverse biological effects.
doi_str_mv 10.1007/s10661-015-4669-1
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subjects Atmospheric Protection/Air Quality Control/Air Pollution
Biological effects
Chemical Fractionation - methods
Chemistry
Chromatography
Earth and Environmental Science
Ecology
Ecotoxicology
Environment
Environmental cleanup
Environmental Management
Environmental Monitoring
Ethiopia
Gas chromatography
Gas Chromatography-Mass Spectrometry
Geologic Sediments - analysis
Hexanes
Lakes
Lakes - analysis
Mass Spectrometry
Mass spectroscopy
Microwaves
Monitoring/Environmental Analysis
n-Hexane
Polycyclic aromatic hydrocarbons
Polycyclic Aromatic Hydrocarbons - analysis
Polycyclic Aromatic Hydrocarbons - toxicity
Rivers
Scientific imaging
Sediment samplers
Sediments
Toxicity
Water analysis
Water Pollutants, Chemical - analysis
title Distribution of polycyclic aromatic hydrocarbons in sediments of Akaki River, Lake Awassa, and Lake Ziway, Ethiopia
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