Seasonal and event-scale variations in solute chemistry for four Sierra Nevada catchments

Hydrobiogeochemical processes controlling stream water chemistry were examined in four small (

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Veröffentlicht in:Journal of hydrology (Amsterdam) 2001-09, Vol.250 (1), p.106-121
Hauptverfasser: Holloway, JoAnn M, Dahlgren, Randy A
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container_title Journal of hydrology (Amsterdam)
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creator Holloway, JoAnn M
Dahlgren, Randy A
description Hydrobiogeochemical processes controlling stream water chemistry were examined in four small (
doi_str_mv 10.1016/S0022-1694(01)00424-3
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The Mediterranean climate with its cool/wet and hot/dry cycle produces strong seasonal patterns in hydrological, biological and geochemical processes. Stream water solutes fall into three general groups according to seasonal fluctuation in concentration: strong, rainy season minimum–dry season maximum (Cl −, SO 4 2−, base cations); weak, rainy season minimum–dry season maximum (Si); and rainy season maximum–dry season minimum (NO 3 − and K +). Solute dynamics in soil solutions and stream water suggest that mixing of drainage waters from bedrock and soil sources regulate stream water solute concentrations. Patterns are further altered by the leaching of solutes accumulated in the soil over the summer period of desiccation and the temporal discoupling of nutrient cycles that occurs due to differences in the timing between vegetation growth (late spring) and leaching (early winter). Solute concentrations are remarkably similar between watersheds with varying bedrock types, with the exception of nitrate, sulfate and bicarbonate. Three watersheds have nitrogen-bearing metasedimentary bedrock that contributes to elevated nitrate concentrations in stream waters. Watersheds whose bedrock includes mineralized veins of sulfide and carbonate minerals similarly have greater sulfate and bicarbonate concentrations in stream water. 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The Mediterranean climate with its cool/wet and hot/dry cycle produces strong seasonal patterns in hydrological, biological and geochemical processes. Stream water solutes fall into three general groups according to seasonal fluctuation in concentration: strong, rainy season minimum–dry season maximum (Cl −, SO 4 2−, base cations); weak, rainy season minimum–dry season maximum (Si); and rainy season maximum–dry season minimum (NO 3 − and K +). Solute dynamics in soil solutions and stream water suggest that mixing of drainage waters from bedrock and soil sources regulate stream water solute concentrations. Patterns are further altered by the leaching of solutes accumulated in the soil over the summer period of desiccation and the temporal discoupling of nutrient cycles that occurs due to differences in the timing between vegetation growth (late spring) and leaching (early winter). Solute concentrations are remarkably similar between watersheds with varying bedrock types, with the exception of nitrate, sulfate and bicarbonate. Three watersheds have nitrogen-bearing metasedimentary bedrock that contributes to elevated nitrate concentrations in stream waters. Watersheds whose bedrock includes mineralized veins of sulfide and carbonate minerals similarly have greater sulfate and bicarbonate concentrations in stream water. Hydrobiogeochemical processes are highly dynamic at the seasonal and storm-event temporal scales and spatially complex at the watershed scale making management of stream water chemical composition, such as nitrate concentrations, very challenging.</description><subject>Biogeochemistry</subject><subject>Earth sciences</subject><subject>Earth, ocean, space</subject><subject>Exact sciences and technology</subject><subject>Hydrologic cycle</subject><subject>Hydrology</subject><subject>Hydrology. 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subjects Biogeochemistry
Earth sciences
Earth, ocean, space
Exact sciences and technology
Hydrologic cycle
Hydrology
Hydrology. Hydrogeology
Soil solution
Stream
USA, California, Sierra Nevada Mts
Water–rock interaction
title Seasonal and event-scale variations in solute chemistry for four Sierra Nevada catchments
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