Permeation properties of polymeric membranes for biohydrogen purification
Palm Oil Mill Effluent (POME), generated from the oil extraction process, possesses high Biochemical Oxygen Demand (BOD) and Chemical Oxygen Demand (COD). POME can be treated in an efficient bioreactor under controlled conditions to produce high value biohydrogen mixture containing CO2. The H2 exist...
Gespeichert in:
Veröffentlicht in: | International journal of hydrogen energy 2016-02, Vol.41 (7), p.4474-4488 |
---|---|
Hauptverfasser: | , , , , |
Format: | Artikel |
Sprache: | eng |
Schlagworte: | |
Online-Zugang: | Volltext |
Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
container_end_page | 4488 |
---|---|
container_issue | 7 |
container_start_page | 4474 |
container_title | International journal of hydrogen energy |
container_volume | 41 |
creator | Mohamad, Izzati Nadia Rohani, Rosiah Mastar@Masdar, Mohd. Shahbudin Mohd Nor, Mohd Tusirin Md. Jahim, Jamaliah |
description | Palm Oil Mill Effluent (POME), generated from the oil extraction process, possesses high Biochemical Oxygen Demand (BOD) and Chemical Oxygen Demand (COD). POME can be treated in an efficient bioreactor under controlled conditions to produce high value biohydrogen mixture containing CO2. The H2 existence in the valuable gas mixture (in a reasonable quantity) could be used as a clean energy source for renewable energy i.e., in hydrogen fuel cell. CO2 presence in fuel cell causes CO2 poisoning and affects its performance. Therefore, the purification of H2 from CO2 produced from POME fermentation is desirable to ensure that an appropriate purity of H2 is achieved. This work focused on the performance of gas membrane separation technology; by specifically using two different polymeric membranes, namely polysulfone (PSF) and polydimethylsiloxane (PDMS). Based on the results obtained, the selectivity for H2/CO2 was achieved using PSF membranes; with the values obtained of 1.54–3.32 at a pressure of 1–8 bar. This result shows that PSF membranes have better performance for H2 purification than PDMS membranes. This is supported by the analysis of the membranes after the test, which includes Fourier Transform Infrared (FTIR), Scanning Electron Microscopy (SEM) and Atomic Force Microscopy (AFM) analyses. PSF membranes showed no changes on their FTIR spectra after permeation, while PDMS membranes, of 75 and 200 μm thicknesses, recorded higher transmittance of their spectra after permeation. The flexibility of the PDMS membranes is evidence of more permeance of the hydrogen mixture that leads to less selectivity of H2/CO2. Meanwhile, SEM and AFM analyses proved the morphology effects; which include changes of pore size distribution cross-section, membrane thickness and surface roughness, after permeation of the applied pressure from 1 to 8 bar, which was possibly due to the compaction effect.
•Fermentation of Palm Oil Mill Effluent (POME) in oil palm industry produced BioH2.•BioH2 upgrading from H2/CO2 mixture was conducted using PSF and PDMS membranes.•PSF membranes gave reasonable bioH2 permeance and selectivity at low pressure.•PSF membrane system can be coupled with POME bioreactor for bioH2 upgrading. |
doi_str_mv | 10.1016/j.ijhydene.2015.08.002 |
format | Article |
fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1808128848</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><els_id>S0360319915020078</els_id><sourcerecordid>1808128848</sourcerecordid><originalsourceid>FETCH-LOGICAL-c452t-afc1dea3739e6047bf369cd7f752ff8afd3b90243817e66fdf79931118f099703</originalsourceid><addsrcrecordid>eNqFkE9LxDAQxYMouK5-BenRS-uk6TbJTVn8s7CgBz2HNJ1oStvUpCvstze6evY0MLzfmzePkEsKBQVaX3eF6973LY5YlEBXBYgCoDwiCyq4zFkl-DFZAKshZ1TKU3IWYwdAOVRyQTbPGAbUs_NjNgU_YZgdxszbbPL9fsDgTDbg0AQ9prX1IWucT9eCf8NE7IKzzvzg5-TE6j7ixe9cktf7u5f1Y759etisb7e5qVblnGtraIuacSaxhoo3ltXStNzyVWmt0LZljYSyYoJyrGvbWi4lo5QKC1JyYEtydfBNcT92GGc1uGiw71NCv4uKChC0FKISSVofpCb4GANaNQU36LBXFNR3d6pTf92p7-4UCJW6S-DNAcT0yKfDoKJxOBpsXUAzq9a7_yy-ALimfL4</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1808128848</pqid></control><display><type>article</type><title>Permeation properties of polymeric membranes for biohydrogen purification</title><source>Access via ScienceDirect (Elsevier)</source><creator>Mohamad, Izzati Nadia ; Rohani, Rosiah ; Mastar@Masdar, Mohd. Shahbudin ; Mohd Nor, Mohd Tusirin ; Md. Jahim, Jamaliah</creator><creatorcontrib>Mohamad, Izzati Nadia ; Rohani, Rosiah ; Mastar@Masdar, Mohd. Shahbudin ; Mohd Nor, Mohd Tusirin ; Md. Jahim, Jamaliah</creatorcontrib><description>Palm Oil Mill Effluent (POME), generated from the oil extraction process, possesses high Biochemical Oxygen Demand (BOD) and Chemical Oxygen Demand (COD). POME can be treated in an efficient bioreactor under controlled conditions to produce high value biohydrogen mixture containing CO2. The H2 existence in the valuable gas mixture (in a reasonable quantity) could be used as a clean energy source for renewable energy i.e., in hydrogen fuel cell. CO2 presence in fuel cell causes CO2 poisoning and affects its performance. Therefore, the purification of H2 from CO2 produced from POME fermentation is desirable to ensure that an appropriate purity of H2 is achieved. This work focused on the performance of gas membrane separation technology; by specifically using two different polymeric membranes, namely polysulfone (PSF) and polydimethylsiloxane (PDMS). Based on the results obtained, the selectivity for H2/CO2 was achieved using PSF membranes; with the values obtained of 1.54–3.32 at a pressure of 1–8 bar. This result shows that PSF membranes have better performance for H2 purification than PDMS membranes. This is supported by the analysis of the membranes after the test, which includes Fourier Transform Infrared (FTIR), Scanning Electron Microscopy (SEM) and Atomic Force Microscopy (AFM) analyses. PSF membranes showed no changes on their FTIR spectra after permeation, while PDMS membranes, of 75 and 200 μm thicknesses, recorded higher transmittance of their spectra after permeation. The flexibility of the PDMS membranes is evidence of more permeance of the hydrogen mixture that leads to less selectivity of H2/CO2. Meanwhile, SEM and AFM analyses proved the morphology effects; which include changes of pore size distribution cross-section, membrane thickness and surface roughness, after permeation of the applied pressure from 1 to 8 bar, which was possibly due to the compaction effect.
•Fermentation of Palm Oil Mill Effluent (POME) in oil palm industry produced BioH2.•BioH2 upgrading from H2/CO2 mixture was conducted using PSF and PDMS membranes.•PSF membranes gave reasonable bioH2 permeance and selectivity at low pressure.•PSF membrane system can be coupled with POME bioreactor for bioH2 upgrading.</description><identifier>ISSN: 0360-3199</identifier><identifier>EISSN: 1879-3487</identifier><identifier>DOI: 10.1016/j.ijhydene.2015.08.002</identifier><language>eng</language><publisher>Elsevier Ltd</publisher><subject>Atomic force microscopy ; Biohydrogen ; Carbon dioxide ; Membrane separation ; Membranes ; PDMS ; Penetration ; Permeation ; POME ; PSF ; Purification ; Scanning electron microscopy ; Silicone resins</subject><ispartof>International journal of hydrogen energy, 2016-02, Vol.41 (7), p.4474-4488</ispartof><rights>2015 Hydrogen Energy Publications, LLC.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c452t-afc1dea3739e6047bf369cd7f752ff8afd3b90243817e66fdf79931118f099703</citedby><cites>FETCH-LOGICAL-c452t-afc1dea3739e6047bf369cd7f752ff8afd3b90243817e66fdf79931118f099703</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.ijhydene.2015.08.002$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3550,27924,27925,45995</link.rule.ids></links><search><creatorcontrib>Mohamad, Izzati Nadia</creatorcontrib><creatorcontrib>Rohani, Rosiah</creatorcontrib><creatorcontrib>Mastar@Masdar, Mohd. Shahbudin</creatorcontrib><creatorcontrib>Mohd Nor, Mohd Tusirin</creatorcontrib><creatorcontrib>Md. Jahim, Jamaliah</creatorcontrib><title>Permeation properties of polymeric membranes for biohydrogen purification</title><title>International journal of hydrogen energy</title><description>Palm Oil Mill Effluent (POME), generated from the oil extraction process, possesses high Biochemical Oxygen Demand (BOD) and Chemical Oxygen Demand (COD). POME can be treated in an efficient bioreactor under controlled conditions to produce high value biohydrogen mixture containing CO2. The H2 existence in the valuable gas mixture (in a reasonable quantity) could be used as a clean energy source for renewable energy i.e., in hydrogen fuel cell. CO2 presence in fuel cell causes CO2 poisoning and affects its performance. Therefore, the purification of H2 from CO2 produced from POME fermentation is desirable to ensure that an appropriate purity of H2 is achieved. This work focused on the performance of gas membrane separation technology; by specifically using two different polymeric membranes, namely polysulfone (PSF) and polydimethylsiloxane (PDMS). Based on the results obtained, the selectivity for H2/CO2 was achieved using PSF membranes; with the values obtained of 1.54–3.32 at a pressure of 1–8 bar. This result shows that PSF membranes have better performance for H2 purification than PDMS membranes. This is supported by the analysis of the membranes after the test, which includes Fourier Transform Infrared (FTIR), Scanning Electron Microscopy (SEM) and Atomic Force Microscopy (AFM) analyses. PSF membranes showed no changes on their FTIR spectra after permeation, while PDMS membranes, of 75 and 200 μm thicknesses, recorded higher transmittance of their spectra after permeation. The flexibility of the PDMS membranes is evidence of more permeance of the hydrogen mixture that leads to less selectivity of H2/CO2. Meanwhile, SEM and AFM analyses proved the morphology effects; which include changes of pore size distribution cross-section, membrane thickness and surface roughness, after permeation of the applied pressure from 1 to 8 bar, which was possibly due to the compaction effect.
•Fermentation of Palm Oil Mill Effluent (POME) in oil palm industry produced BioH2.•BioH2 upgrading from H2/CO2 mixture was conducted using PSF and PDMS membranes.•PSF membranes gave reasonable bioH2 permeance and selectivity at low pressure.•PSF membrane system can be coupled with POME bioreactor for bioH2 upgrading.</description><subject>Atomic force microscopy</subject><subject>Biohydrogen</subject><subject>Carbon dioxide</subject><subject>Membrane separation</subject><subject>Membranes</subject><subject>PDMS</subject><subject>Penetration</subject><subject>Permeation</subject><subject>POME</subject><subject>PSF</subject><subject>Purification</subject><subject>Scanning electron microscopy</subject><subject>Silicone resins</subject><issn>0360-3199</issn><issn>1879-3487</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNqFkE9LxDAQxYMouK5-BenRS-uk6TbJTVn8s7CgBz2HNJ1oStvUpCvstze6evY0MLzfmzePkEsKBQVaX3eF6973LY5YlEBXBYgCoDwiCyq4zFkl-DFZAKshZ1TKU3IWYwdAOVRyQTbPGAbUs_NjNgU_YZgdxszbbPL9fsDgTDbg0AQ9prX1IWucT9eCf8NE7IKzzvzg5-TE6j7ixe9cktf7u5f1Y759etisb7e5qVblnGtraIuacSaxhoo3ltXStNzyVWmt0LZljYSyYoJyrGvbWi4lo5QKC1JyYEtydfBNcT92GGc1uGiw71NCv4uKChC0FKISSVofpCb4GANaNQU36LBXFNR3d6pTf92p7-4UCJW6S-DNAcT0yKfDoKJxOBpsXUAzq9a7_yy-ALimfL4</recordid><startdate>20160223</startdate><enddate>20160223</enddate><creator>Mohamad, Izzati Nadia</creator><creator>Rohani, Rosiah</creator><creator>Mastar@Masdar, Mohd. Shahbudin</creator><creator>Mohd Nor, Mohd Tusirin</creator><creator>Md. Jahim, Jamaliah</creator><general>Elsevier Ltd</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>8FD</scope><scope>L7M</scope></search><sort><creationdate>20160223</creationdate><title>Permeation properties of polymeric membranes for biohydrogen purification</title><author>Mohamad, Izzati Nadia ; Rohani, Rosiah ; Mastar@Masdar, Mohd. Shahbudin ; Mohd Nor, Mohd Tusirin ; Md. Jahim, Jamaliah</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c452t-afc1dea3739e6047bf369cd7f752ff8afd3b90243817e66fdf79931118f099703</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Atomic force microscopy</topic><topic>Biohydrogen</topic><topic>Carbon dioxide</topic><topic>Membrane separation</topic><topic>Membranes</topic><topic>PDMS</topic><topic>Penetration</topic><topic>Permeation</topic><topic>POME</topic><topic>PSF</topic><topic>Purification</topic><topic>Scanning electron microscopy</topic><topic>Silicone resins</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Mohamad, Izzati Nadia</creatorcontrib><creatorcontrib>Rohani, Rosiah</creatorcontrib><creatorcontrib>Mastar@Masdar, Mohd. Shahbudin</creatorcontrib><creatorcontrib>Mohd Nor, Mohd Tusirin</creatorcontrib><creatorcontrib>Md. Jahim, Jamaliah</creatorcontrib><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>International journal of hydrogen energy</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Mohamad, Izzati Nadia</au><au>Rohani, Rosiah</au><au>Mastar@Masdar, Mohd. Shahbudin</au><au>Mohd Nor, Mohd Tusirin</au><au>Md. Jahim, Jamaliah</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Permeation properties of polymeric membranes for biohydrogen purification</atitle><jtitle>International journal of hydrogen energy</jtitle><date>2016-02-23</date><risdate>2016</risdate><volume>41</volume><issue>7</issue><spage>4474</spage><epage>4488</epage><pages>4474-4488</pages><issn>0360-3199</issn><eissn>1879-3487</eissn><abstract>Palm Oil Mill Effluent (POME), generated from the oil extraction process, possesses high Biochemical Oxygen Demand (BOD) and Chemical Oxygen Demand (COD). POME can be treated in an efficient bioreactor under controlled conditions to produce high value biohydrogen mixture containing CO2. The H2 existence in the valuable gas mixture (in a reasonable quantity) could be used as a clean energy source for renewable energy i.e., in hydrogen fuel cell. CO2 presence in fuel cell causes CO2 poisoning and affects its performance. Therefore, the purification of H2 from CO2 produced from POME fermentation is desirable to ensure that an appropriate purity of H2 is achieved. This work focused on the performance of gas membrane separation technology; by specifically using two different polymeric membranes, namely polysulfone (PSF) and polydimethylsiloxane (PDMS). Based on the results obtained, the selectivity for H2/CO2 was achieved using PSF membranes; with the values obtained of 1.54–3.32 at a pressure of 1–8 bar. This result shows that PSF membranes have better performance for H2 purification than PDMS membranes. This is supported by the analysis of the membranes after the test, which includes Fourier Transform Infrared (FTIR), Scanning Electron Microscopy (SEM) and Atomic Force Microscopy (AFM) analyses. PSF membranes showed no changes on their FTIR spectra after permeation, while PDMS membranes, of 75 and 200 μm thicknesses, recorded higher transmittance of their spectra after permeation. The flexibility of the PDMS membranes is evidence of more permeance of the hydrogen mixture that leads to less selectivity of H2/CO2. Meanwhile, SEM and AFM analyses proved the morphology effects; which include changes of pore size distribution cross-section, membrane thickness and surface roughness, after permeation of the applied pressure from 1 to 8 bar, which was possibly due to the compaction effect.
•Fermentation of Palm Oil Mill Effluent (POME) in oil palm industry produced BioH2.•BioH2 upgrading from H2/CO2 mixture was conducted using PSF and PDMS membranes.•PSF membranes gave reasonable bioH2 permeance and selectivity at low pressure.•PSF membrane system can be coupled with POME bioreactor for bioH2 upgrading.</abstract><pub>Elsevier Ltd</pub><doi>10.1016/j.ijhydene.2015.08.002</doi><tpages>15</tpages></addata></record> |
fulltext | fulltext |
identifier | ISSN: 0360-3199 |
ispartof | International journal of hydrogen energy, 2016-02, Vol.41 (7), p.4474-4488 |
issn | 0360-3199 1879-3487 |
language | eng |
recordid | cdi_proquest_miscellaneous_1808128848 |
source | Access via ScienceDirect (Elsevier) |
subjects | Atomic force microscopy Biohydrogen Carbon dioxide Membrane separation Membranes PDMS Penetration Permeation POME PSF Purification Scanning electron microscopy Silicone resins |
title | Permeation properties of polymeric membranes for biohydrogen purification |
url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-25T18%3A13%3A33IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Permeation%20properties%20of%20polymeric%20membranes%20for%20biohydrogen%20purification&rft.jtitle=International%20journal%20of%20hydrogen%20energy&rft.au=Mohamad,%20Izzati%20Nadia&rft.date=2016-02-23&rft.volume=41&rft.issue=7&rft.spage=4474&rft.epage=4488&rft.pages=4474-4488&rft.issn=0360-3199&rft.eissn=1879-3487&rft_id=info:doi/10.1016/j.ijhydene.2015.08.002&rft_dat=%3Cproquest_cross%3E1808128848%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1808128848&rft_id=info:pmid/&rft_els_id=S0360319915020078&rfr_iscdi=true |