Controllable synthesis and sintering of silver nanoparticles for inkjet-printed flexible electronics

An effective and facile strategy was developed to successfully synthesize nearly uniform silver nanoparticles (AgNPs) with particle size of

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Veröffentlicht in:Journal of alloys and compounds 2015-11, Vol.649, p.687-693
Hauptverfasser: Zhang, Zhiliang, Zhu, Weiyue
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container_title Journal of alloys and compounds
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creator Zhang, Zhiliang
Zhu, Weiyue
description An effective and facile strategy was developed to successfully synthesize nearly uniform silver nanoparticles (AgNPs) with particle size of
doi_str_mv 10.1016/j.jallcom.2015.07.195
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In such system, a series of different chain-length alkylamines were exploited as capped molecules to controllable synthesis of uniform AgNPs with the mean nanoparticle size in rang of 8.6 ± 0.9, 8.9 ± 1.2 and 9.2 ± 1.6 nm, and these ultra-small nanoparticles were very favorable to attain an excellent printing fluency. Based on the as-synthesized AgNPs, a sequence of flexible electrocircuits was successfully fabricated by ink-jet printing technique. After the dipped treatment, the printed AgNPs were achieved to spontaneous coalescence and aggregation at room temperature induced by preferential dissolution of capped molecules on AgNPs surfaces into methanol solution. These aggregated AgNPs demonstrated superior controllability, excellent stability and low resistivity in the range of 31.6–26.5 μΩ cm, and would have enormous potential in the application to be tailored for assembly of optoelectronics devices. [Display omitted] •Silver nanoparticles with particle size of &lt;10 nm was controllably synthesized.•The sintering of silver nanoparticles was conducted at room temperature.•The resistivity was reached as low as 26.5 μΩ cm for flexible electronics.</description><identifier>ISSN: 0925-8388</identifier><identifier>EISSN: 1873-4669</identifier><identifier>DOI: 10.1016/j.jallcom.2015.07.195</identifier><language>eng</language><publisher>Elsevier B.V</publisher><subject>Capping ; Controllable synthesis ; Dipping methods ; Electronics ; Flexible electronics ; Ink-jet printing technique ; Methyl alcohol ; Nanoparticles ; Nanostructure ; Optoelectronic devices ; Printing ; Silver nanoparticles ; Sintering</subject><ispartof>Journal of alloys and compounds, 2015-11, Vol.649, p.687-693</ispartof><rights>2015 Elsevier B.V.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c342t-266336f13452ec9e1537364b137691e998ab15e0a2f2415ad6ce6295eb5a75413</citedby><cites>FETCH-LOGICAL-c342t-266336f13452ec9e1537364b137691e998ab15e0a2f2415ad6ce6295eb5a75413</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.jallcom.2015.07.195$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3536,27903,27904,45974</link.rule.ids></links><search><creatorcontrib>Zhang, Zhiliang</creatorcontrib><creatorcontrib>Zhu, Weiyue</creatorcontrib><title>Controllable synthesis and sintering of silver nanoparticles for inkjet-printed flexible electronics</title><title>Journal of alloys and compounds</title><description>An effective and facile strategy was developed to successfully synthesize nearly uniform silver nanoparticles (AgNPs) with particle size of &lt;10 nm, and demonstrated to achieve the sintering of AgNPs at room temperature for inkjet-printed flexible electronics. In such system, a series of different chain-length alkylamines were exploited as capped molecules to controllable synthesis of uniform AgNPs with the mean nanoparticle size in rang of 8.6 ± 0.9, 8.9 ± 1.2 and 9.2 ± 1.6 nm, and these ultra-small nanoparticles were very favorable to attain an excellent printing fluency. Based on the as-synthesized AgNPs, a sequence of flexible electrocircuits was successfully fabricated by ink-jet printing technique. After the dipped treatment, the printed AgNPs were achieved to spontaneous coalescence and aggregation at room temperature induced by preferential dissolution of capped molecules on AgNPs surfaces into methanol solution. These aggregated AgNPs demonstrated superior controllability, excellent stability and low resistivity in the range of 31.6–26.5 μΩ cm, and would have enormous potential in the application to be tailored for assembly of optoelectronics devices. [Display omitted] •Silver nanoparticles with particle size of &lt;10 nm was controllably synthesized.•The sintering of silver nanoparticles was conducted at room temperature.•The resistivity was reached as low as 26.5 μΩ cm for flexible electronics.</description><subject>Capping</subject><subject>Controllable synthesis</subject><subject>Dipping methods</subject><subject>Electronics</subject><subject>Flexible electronics</subject><subject>Ink-jet printing technique</subject><subject>Methyl alcohol</subject><subject>Nanoparticles</subject><subject>Nanostructure</subject><subject>Optoelectronic devices</subject><subject>Printing</subject><subject>Silver nanoparticles</subject><subject>Sintering</subject><issn>0925-8388</issn><issn>1873-4669</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><recordid>eNqFkE1LxDAURYMoOI7-BKFLN615SZM2K5HBLxDc6Dpk0ldNzSRjUkX_vRnGvavHg3svnEPIOdAGKMjLqZmM9zZuGkZBNLRrQIkDsoC-43UrpTokC6qYqHve98fkJOeJUgqKw4IMqxjmFL03a49V_gnzG2aXKxOGKrswY3LhtYpjefwXpiqYELcmzc56zNUYU-XC-4RzvU279FCNHr_dbgs92rIcnM2n5Gg0PuPZ312Sl9ub59V9_fh097C6fqwtb9lcMyk5lyPwVjC0CkHwjst2DbyTClCp3qxBIDVsZC0IM0iLkimBa2E60QJfkov97jbFj0_Ms964bLHABYyfWUNPe2AMGC1RsY_aFHNOOOoCsDHpRwPVO6t60n9W9c6qpp0uVkvvat_DwvHlMOlsHQaLg0uFVw_R_bPwC_KBhLg</recordid><startdate>20151115</startdate><enddate>20151115</enddate><creator>Zhang, Zhiliang</creator><creator>Zhu, Weiyue</creator><general>Elsevier B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20151115</creationdate><title>Controllable synthesis and sintering of silver nanoparticles for inkjet-printed flexible electronics</title><author>Zhang, Zhiliang ; Zhu, Weiyue</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c342t-266336f13452ec9e1537364b137691e998ab15e0a2f2415ad6ce6295eb5a75413</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>Capping</topic><topic>Controllable synthesis</topic><topic>Dipping methods</topic><topic>Electronics</topic><topic>Flexible electronics</topic><topic>Ink-jet printing technique</topic><topic>Methyl alcohol</topic><topic>Nanoparticles</topic><topic>Nanostructure</topic><topic>Optoelectronic devices</topic><topic>Printing</topic><topic>Silver nanoparticles</topic><topic>Sintering</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhang, Zhiliang</creatorcontrib><creatorcontrib>Zhu, Weiyue</creatorcontrib><collection>CrossRef</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of alloys and compounds</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhang, Zhiliang</au><au>Zhu, Weiyue</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Controllable synthesis and sintering of silver nanoparticles for inkjet-printed flexible electronics</atitle><jtitle>Journal of alloys and compounds</jtitle><date>2015-11-15</date><risdate>2015</risdate><volume>649</volume><spage>687</spage><epage>693</epage><pages>687-693</pages><issn>0925-8388</issn><eissn>1873-4669</eissn><abstract>An effective and facile strategy was developed to successfully synthesize nearly uniform silver nanoparticles (AgNPs) with particle size of &lt;10 nm, and demonstrated to achieve the sintering of AgNPs at room temperature for inkjet-printed flexible electronics. In such system, a series of different chain-length alkylamines were exploited as capped molecules to controllable synthesis of uniform AgNPs with the mean nanoparticle size in rang of 8.6 ± 0.9, 8.9 ± 1.2 and 9.2 ± 1.6 nm, and these ultra-small nanoparticles were very favorable to attain an excellent printing fluency. Based on the as-synthesized AgNPs, a sequence of flexible electrocircuits was successfully fabricated by ink-jet printing technique. After the dipped treatment, the printed AgNPs were achieved to spontaneous coalescence and aggregation at room temperature induced by preferential dissolution of capped molecules on AgNPs surfaces into methanol solution. These aggregated AgNPs demonstrated superior controllability, excellent stability and low resistivity in the range of 31.6–26.5 μΩ cm, and would have enormous potential in the application to be tailored for assembly of optoelectronics devices. [Display omitted] •Silver nanoparticles with particle size of &lt;10 nm was controllably synthesized.•The sintering of silver nanoparticles was conducted at room temperature.•The resistivity was reached as low as 26.5 μΩ cm for flexible electronics.</abstract><pub>Elsevier B.V</pub><doi>10.1016/j.jallcom.2015.07.195</doi><tpages>7</tpages></addata></record>
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subjects Capping
Controllable synthesis
Dipping methods
Electronics
Flexible electronics
Ink-jet printing technique
Methyl alcohol
Nanoparticles
Nanostructure
Optoelectronic devices
Printing
Silver nanoparticles
Sintering
title Controllable synthesis and sintering of silver nanoparticles for inkjet-printed flexible electronics
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