Estimation of Redox Condition of Simulated High-level Waste Glass Based on the Chemical Composition of Crystalline Phases of Platinum-group Elements

The redox condition of simulated high-level waste (HLW) glass was investigated by thermodynamic calculations for the phase equilibrium of crystalline phases composed of platinum group elements (PGE, Pd, Rh, and Ru) based on the thermodynamic data for Pd-Rh-Ru and (Ru,Rh)O2 solid solutions. Phase equ...

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Veröffentlicht in:	Nihon Genshiryoku Gakkai wabun ronbunshi = Transactions of the Atomic Energy Society of Japan 2016, Vol.15(1), pp.43-52
Hauptverfasser:	SUGAWARA, Toru, OHIRA, Toshiaki, KOMAMINE, Satoshi, OCHI, Eiji
Format:	Artikel
Sprache:	eng ; jpn
Schlagworte:	(Ru,Rh)O2 Crystal structure fission product Fugacity Glass glass melter glass waste form Mathematical analysis oxidation behavior oxygen fugacity Palladium Pd-Rh-Ru Phase equilibria Phases redox reprocessing Thermodynamics
Online-Zugang:	Volltext
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