Adsorption of silver nanoparticles from aqueous solution on copper-based metal organic frameworks (HKUST-1)
Silver nanoparticles (AgNP) are emerging pollutants. The use of novel materials such as Cu-(benzene 1,3,5-tricarboxylate, BTC) Metal-Organic Framework (MOFs), for AgNP adsorption and their removal from aqueous solutions has been studied. The effect of different parameters was followed and isotherm m...
Gespeichert in:
| Veröffentlicht in: | Chemosphere (Oxford) 2016-05, Vol.150, p.659-666 |
|---|---|
| Hauptverfasser: | , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 666 |
|---|---|
| container_issue | |
| container_start_page | 659 |
| container_title | Chemosphere (Oxford) |
| container_volume | 150 |
| creator | Conde-González, J.E. Peña-Méndez, E.M. Rybáková, S. Pasán, J. Ruiz-Pérez, C. Havel, J. |
| description | Silver nanoparticles (AgNP) are emerging pollutants. The use of novel materials such as Cu-(benzene 1,3,5-tricarboxylate, BTC) Metal-Organic Framework (MOFs), for AgNP adsorption and their removal from aqueous solutions has been studied. The effect of different parameters was followed and isotherm model was suggested. MOFs adsorbed fast and efficiently AgNP in the range C0 |
| doi_str_mv | 10.1016/j.chemosphere.2016.02.005 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1808118423</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><els_id>S0045653516301485</els_id><sourcerecordid>1785253962</sourcerecordid><originalsourceid>FETCH-LOGICAL-c513t-fdca1796c346c555df8ed3c33873f77b56cad62499a832080abdb54c140b27253</originalsourceid><addsrcrecordid>eNqNkc1u3CAUhVHVqDNN-goV3U0WdvgxNixHo_xUjZRFkjXCcN1hYhsXPKn69mE0adVdskJC3zmXy4fQN0pKSmh9sSvtFoaQpi1EKFm-KgkrCREf0JLKRhWUKfkRLQmpRFELLhboc0o7QjIp1Ce0YHWmmGJL9LR2KcRp9mHEocPJ988Q8WjGMJk4e9tDwl0MAza_9hD2CafQ74_0iG2YJohFaxI4PMBsehziTzN6mzNmgN8hPiW8uvnxeP9Q0PMzdNKZPsGX1_MUPV5dPmxuitu76--b9W1hBeVz0TlraKNqy6vaCiFcJ8Fxy7lseNc0raitcTWrlDKSMyKJaV0rKksr0rKGCX6KVsfeKYb86jTrwScLfW_GwwqaSiIplRXjb6ONFLlR1ewdaMMkr6Q4tKojamNIKUKnp-gHE_9oSvTBoN7p_wzqg0FNmM4Gc_br65h9O4D7l_yrLAObIwD5C589RJ2sh9GC8xHsrF3w7xjzAuxjssA</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1772834853</pqid></control><display><type>article</type><title>Adsorption of silver nanoparticles from aqueous solution on copper-based metal organic frameworks (HKUST-1)</title><source>MEDLINE</source><source>Elsevier ScienceDirect Journals</source><creator>Conde-González, J.E. ; Peña-Méndez, E.M. ; Rybáková, S. ; Pasán, J. ; Ruiz-Pérez, C. ; Havel, J.</creator><creatorcontrib>Conde-González, J.E. ; Peña-Méndez, E.M. ; Rybáková, S. ; Pasán, J. ; Ruiz-Pérez, C. ; Havel, J.</creatorcontrib><description>Silver nanoparticles (AgNP) are emerging pollutants. The use of novel materials such as Cu-(benzene 1,3,5-tricarboxylate, BTC) Metal-Organic Framework (MOFs), for AgNP adsorption and their removal from aqueous solutions has been studied. The effect of different parameters was followed and isotherm model was suggested. MOFs adsorbed fast and efficiently AgNP in the range C0 < 10 mg L−1, being Freundlich isotherm (R = 0.993) these data fitted to. Among studied parameters a remarkable effect of chloride on sorption was found, thus their possible interactions were considered. The high adsorption efficiency of AgNP was achieved and it was found to be very fast. The feasibility of adsorption on Cu-(BTC) was proved in spiked waters. The results showed the potential interest of new material as adsorbent for removing AgNP from environment.
•This study investigates the removal of AgNP colloids by Cu-(BTC) MOFs.•Adsorption of AgNP on HKUST-1 was very fast and followed Freundlich isotherm.•The efficient and complete removal of AgNP was affected by the type of water.•SEM and EDX analysis showed that AgNP were adsorbed onto the MOFs.•Very low amount of HKUST-1 (10 mg) are necessary to perform adequate adsorption of AgNP the range of environmental levels.</description><identifier>ISSN: 0045-6535</identifier><identifier>EISSN: 1879-1298</identifier><identifier>DOI: 10.1016/j.chemosphere.2016.02.005</identifier><identifier>PMID: 26879292</identifier><language>eng</language><publisher>England: Elsevier Ltd</publisher><subject>Adsorbents ; Adsorption ; Aqueous solutions ; Chlorides ; Colloids ; Copper ; Copper - chemistry ; Isotherms ; Mathematical models ; Metal Nanoparticles - analysis ; Metal organic frameworks ; Nanoparticles ; Organometallic Compounds - chemistry ; Silver ; Silver - analysis ; Silver nanoparticles ; Water ; Water Pollutants, Chemical - analysis ; Water Purification - methods</subject><ispartof>Chemosphere (Oxford), 2016-05, Vol.150, p.659-666</ispartof><rights>2016 Elsevier Ltd</rights><rights>Copyright © 2016 Elsevier Ltd. All rights reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c513t-fdca1796c346c555df8ed3c33873f77b56cad62499a832080abdb54c140b27253</citedby><cites>FETCH-LOGICAL-c513t-fdca1796c346c555df8ed3c33873f77b56cad62499a832080abdb54c140b27253</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0045653516301485$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3537,27901,27902,65534</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/26879292$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Conde-González, J.E.</creatorcontrib><creatorcontrib>Peña-Méndez, E.M.</creatorcontrib><creatorcontrib>Rybáková, S.</creatorcontrib><creatorcontrib>Pasán, J.</creatorcontrib><creatorcontrib>Ruiz-Pérez, C.</creatorcontrib><creatorcontrib>Havel, J.</creatorcontrib><title>Adsorption of silver nanoparticles from aqueous solution on copper-based metal organic frameworks (HKUST-1)</title><title>Chemosphere (Oxford)</title><addtitle>Chemosphere</addtitle><description>Silver nanoparticles (AgNP) are emerging pollutants. The use of novel materials such as Cu-(benzene 1,3,5-tricarboxylate, BTC) Metal-Organic Framework (MOFs), for AgNP adsorption and their removal from aqueous solutions has been studied. The effect of different parameters was followed and isotherm model was suggested. MOFs adsorbed fast and efficiently AgNP in the range C0 < 10 mg L−1, being Freundlich isotherm (R = 0.993) these data fitted to. Among studied parameters a remarkable effect of chloride on sorption was found, thus their possible interactions were considered. The high adsorption efficiency of AgNP was achieved and it was found to be very fast. The feasibility of adsorption on Cu-(BTC) was proved in spiked waters. The results showed the potential interest of new material as adsorbent for removing AgNP from environment.
•This study investigates the removal of AgNP colloids by Cu-(BTC) MOFs.•Adsorption of AgNP on HKUST-1 was very fast and followed Freundlich isotherm.•The efficient and complete removal of AgNP was affected by the type of water.•SEM and EDX analysis showed that AgNP were adsorbed onto the MOFs.•Very low amount of HKUST-1 (10 mg) are necessary to perform adequate adsorption of AgNP the range of environmental levels.</description><subject>Adsorbents</subject><subject>Adsorption</subject><subject>Aqueous solutions</subject><subject>Chlorides</subject><subject>Colloids</subject><subject>Copper</subject><subject>Copper - chemistry</subject><subject>Isotherms</subject><subject>Mathematical models</subject><subject>Metal Nanoparticles - analysis</subject><subject>Metal organic frameworks</subject><subject>Nanoparticles</subject><subject>Organometallic Compounds - chemistry</subject><subject>Silver</subject><subject>Silver - analysis</subject><subject>Silver nanoparticles</subject><subject>Water</subject><subject>Water Pollutants, Chemical - analysis</subject><subject>Water Purification - methods</subject><issn>0045-6535</issn><issn>1879-1298</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqNkc1u3CAUhVHVqDNN-goV3U0WdvgxNixHo_xUjZRFkjXCcN1hYhsXPKn69mE0adVdskJC3zmXy4fQN0pKSmh9sSvtFoaQpi1EKFm-KgkrCREf0JLKRhWUKfkRLQmpRFELLhboc0o7QjIp1Ce0YHWmmGJL9LR2KcRp9mHEocPJ988Q8WjGMJk4e9tDwl0MAza_9hD2CafQ74_0iG2YJohFaxI4PMBsehziTzN6mzNmgN8hPiW8uvnxeP9Q0PMzdNKZPsGX1_MUPV5dPmxuitu76--b9W1hBeVz0TlraKNqy6vaCiFcJ8Fxy7lseNc0raitcTWrlDKSMyKJaV0rKksr0rKGCX6KVsfeKYb86jTrwScLfW_GwwqaSiIplRXjb6ONFLlR1ewdaMMkr6Q4tKojamNIKUKnp-gHE_9oSvTBoN7p_wzqg0FNmM4Gc_br65h9O4D7l_yrLAObIwD5C589RJ2sh9GC8xHsrF3w7xjzAuxjssA</recordid><startdate>20160501</startdate><enddate>20160501</enddate><creator>Conde-González, J.E.</creator><creator>Peña-Méndez, E.M.</creator><creator>Rybáková, S.</creator><creator>Pasán, J.</creator><creator>Ruiz-Pérez, C.</creator><creator>Havel, J.</creator><general>Elsevier Ltd</general><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>7ST</scope><scope>7TV</scope><scope>7U7</scope><scope>C1K</scope><scope>SOI</scope><scope>8FD</scope><scope>FR3</scope><scope>KR7</scope></search><sort><creationdate>20160501</creationdate><title>Adsorption of silver nanoparticles from aqueous solution on copper-based metal organic frameworks (HKUST-1)</title><author>Conde-González, J.E. ; Peña-Méndez, E.M. ; Rybáková, S. ; Pasán, J. ; Ruiz-Pérez, C. ; Havel, J.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c513t-fdca1796c346c555df8ed3c33873f77b56cad62499a832080abdb54c140b27253</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Adsorbents</topic><topic>Adsorption</topic><topic>Aqueous solutions</topic><topic>Chlorides</topic><topic>Colloids</topic><topic>Copper</topic><topic>Copper - chemistry</topic><topic>Isotherms</topic><topic>Mathematical models</topic><topic>Metal Nanoparticles - analysis</topic><topic>Metal organic frameworks</topic><topic>Nanoparticles</topic><topic>Organometallic Compounds - chemistry</topic><topic>Silver</topic><topic>Silver - analysis</topic><topic>Silver nanoparticles</topic><topic>Water</topic><topic>Water Pollutants, Chemical - analysis</topic><topic>Water Purification - methods</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Conde-González, J.E.</creatorcontrib><creatorcontrib>Peña-Méndez, E.M.</creatorcontrib><creatorcontrib>Rybáková, S.</creatorcontrib><creatorcontrib>Pasán, J.</creatorcontrib><creatorcontrib>Ruiz-Pérez, C.</creatorcontrib><creatorcontrib>Havel, J.</creatorcontrib><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>Environment Abstracts</collection><collection>Pollution Abstracts</collection><collection>Toxicology Abstracts</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Environment Abstracts</collection><collection>Technology Research Database</collection><collection>Engineering Research Database</collection><collection>Civil Engineering Abstracts</collection><jtitle>Chemosphere (Oxford)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Conde-González, J.E.</au><au>Peña-Méndez, E.M.</au><au>Rybáková, S.</au><au>Pasán, J.</au><au>Ruiz-Pérez, C.</au><au>Havel, J.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Adsorption of silver nanoparticles from aqueous solution on copper-based metal organic frameworks (HKUST-1)</atitle><jtitle>Chemosphere (Oxford)</jtitle><addtitle>Chemosphere</addtitle><date>2016-05-01</date><risdate>2016</risdate><volume>150</volume><spage>659</spage><epage>666</epage><pages>659-666</pages><issn>0045-6535</issn><eissn>1879-1298</eissn><abstract>Silver nanoparticles (AgNP) are emerging pollutants. The use of novel materials such as Cu-(benzene 1,3,5-tricarboxylate, BTC) Metal-Organic Framework (MOFs), for AgNP adsorption and their removal from aqueous solutions has been studied. The effect of different parameters was followed and isotherm model was suggested. MOFs adsorbed fast and efficiently AgNP in the range C0 < 10 mg L−1, being Freundlich isotherm (R = 0.993) these data fitted to. Among studied parameters a remarkable effect of chloride on sorption was found, thus their possible interactions were considered. The high adsorption efficiency of AgNP was achieved and it was found to be very fast. The feasibility of adsorption on Cu-(BTC) was proved in spiked waters. The results showed the potential interest of new material as adsorbent for removing AgNP from environment.
•This study investigates the removal of AgNP colloids by Cu-(BTC) MOFs.•Adsorption of AgNP on HKUST-1 was very fast and followed Freundlich isotherm.•The efficient and complete removal of AgNP was affected by the type of water.•SEM and EDX analysis showed that AgNP were adsorbed onto the MOFs.•Very low amount of HKUST-1 (10 mg) are necessary to perform adequate adsorption of AgNP the range of environmental levels.</abstract><cop>England</cop><pub>Elsevier Ltd</pub><pmid>26879292</pmid><doi>10.1016/j.chemosphere.2016.02.005</doi><tpages>8</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0045-6535 |
| ispartof | Chemosphere (Oxford), 2016-05, Vol.150, p.659-666 |
| issn | 0045-6535 1879-1298 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1808118423 |
| source | MEDLINE; Elsevier ScienceDirect Journals |
| subjects | Adsorbents Adsorption Aqueous solutions Chlorides Colloids Copper Copper - chemistry Isotherms Mathematical models Metal Nanoparticles - analysis Metal organic frameworks Nanoparticles Organometallic Compounds - chemistry Silver Silver - analysis Silver nanoparticles Water Water Pollutants, Chemical - analysis Water Purification - methods |
| title | Adsorption of silver nanoparticles from aqueous solution on copper-based metal organic frameworks (HKUST-1) |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-14T03%3A59%3A18IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Adsorption%20of%20silver%20nanoparticles%20from%20aqueous%20solution%20on%20copper-based%20metal%20organic%20frameworks%20(HKUST-1)&rft.jtitle=Chemosphere%20(Oxford)&rft.au=Conde-Gonz%C3%A1lez,%20J.E.&rft.date=2016-05-01&rft.volume=150&rft.spage=659&rft.epage=666&rft.pages=659-666&rft.issn=0045-6535&rft.eissn=1879-1298&rft_id=info:doi/10.1016/j.chemosphere.2016.02.005&rft_dat=%3Cproquest_cross%3E1785253962%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1772834853&rft_id=info:pmid/26879292&rft_els_id=S0045653516301485&rfr_iscdi=true |