Synthesis and characterization of the well-defined polypentadiene via living anionic polymerization of (E)-1,3-pentadiene

The well-defined anionic polymerization of (E)-1,3-pentadiene (EP) using various RLi initiators in nonpolar solvent was studied. The results of the polymerization kinetics with n-BuLi initiator in cyclohexane confirmed the expected living nature of the anionic polymerization of EP. An apparent activ...

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Veröffentlicht in:	Polymer (Guilford) 2016-04, Vol.89, p.28-40
Hauptverfasser:	Liu, Kun, He, Qing, Ren, Lei, Gong, Lai Jiang, Hu, Jin Long, Ou, En Cai, Xu, Wei Jian
Format:	Artikel
Sprache:	eng
Schlagworte:	1,3-Pentadiene Activation energy Anionic living polymerization Anionic polymerization Initiators Microstructure Molecular structure Nuclear magnetic resonance Polyisoprenes Polymerization Solvents
Online-Zugang:	Volltext
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