Perturbation theory model of reactivity and enantioselectivity of palladium-catalyzed Heck–Heck cascade reactions

Enantioselective intramolecular Heck–Heck cascade reactions have emerged as an excellent tool for the construction of polycyclic frameworks, such as lycorane alkaloids, xestoquinone and analogues. However, it is particularly difficult to rationalize the effect of simultaneous changes in both the str...

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Veröffentlicht in:	RSC advances 2016-01, Vol.6 (45), p.38602-38610
Hauptverfasser:	Blázquez-Barbadillo, C., Aranzamendi, E., Coya, E., Lete, E., Sotomayor, N., González-Díaz, H.
Format:	Artikel
Sprache:	eng
Schlagworte:	Cascade chemical reactions Catalysts Correlation coefficients Ligands Mathematical models Molecular structure Perturbation theory Trends
Online-Zugang:	Volltext
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