Inclusion of Triphenylphosphine in the Supercage of Zeolite Y

A mixture of triphenylphosphine and zeolite Y was thermally treated in an autoclave (423 K, 24 h), resulting in the inclusion of PPh3 in the supercage of zeolite Y, up to 21 wt % (1.5 PPh3 molecules per supercage). PdCl2 was introduced to the PPh3-treated zeolite Y to fabricate a Pd complex in the s...

Ausführliche Beschreibung

Gespeichert in:

Bibliographische Detailangaben
Veröffentlicht in:	Chemistry letters 2016-04, Vol.45 (4), p.427-429
Hauptverfasser:	Okumura, Kazu, Nakanishi, Masakazu, Kikuchi, Yujiro, Kouno, Tomoyuki
Format:	Artikel
Sprache:	eng
Schlagworte:	Autoclaving Chemical reactions Inclusions Palladium Zeolites
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!

container_end_page	429
container_issue	4
container_start_page	427
container_title	Chemistry letters
container_volume	45
creator	Okumura, Kazu Nakanishi, Masakazu Kikuchi, Yujiro Kouno, Tomoyuki
description	A mixture of triphenylphosphine and zeolite Y was thermally treated in an autoclave (423 K, 24 h), resulting in the inclusion of PPh3 in the supercage of zeolite Y, up to 21 wt % (1.5 PPh3 molecules per supercage). PdCl2 was introduced to the PPh3-treated zeolite Y to fabricate a Pd complex in the supercage, and a coupling reaction was performed over the obtained complex. The turnover frequency increased with increased PPh3 loading, suggesting that the [PdCl2(PPh3)2] complex included in the supercage could be the active species.
doi_str_mv	10.1246/cl.160019
format	Article
fullrecord	<record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1808109644</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1808109644</sourcerecordid><originalsourceid>FETCH-LOGICAL-c447t-aaf5bc8ea9b94838a68c04fb24ad6b0be37993797af3c1b1dc68e1dd2683f1603</originalsourceid><addsrcrecordid>eNpl0D1PwzAQBmALgUQpDPyDSCwwpPirtjMwIMRHpUoMlAEWy3EuxJUbBzsZ-u9J1Q4IhtMtz726O4QuCZ4RysWt9TMiMCbFEZoQxlWOJZkfowlmQuQSU3qKzlJaY4xVwegE3S1a64fkQpuFOltF1zXQbn3XhNQ1roXMtVnfQPY2dBCt-YId-4TgXQ_Zxzk6qY1PcHHoU_T-9Lh6eMmXr8-Lh_tlbjmXfW5MPS-tAlOUBVdMGaEs5nVJualEiUtgsijGkqZmlpSkskIBqSoqFKvHc9gUXe9zuxi-B0i93rhkwXvTQhiSJgorggvB-Uiv_tB1GGI7bqeJlEpKyqga1c1e2RhSilDrLrqNiVtNsN49Uluv948crTjYBjbOjknBOui3a9OZ9lf6v8EfNWZ3Tg</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1778772328</pqid></control><display><type>article</type><title>Inclusion of Triphenylphosphine in the Supercage of Zeolite Y</title><source>Oxford University Press Journals All Titles (1996-Current)</source><creator>Okumura, Kazu ; Nakanishi, Masakazu ; Kikuchi, Yujiro ; Kouno, Tomoyuki</creator><creatorcontrib>Okumura, Kazu ; Nakanishi, Masakazu ; Kikuchi, Yujiro ; Kouno, Tomoyuki</creatorcontrib><description>A mixture of triphenylphosphine and zeolite Y was thermally treated in an autoclave (423 K, 24 h), resulting in the inclusion of PPh3 in the supercage of zeolite Y, up to 21 wt % (1.5 PPh3 molecules per supercage). PdCl2 was introduced to the PPh3-treated zeolite Y to fabricate a Pd complex in the supercage, and a coupling reaction was performed over the obtained complex. The turnover frequency increased with increased PPh3 loading, suggesting that the [PdCl2(PPh3)2] complex included in the supercage could be the active species.</description><identifier>ISSN: 0366-7022</identifier><identifier>EISSN: 1348-0715</identifier><identifier>DOI: 10.1246/cl.160019</identifier><language>eng</language><publisher>Tokyo: The Chemical Society of Japan</publisher><subject>Autoclaving ; Chemical reactions ; Inclusions ; Palladium ; Zeolites</subject><ispartof>Chemistry letters, 2016-04, Vol.45 (4), p.427-429</ispartof><rights>The Chemical Society of Japan</rights><rights>Copyright Japan Science and Technology Agency 2016</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c447t-aaf5bc8ea9b94838a68c04fb24ad6b0be37993797af3c1b1dc68e1dd2683f1603</citedby><cites>FETCH-LOGICAL-c447t-aaf5bc8ea9b94838a68c04fb24ad6b0be37993797af3c1b1dc68e1dd2683f1603</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Okumura, Kazu</creatorcontrib><creatorcontrib>Nakanishi, Masakazu</creatorcontrib><creatorcontrib>Kikuchi, Yujiro</creatorcontrib><creatorcontrib>Kouno, Tomoyuki</creatorcontrib><title>Inclusion of Triphenylphosphine in the Supercage of Zeolite Y</title><title>Chemistry letters</title><addtitle>Chemistry Letters</addtitle><description>A mixture of triphenylphosphine and zeolite Y was thermally treated in an autoclave (423 K, 24 h), resulting in the inclusion of PPh3 in the supercage of zeolite Y, up to 21 wt % (1.5 PPh3 molecules per supercage). PdCl2 was introduced to the PPh3-treated zeolite Y to fabricate a Pd complex in the supercage, and a coupling reaction was performed over the obtained complex. The turnover frequency increased with increased PPh3 loading, suggesting that the [PdCl2(PPh3)2] complex included in the supercage could be the active species.</description><subject>Autoclaving</subject><subject>Chemical reactions</subject><subject>Inclusions</subject><subject>Palladium</subject><subject>Zeolites</subject><issn>0366-7022</issn><issn>1348-0715</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNpl0D1PwzAQBmALgUQpDPyDSCwwpPirtjMwIMRHpUoMlAEWy3EuxJUbBzsZ-u9J1Q4IhtMtz726O4QuCZ4RysWt9TMiMCbFEZoQxlWOJZkfowlmQuQSU3qKzlJaY4xVwegE3S1a64fkQpuFOltF1zXQbn3XhNQ1roXMtVnfQPY2dBCt-YId-4TgXQ_Zxzk6qY1PcHHoU_T-9Lh6eMmXr8-Lh_tlbjmXfW5MPS-tAlOUBVdMGaEs5nVJualEiUtgsijGkqZmlpSkskIBqSoqFKvHc9gUXe9zuxi-B0i93rhkwXvTQhiSJgorggvB-Uiv_tB1GGI7bqeJlEpKyqga1c1e2RhSilDrLrqNiVtNsN49Uluv948crTjYBjbOjknBOui3a9OZ9lf6v8EfNWZ3Tg</recordid><startdate>20160405</startdate><enddate>20160405</enddate><creator>Okumura, Kazu</creator><creator>Nakanishi, Masakazu</creator><creator>Kikuchi, Yujiro</creator><creator>Kouno, Tomoyuki</creator><general>The Chemical Society of Japan</general><general>Chemical Society of Japan</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20160405</creationdate><title>Inclusion of Triphenylphosphine in the Supercage of Zeolite Y</title><author>Okumura, Kazu ; Nakanishi, Masakazu ; Kikuchi, Yujiro ; Kouno, Tomoyuki</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c447t-aaf5bc8ea9b94838a68c04fb24ad6b0be37993797af3c1b1dc68e1dd2683f1603</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Autoclaving</topic><topic>Chemical reactions</topic><topic>Inclusions</topic><topic>Palladium</topic><topic>Zeolites</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Okumura, Kazu</creatorcontrib><creatorcontrib>Nakanishi, Masakazu</creatorcontrib><creatorcontrib>Kikuchi, Yujiro</creatorcontrib><creatorcontrib>Kouno, Tomoyuki</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Chemistry letters</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Okumura, Kazu</au><au>Nakanishi, Masakazu</au><au>Kikuchi, Yujiro</au><au>Kouno, Tomoyuki</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Inclusion of Triphenylphosphine in the Supercage of Zeolite Y</atitle><jtitle>Chemistry letters</jtitle><addtitle>Chemistry Letters</addtitle><date>2016-04-05</date><risdate>2016</risdate><volume>45</volume><issue>4</issue><spage>427</spage><epage>429</epage><pages>427-429</pages><issn>0366-7022</issn><eissn>1348-0715</eissn><abstract>A mixture of triphenylphosphine and zeolite Y was thermally treated in an autoclave (423 K, 24 h), resulting in the inclusion of PPh3 in the supercage of zeolite Y, up to 21 wt % (1.5 PPh3 molecules per supercage). PdCl2 was introduced to the PPh3-treated zeolite Y to fabricate a Pd complex in the supercage, and a coupling reaction was performed over the obtained complex. The turnover frequency increased with increased PPh3 loading, suggesting that the [PdCl2(PPh3)2] complex included in the supercage could be the active species.</abstract><cop>Tokyo</cop><pub>The Chemical Society of Japan</pub><doi>10.1246/cl.160019</doi><tpages>3</tpages></addata></record>
fulltext	fulltext
identifier	ISSN: 0366-7022
ispartof	Chemistry letters, 2016-04, Vol.45 (4), p.427-429
issn	0366-7022 1348-0715
language	eng
recordid	cdi_proquest_miscellaneous_1808109644
source	Oxford University Press Journals All Titles (1996-Current)
subjects	Autoclaving Chemical reactions Inclusions Palladium Zeolites
title	Inclusion of Triphenylphosphine in the Supercage of Zeolite Y
url	https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-06T12%3A08%3A54IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Inclusion%20of%20Triphenylphosphine%20in%20the%20Supercage%20of%20Zeolite%20Y&rft.jtitle=Chemistry%20letters&rft.au=Okumura,%20Kazu&rft.date=2016-04-05&rft.volume=45&rft.issue=4&rft.spage=427&rft.epage=429&rft.pages=427-429&rft.issn=0366-7022&rft.eissn=1348-0715&rft_id=info:doi/10.1246/cl.160019&rft_dat=%3Cproquest_cross%3E1808109644%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1778772328&rft_id=info:pmid/&rfr_iscdi=true