Biogenic Potassium Salt Particles as Seeds for Secondary Organic Aerosol in the Amazon

The fine particles serving as cloud condensation nuclei in pristine Amazonian rainforest air consist mostly of secondary organic aerosol. Their origin is enigmatic, however, because new particle formation in the atmosphere is not observed. Here, we show that the growth of organic aerosol particles c...

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Veröffentlicht in:Science (American Association for the Advancement of Science) 2012-08, Vol.337 (6098), p.1075-1078
Hauptverfasser: Pöhlker, Christopher, Wiedemann, Kenia T., Sinha, Bärbel, Shiraiwa, Manabu, Gunthe, Sachin S., Smith, Mackenzie, Su, Hang, Artaxo, Paulo, Chen, Qi, Cheng, Yafang, Elbert, Wolfgang, Gilles, Mary K., Kilcoyne, Arthur L. D., Moffet, Ryan C., Weigand, Markus, Martin, Scot T., Pöschl, Ulrich, Andreae, Meinrat O.
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container_issue 6098
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container_title Science (American Association for the Advancement of Science)
container_volume 337
creator Pöhlker, Christopher
Wiedemann, Kenia T.
Sinha, Bärbel
Shiraiwa, Manabu
Gunthe, Sachin S.
Smith, Mackenzie
Su, Hang
Artaxo, Paulo
Chen, Qi
Cheng, Yafang
Elbert, Wolfgang
Gilles, Mary K.
Kilcoyne, Arthur L. D.
Moffet, Ryan C.
Weigand, Markus
Martin, Scot T.
Pöschl, Ulrich
Andreae, Meinrat O.
description The fine particles serving as cloud condensation nuclei in pristine Amazonian rainforest air consist mostly of secondary organic aerosol. Their origin is enigmatic, however, because new particle formation in the atmosphere is not observed. Here, we show that the growth of organic aerosol particles can be initiated by potassium-salt—rich particles emitted by biota in the rainforest. These particles act as seeds for the condensation of low- or semi-volatile organic compounds from the atmospheric gas phase or multiphase oxidation of isoprene and terpenes. Our findings suggest that the primary emission of biogenic salt particles directly influences the number concentration of cloud condensation nuclei and affects the microphysics of cloud formation and precipitation over the rainforest.
doi_str_mv 10.1126/science.1223264
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subjects Aerosols
Atmosphere - chemistry
Atmospheric aerosols
Atmospheric chemistry
Condensation
Droplets
Earth, ocean, space
Exact sciences and technology
External geophysics
Isoprene
Meteorology
Organic chemicals
Organic Chemistry
Oxidation
Particle emission
Particle mass
Particle Size
Particles and aerosols
Particulate emissions
Particulate Matter - chemistry
Plant biology
Potassium
Potassium - chemistry
Potassium salts
Rain - chemistry
Rain forests
Rainforests
Salts
Salts - chemistry
Seeds
South America
Terpenes
Trees - chemistry
Tropical rain forests
Volatile organic compounds
title Biogenic Potassium Salt Particles as Seeds for Secondary Organic Aerosol in the Amazon
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