A novel catalyst for ammonia synthesis at ambient temperature and pressure: Visible light responsive photocatalyst using localized surface plasmon resonance

A novel catalyst for ammonia synthesis using localized surface plasmon resonance (LSPR) was investigated. Os–Au composite nanoparticles showed a high catalytic activity in ammonia synthesis reaction under visible light irradiation at room temperature and atmospheric pressure. Photo energy was likely...

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Veröffentlicht in:Catalysis communications 2015-01, Vol.59, p.40-44
Hauptverfasser: Zeng, Haisheng, Terazono, Shinji, Tanuma, Toshihiro
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creator Zeng, Haisheng
Terazono, Shinji
Tanuma, Toshihiro
description A novel catalyst for ammonia synthesis using localized surface plasmon resonance (LSPR) was investigated. Os–Au composite nanoparticles showed a high catalytic activity in ammonia synthesis reaction under visible light irradiation at room temperature and atmospheric pressure. Photo energy was likely to be transferred to Os via Au particles, and contributed to the enhancement of the catalytic activity, because the ammonia production rate and the LSPR absorbance of Au particles showed similar dependence on the irradiation wavelength. [Display omitted] •A novel photocatalyst for ammonia synthesis at room temperature was investigated.•Os–Au showed a catalytic activity for ammonia synthesis under visible light irradiation.•Localized surface plasmon resonance was suggested to play the role in photocatalytic activity.
doi_str_mv 10.1016/j.catcom.2014.09.034
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source Open Access Titles of Japan; Elsevier ScienceDirect Journals; EZB-FREE-00999 freely available EZB journals
subjects Ammonia
Ammonia synthesis
Catalysts
Catalytic activity
Localized surface plasmon resonance
Particulate composites
Photocatalyst
Plasmons
Surface chemistry
Synthesis
Synthesis (chemistry)
title A novel catalyst for ammonia synthesis at ambient temperature and pressure: Visible light responsive photocatalyst using localized surface plasmon resonance
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