The controlled synthesis of polyglucose in one-dimensional coordination nanochannels
We demonstrate a feasible method for the preparation of polyglucose (PGlc) with controlled structures, where the polymerization of glucose monomers was performed using one-dimensional nanochannels of [La(1,3,5-benzenetrisbenzoate)(H 2 O)] n ( 1 ). Cationic ring-opening polymerization of 1,6-anhydro-...
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2016-04, Vol.52 (29), p.5156-5159 |
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| container_title | Chemical communications (Cambridge, England) |
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| creator | Kobayashi, Yuichiro Horie, Yuki Honjo, Kayako Uemura, Takashi Kitagawa, Susumu |
| description | We demonstrate a feasible method for the preparation of polyglucose (PGlc) with controlled structures, where the polymerization of glucose monomers was performed using one-dimensional nanochannels of [La(1,3,5-benzenetrisbenzoate)(H
2
O)]
n
(
1
). Cationic ring-opening polymerization of 1,6-anhydro-β-
d
-glucose (
levo
glucosan) using
1
gave a quasi-linear PGlc, which contrasts highly with the results obtained from conventional polymerizations in bulk and solution. The regulated structure of PGlc prepared using the PCP led to a remarkable improvement in the processability and thermal stability of PGlc, which is useful in applications as a bioplastic.
Ring-opening polymerization of 1,6-anhydro-β-
d
-glucose in one-dimensional nanochannels of a porous coordination polymer gave a quasi-linear polyglucose without cross-linking. |
| doi_str_mv | 10.1039/c6cc01357k |
| format | Article |
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2
O)]
n
(
1
). Cationic ring-opening polymerization of 1,6-anhydro-β-
d
-glucose (
levo
glucosan) using
1
gave a quasi-linear PGlc, which contrasts highly with the results obtained from conventional polymerizations in bulk and solution. The regulated structure of PGlc prepared using the PCP led to a remarkable improvement in the processability and thermal stability of PGlc, which is useful in applications as a bioplastic.
Ring-opening polymerization of 1,6-anhydro-β-
d
-glucose in one-dimensional nanochannels of a porous coordination polymer gave a quasi-linear polyglucose without cross-linking.</description><identifier>ISSN: 1359-7345</identifier><identifier>EISSN: 1364-548X</identifier><identifier>DOI: 10.1039/c6cc01357k</identifier><identifier>PMID: 26996883</identifier><language>eng</language><publisher>England</publisher><subject>Benzoates - chemistry ; Biodegradable ; Bulk polymerization ; Cationic ; Glucans - chemical synthesis ; Glucans - chemistry ; Glucose ; Glucose - analogs & derivatives ; Glucose - chemical synthesis ; Glucose - chemistry ; Models, Molecular ; Monomers ; Nanostructure ; Nanostructures - chemistry ; Nanostructures - ultrastructure ; Polymerization ; Synthesis</subject><ispartof>Chemical communications (Cambridge, England), 2016-04, Vol.52 (29), p.5156-5159</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c408t-6cd7ade45936a8a293152a4d1adc0bec6210fd6b9952a38f3c0e5a9655470f293</citedby><cites>FETCH-LOGICAL-c408t-6cd7ade45936a8a293152a4d1adc0bec6210fd6b9952a38f3c0e5a9655470f293</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/26996883$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Kobayashi, Yuichiro</creatorcontrib><creatorcontrib>Horie, Yuki</creatorcontrib><creatorcontrib>Honjo, Kayako</creatorcontrib><creatorcontrib>Uemura, Takashi</creatorcontrib><creatorcontrib>Kitagawa, Susumu</creatorcontrib><title>The controlled synthesis of polyglucose in one-dimensional coordination nanochannels</title><title>Chemical communications (Cambridge, England)</title><addtitle>Chem Commun (Camb)</addtitle><description>We demonstrate a feasible method for the preparation of polyglucose (PGlc) with controlled structures, where the polymerization of glucose monomers was performed using one-dimensional nanochannels of [La(1,3,5-benzenetrisbenzoate)(H
2
O)]
n
(
1
). Cationic ring-opening polymerization of 1,6-anhydro-β-
d
-glucose (
levo
glucosan) using
1
gave a quasi-linear PGlc, which contrasts highly with the results obtained from conventional polymerizations in bulk and solution. The regulated structure of PGlc prepared using the PCP led to a remarkable improvement in the processability and thermal stability of PGlc, which is useful in applications as a bioplastic.
Ring-opening polymerization of 1,6-anhydro-β-
d
-glucose in one-dimensional nanochannels of a porous coordination polymer gave a quasi-linear polyglucose without cross-linking.</description><subject>Benzoates - chemistry</subject><subject>Biodegradable</subject><subject>Bulk polymerization</subject><subject>Cationic</subject><subject>Glucans - chemical synthesis</subject><subject>Glucans - chemistry</subject><subject>Glucose</subject><subject>Glucose - analogs & derivatives</subject><subject>Glucose - chemical synthesis</subject><subject>Glucose - chemistry</subject><subject>Models, Molecular</subject><subject>Monomers</subject><subject>Nanostructure</subject><subject>Nanostructures - chemistry</subject><subject>Nanostructures - ultrastructure</subject><subject>Polymerization</subject><subject>Synthesis</subject><issn>1359-7345</issn><issn>1364-548X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqFkbtPwzAQxi0EoqWwsIMyIqSAHT9ijyjiJSqxFIktcu0LDbh2sZOh_z0phTJyy71-9w3fIXRK8BXBVF0bYQwmlJcfe2hMqGA5Z_J1f1NzlZeU8RE6SukdD0G4PESjQiglpKRjNJstIDPBdzE4BzZLa98tILUpC022Cm795noTEmStz4KH3LZL8KkNXrvhLETbet0Nbea1D2ahvQeXjtFBo12Ck588QS93t7PqIZ8-3z9WN9PcMCy7XBhbaguMKyq01IWihBeaWaKtwXMwoiC4sWKu1DCmsqEGA9dKcM5K3Az4BF1sdVcxfPaQunrZJgPOaQ-hTzWRWBLMKOb_o2VZKkmYZAN6uUVNDClFaOpVbJc6rmuC643hdSWq6tvwpwE-_9Ht50uwO_TX4QE42wIxmd3272P0C6_Zhfo</recordid><startdate>20160414</startdate><enddate>20160414</enddate><creator>Kobayashi, Yuichiro</creator><creator>Horie, Yuki</creator><creator>Honjo, Kayako</creator><creator>Uemura, Takashi</creator><creator>Kitagawa, Susumu</creator><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20160414</creationdate><title>The controlled synthesis of polyglucose in one-dimensional coordination nanochannels</title><author>Kobayashi, Yuichiro ; Horie, Yuki ; Honjo, Kayako ; Uemura, Takashi ; Kitagawa, Susumu</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c408t-6cd7ade45936a8a293152a4d1adc0bec6210fd6b9952a38f3c0e5a9655470f293</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Benzoates - chemistry</topic><topic>Biodegradable</topic><topic>Bulk polymerization</topic><topic>Cationic</topic><topic>Glucans - chemical synthesis</topic><topic>Glucans - chemistry</topic><topic>Glucose</topic><topic>Glucose - analogs & derivatives</topic><topic>Glucose - chemical synthesis</topic><topic>Glucose - chemistry</topic><topic>Models, Molecular</topic><topic>Monomers</topic><topic>Nanostructure</topic><topic>Nanostructures - chemistry</topic><topic>Nanostructures - ultrastructure</topic><topic>Polymerization</topic><topic>Synthesis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kobayashi, Yuichiro</creatorcontrib><creatorcontrib>Horie, Yuki</creatorcontrib><creatorcontrib>Honjo, Kayako</creatorcontrib><creatorcontrib>Uemura, Takashi</creatorcontrib><creatorcontrib>Kitagawa, Susumu</creatorcontrib><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Chemical communications (Cambridge, England)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kobayashi, Yuichiro</au><au>Horie, Yuki</au><au>Honjo, Kayako</au><au>Uemura, Takashi</au><au>Kitagawa, Susumu</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>The controlled synthesis of polyglucose in one-dimensional coordination nanochannels</atitle><jtitle>Chemical communications (Cambridge, England)</jtitle><addtitle>Chem Commun (Camb)</addtitle><date>2016-04-14</date><risdate>2016</risdate><volume>52</volume><issue>29</issue><spage>5156</spage><epage>5159</epage><pages>5156-5159</pages><issn>1359-7345</issn><eissn>1364-548X</eissn><abstract>We demonstrate a feasible method for the preparation of polyglucose (PGlc) with controlled structures, where the polymerization of glucose monomers was performed using one-dimensional nanochannels of [La(1,3,5-benzenetrisbenzoate)(H
2
O)]
n
(
1
). Cationic ring-opening polymerization of 1,6-anhydro-β-
d
-glucose (
levo
glucosan) using
1
gave a quasi-linear PGlc, which contrasts highly with the results obtained from conventional polymerizations in bulk and solution. The regulated structure of PGlc prepared using the PCP led to a remarkable improvement in the processability and thermal stability of PGlc, which is useful in applications as a bioplastic.
Ring-opening polymerization of 1,6-anhydro-β-
d
-glucose in one-dimensional nanochannels of a porous coordination polymer gave a quasi-linear polyglucose without cross-linking.</abstract><cop>England</cop><pmid>26996883</pmid><doi>10.1039/c6cc01357k</doi><tpages>4</tpages></addata></record> |
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| ispartof | Chemical communications (Cambridge, England), 2016-04, Vol.52 (29), p.5156-5159 |
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| language | eng |
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| source | MEDLINE; Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Benzoates - chemistry Biodegradable Bulk polymerization Cationic Glucans - chemical synthesis Glucans - chemistry Glucose Glucose - analogs & derivatives Glucose - chemical synthesis Glucose - chemistry Models, Molecular Monomers Nanostructure Nanostructures - chemistry Nanostructures - ultrastructure Polymerization Synthesis |
| title | The controlled synthesis of polyglucose in one-dimensional coordination nanochannels |
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