Hydrogen-bonding and vibrational coupling of water in a hydrophobic hydration shell as observed by Raman-MCR and isotopic dilution spectroscopy

Hydrogen-bonding and intra/intermolecular vibrational coupling of water next to a hydrophobic molecule ( tert -butyl alcohol, TBA) have been studied by Raman multivariate curve resolution (Raman-MCR) and isotopic dilution spectroscopy. Raman-MCR provides the vibrational spectrum of water pertinent t...

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Veröffentlicht in:	Physical chemistry chemical physics : PCCP 2016-01, Vol.18 (4), p.2767-2775
Hauptverfasser:	Ahmed, Mohammed, Singh, Ajay K, Mondal, Jahur A
Format:	Artikel
Sprache:	eng
Schlagworte:	Band spectra Coupling Coupling (molecular) Dilution Hydration Hydrogen bonding Physical chemistry Spectroscopy
Online-Zugang:	Volltext
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