1,3,5-Trinitroperhydro-1,3,5-triazine (RDX)-Based Sheet Explosive Formulation with a Hybrid Binder System

A plastic‐bonded explosive (PBX) in the form of a sheet was formulated comprising of 1,3,5‐trinitroperhydro‐1,3,5‐triazine (RDX) and an hybrid binder system containing a linear thermoplastic polyurethane and a fluoroelastomer (Viton). The effect of a fluoroelastomer on the explosive as well as mecha...

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Veröffentlicht in:Propellants, explosives, pyrotechnics explosives, pyrotechnics, 2016-04, Vol.41 (2), p.377-382
Hauptverfasser: Jangid, Suresh Kumar, Singh, Mrityunjay Kumar, Solanki, Vasant Jadavji, Talawar, Mahadev Bhimappa, Nath, Tribhuvan, Sinha, Rabindra Kumar, Asthana, Srinandan
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container_end_page 382
container_issue 2
container_start_page 377
container_title Propellants, explosives, pyrotechnics
container_volume 41
creator Jangid, Suresh Kumar
Singh, Mrityunjay Kumar
Solanki, Vasant Jadavji
Talawar, Mahadev Bhimappa
Nath, Tribhuvan
Sinha, Rabindra Kumar
Asthana, Srinandan
description A plastic‐bonded explosive (PBX) in the form of a sheet was formulated comprising of 1,3,5‐trinitroperhydro‐1,3,5‐triazine (RDX) and an hybrid binder system containing a linear thermoplastic polyurethane and a fluoroelastomer (Viton). The effect of a fluoroelastomer on the explosive as well as mechanical properties and thermal behavior of sheet explosive formulations were investigated and compared with a control formulation containing 90 % of RDX and 10 % of natural rubber (ISNR‐5). The replacement of 10 % natural rubber by a hybrid binder system led to an increase in the velocity of detonation (VOD) of the order of 250–950 m s−1 and better mechanical properties in terms of tensile strength (1.9–2.5 MPa) compared to the control formulation (RDX/ISNR‐5 (90/10)). The compatibility of ingredients and thermal decomposition kinetics of selected sheet explosive formulations were investigated by vacuum stability tests and differential scanning calorimetry (DSC). The results suggested better compatibility of RDX with the hybrid binder system (polyurethane/Viton), which is useful to reduce potential hazards in handling, processing, and storage.
doi_str_mv 10.1002/prep.201500193
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subjects Activation energy
Binders
Explosions
Explosive forming
Fluoropolymers
Formulations
Hybrid binder system
Hybrid systems
Natural rubber
Product design
RDX
Sheet explosives
Velocity of detonation (VOD)
title 1,3,5-Trinitroperhydro-1,3,5-triazine (RDX)-Based Sheet Explosive Formulation with a Hybrid Binder System
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