1,3,5-Trinitroperhydro-1,3,5-triazine (RDX)-Based Sheet Explosive Formulation with a Hybrid Binder System
A plastic‐bonded explosive (PBX) in the form of a sheet was formulated comprising of 1,3,5‐trinitroperhydro‐1,3,5‐triazine (RDX) and an hybrid binder system containing a linear thermoplastic polyurethane and a fluoroelastomer (Viton). The effect of a fluoroelastomer on the explosive as well as mecha...
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Veröffentlicht in: | Propellants, explosives, pyrotechnics explosives, pyrotechnics, 2016-04, Vol.41 (2), p.377-382 |
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creator | Jangid, Suresh Kumar Singh, Mrityunjay Kumar Solanki, Vasant Jadavji Talawar, Mahadev Bhimappa Nath, Tribhuvan Sinha, Rabindra Kumar Asthana, Srinandan |
description | A plastic‐bonded explosive (PBX) in the form of a sheet was formulated comprising of 1,3,5‐trinitroperhydro‐1,3,5‐triazine (RDX) and an hybrid binder system containing a linear thermoplastic polyurethane and a fluoroelastomer (Viton). The effect of a fluoroelastomer on the explosive as well as mechanical properties and thermal behavior of sheet explosive formulations were investigated and compared with a control formulation containing 90 % of RDX and 10 % of natural rubber (ISNR‐5). The replacement of 10 % natural rubber by a hybrid binder system led to an increase in the velocity of detonation (VOD) of the order of 250–950 m s−1 and better mechanical properties in terms of tensile strength (1.9–2.5 MPa) compared to the control formulation (RDX/ISNR‐5 (90/10)). The compatibility of ingredients and thermal decomposition kinetics of selected sheet explosive formulations were investigated by vacuum stability tests and differential scanning calorimetry (DSC). The results suggested better compatibility of RDX with the hybrid binder system (polyurethane/Viton), which is useful to reduce potential hazards in handling, processing, and storage. |
doi_str_mv | 10.1002/prep.201500193 |
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The effect of a fluoroelastomer on the explosive as well as mechanical properties and thermal behavior of sheet explosive formulations were investigated and compared with a control formulation containing 90 % of RDX and 10 % of natural rubber (ISNR‐5). The replacement of 10 % natural rubber by a hybrid binder system led to an increase in the velocity of detonation (VOD) of the order of 250–950 m s−1 and better mechanical properties in terms of tensile strength (1.9–2.5 MPa) compared to the control formulation (RDX/ISNR‐5 (90/10)). The compatibility of ingredients and thermal decomposition kinetics of selected sheet explosive formulations were investigated by vacuum stability tests and differential scanning calorimetry (DSC). The results suggested better compatibility of RDX with the hybrid binder system (polyurethane/Viton), which is useful to reduce potential hazards in handling, processing, and storage.</description><identifier>ISSN: 0721-3115</identifier><identifier>EISSN: 1521-4087</identifier><identifier>DOI: 10.1002/prep.201500193</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag</publisher><subject>Activation energy ; Binders ; Explosions ; Explosive forming ; Fluoropolymers ; Formulations ; Hybrid binder system ; Hybrid systems ; Natural rubber ; Product design ; RDX ; Sheet explosives ; Velocity of detonation (VOD)</subject><ispartof>Propellants, explosives, pyrotechnics, 2016-04, Vol.41 (2), p.377-382</ispartof><rights>2016 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>2016 WILEY-VCH Verlag GmbH & Co. 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The effect of a fluoroelastomer on the explosive as well as mechanical properties and thermal behavior of sheet explosive formulations were investigated and compared with a control formulation containing 90 % of RDX and 10 % of natural rubber (ISNR‐5). The replacement of 10 % natural rubber by a hybrid binder system led to an increase in the velocity of detonation (VOD) of the order of 250–950 m s−1 and better mechanical properties in terms of tensile strength (1.9–2.5 MPa) compared to the control formulation (RDX/ISNR‐5 (90/10)). The compatibility of ingredients and thermal decomposition kinetics of selected sheet explosive formulations were investigated by vacuum stability tests and differential scanning calorimetry (DSC). The results suggested better compatibility of RDX with the hybrid binder system (polyurethane/Viton), which is useful to reduce potential hazards in handling, processing, and storage.</description><subject>Activation energy</subject><subject>Binders</subject><subject>Explosions</subject><subject>Explosive forming</subject><subject>Fluoropolymers</subject><subject>Formulations</subject><subject>Hybrid binder system</subject><subject>Hybrid systems</subject><subject>Natural rubber</subject><subject>Product design</subject><subject>RDX</subject><subject>Sheet explosives</subject><subject>Velocity of detonation (VOD)</subject><issn>0721-3115</issn><issn>1521-4087</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNqFkM9L5DAYQMOyws7qXj0H9qJgx3xN2zRHnR1HQdbBH4zsJaTtVybaabpJZ7X71xupiOxlCSHh470QHiH7wKbAWHzcOeymMYOUMZD8E5lAGkOUsFx8JhMmwp0DpF_IV-8fAsLCnhADR_wojW6daU3vbIduPVTORuO4d0b_NS3Sg-sf94fRqfZY0Zs1Yk_nz11jvfmD9My6zbbRvbEtfTL9mmp6PhTOVPTUtBU6ejP4Hjd7ZKfWjcdvb-cuuTub387Oo8urxcXs5DIqeZ7zKC-qKskkS2IJgktW8jqMyjyDMq5Ri6IooeY8SzItslSmtYBCJ8BEwoukQMl3ycH4bufs7y36Xm2ML7FpdIt26xXkLCzJWRzQ7_-gD3br2vA7BSIHkYV4eaCmI1U6673DWnXObLQbFDD1Wl69llfv5YMgR-HJNDj8h1bL6_nyoxuNrgnNnt9d7R5VJrhI1ernQq3ihZytlr_UjL8AFxCUmA</recordid><startdate>201604</startdate><enddate>201604</enddate><creator>Jangid, Suresh Kumar</creator><creator>Singh, Mrityunjay Kumar</creator><creator>Solanki, Vasant Jadavji</creator><creator>Talawar, Mahadev Bhimappa</creator><creator>Nath, Tribhuvan</creator><creator>Sinha, Rabindra Kumar</creator><creator>Asthana, Srinandan</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><general>Wiley Subscription Services, Inc</general><scope>BSCLL</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7TB</scope><scope>8FD</scope><scope>FR3</scope><scope>H8D</scope><scope>L7M</scope></search><sort><creationdate>201604</creationdate><title>1,3,5-Trinitroperhydro-1,3,5-triazine (RDX)-Based Sheet Explosive Formulation with a Hybrid Binder System</title><author>Jangid, Suresh Kumar ; Singh, Mrityunjay Kumar ; Solanki, Vasant Jadavji ; Talawar, Mahadev Bhimappa ; Nath, Tribhuvan ; Sinha, Rabindra Kumar ; Asthana, Srinandan</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3883-8bdd469042917390c3f8bdc861c2fea7bbc1f33646a76595f71ba410743b4be93</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Activation energy</topic><topic>Binders</topic><topic>Explosions</topic><topic>Explosive forming</topic><topic>Fluoropolymers</topic><topic>Formulations</topic><topic>Hybrid binder system</topic><topic>Hybrid systems</topic><topic>Natural rubber</topic><topic>Product design</topic><topic>RDX</topic><topic>Sheet explosives</topic><topic>Velocity of detonation (VOD)</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Jangid, Suresh Kumar</creatorcontrib><creatorcontrib>Singh, Mrityunjay Kumar</creatorcontrib><creatorcontrib>Solanki, Vasant Jadavji</creatorcontrib><creatorcontrib>Talawar, Mahadev Bhimappa</creatorcontrib><creatorcontrib>Nath, Tribhuvan</creatorcontrib><creatorcontrib>Sinha, Rabindra Kumar</creatorcontrib><creatorcontrib>Asthana, Srinandan</creatorcontrib><collection>Istex</collection><collection>CrossRef</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>Technology Research Database</collection><collection>Engineering Research Database</collection><collection>Aerospace Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Propellants, explosives, pyrotechnics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Jangid, Suresh Kumar</au><au>Singh, Mrityunjay Kumar</au><au>Solanki, Vasant Jadavji</au><au>Talawar, Mahadev Bhimappa</au><au>Nath, Tribhuvan</au><au>Sinha, Rabindra Kumar</au><au>Asthana, Srinandan</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>1,3,5-Trinitroperhydro-1,3,5-triazine (RDX)-Based Sheet Explosive Formulation with a Hybrid Binder System</atitle><jtitle>Propellants, explosives, pyrotechnics</jtitle><addtitle>Propellants, Explosives, Pyrotechnics</addtitle><date>2016-04</date><risdate>2016</risdate><volume>41</volume><issue>2</issue><spage>377</spage><epage>382</epage><pages>377-382</pages><issn>0721-3115</issn><eissn>1521-4087</eissn><abstract>A plastic‐bonded explosive (PBX) in the form of a sheet was formulated comprising of 1,3,5‐trinitroperhydro‐1,3,5‐triazine (RDX) and an hybrid binder system containing a linear thermoplastic polyurethane and a fluoroelastomer (Viton). The effect of a fluoroelastomer on the explosive as well as mechanical properties and thermal behavior of sheet explosive formulations were investigated and compared with a control formulation containing 90 % of RDX and 10 % of natural rubber (ISNR‐5). The replacement of 10 % natural rubber by a hybrid binder system led to an increase in the velocity of detonation (VOD) of the order of 250–950 m s−1 and better mechanical properties in terms of tensile strength (1.9–2.5 MPa) compared to the control formulation (RDX/ISNR‐5 (90/10)). The compatibility of ingredients and thermal decomposition kinetics of selected sheet explosive formulations were investigated by vacuum stability tests and differential scanning calorimetry (DSC). The results suggested better compatibility of RDX with the hybrid binder system (polyurethane/Viton), which is useful to reduce potential hazards in handling, processing, and storage.</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag</pub><doi>10.1002/prep.201500193</doi><tpages>6</tpages></addata></record> |
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subjects | Activation energy Binders Explosions Explosive forming Fluoropolymers Formulations Hybrid binder system Hybrid systems Natural rubber Product design RDX Sheet explosives Velocity of detonation (VOD) |
title | 1,3,5-Trinitroperhydro-1,3,5-triazine (RDX)-Based Sheet Explosive Formulation with a Hybrid Binder System |
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