Role(s) of TMA in polymerization

Quenched-flow data for propene polymerization with rac -Me 2 Si(2-Me-4-Ph-1-indenyl) 2 ZrCl 2 /MAO support a picture where removal of MAO qualitatively changes the kinetic profile from a mainly enthalpic to a mainly entropic barrier. DFT studies suggest that a not previously recognized singly-bridge...

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Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2016-04, Vol.45 (16), p.6847-6855
Hauptverfasser:	Ehm, C, Cipullo, R, Budzelaar, P. H. M, Busico, V
Format:	Artikel
Sprache:	eng
Schlagworte:	Barriers Catalysis Chain transfer Pictures Polymerization Reaction kinetics
Online-Zugang:	Volltext
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