Highly efficient and reusable CNT supported iron(ii) catalyst for microwave assisted alcohol oxidation

Highly efficient and reusable CNT supported iron(ii) catalyst for microwave assisted alcohol oxidation

The highly efficient eco-friendly synthesis of ketones (yields over 99%) from secondary alcohols is achieved by combination of [FeCl2{η(3)-HC(pz)3}] (pz = pyrazol-1-yl) supported on functionalized multi-walled carbon nanotubes and microwave irradiation, in a solvent-free medium. The carbon homoscorp...

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Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2016-01, Vol.45 (16), p.6816-6819
Hauptverfasser: Martins, L M D R S, Ribeiro, A P C, Carabineiro, S A C, Figueiredo, J L, Pombeiro, A J L
Format: Artikel
Sprache:eng
Schlagworte:
Alcohols
Carbon
Catalysts
Ketones
Microwaves
Multi wall carbon nanotubes
Oxidation
Synthesis
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Zusammenfassung:The highly efficient eco-friendly synthesis of ketones (yields over 99%) from secondary alcohols is achieved by combination of [FeCl2{η(3)-HC(pz)3}] (pz = pyrazol-1-yl) supported on functionalized multi-walled carbon nanotubes and microwave irradiation, in a solvent-free medium. The carbon homoscorpionate iron(ii) complex is the first one of this class to be used as catalyst for the oxidation of alcohols.
ISSN:1477-9226
1477-9234
DOI:10.1039/c6dt00514d