The performance of benzenesulfonic acid catalyst on the alkylation of thiophenic sulfur
Catalytic performance of benzenesulfonic acid was investigated for alkylation of thiophenic sulfur compounds with diene. The alkylates were confirmed by gas chromatography–mass spectrometry technique. The reaction conditions were optimized as follows: temperature is 85 °C, catalyst/feed weight ratio...
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| Veröffentlicht in: | Applied petrochemical research 2016-03, Vol.6 (1), p.35-40 |
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| creator | Shen, Zhibing Zhang, Juntao Ren, Tao Liang, Shengrong |
| description | Catalytic performance of benzenesulfonic acid was investigated for alkylation of thiophenic sulfur compounds with diene. The alkylates were confirmed by gas chromatography–mass spectrometry technique. The reaction conditions were optimized as follows: temperature is 85 °C, catalyst/feed weight ratio is 10 % and time is 80 min. Under the conditions, the conversion of thiophene was nearly 73 %. The catalyst exhibited some recycle-use performance. The catalytic activity could be maintained by addition of the fresh catalyst periodically and quantitatively. |
| doi_str_mv | 10.1007/s13203-015-0116-z |
| format | Article |
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The alkylates were confirmed by gas chromatography–mass spectrometry technique. The reaction conditions were optimized as follows: temperature is 85 °C, catalyst/feed weight ratio is 10 % and time is 80 min. Under the conditions, the conversion of thiophene was nearly 73 %. The catalyst exhibited some recycle-use performance. The catalytic activity could be maintained by addition of the fresh catalyst periodically and quantitatively.</description><subject>Alkylates</subject><subject>Alkylation</subject><subject>Catalysis</subject><subject>Catalysts</subject><subject>Catalytic activity</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Conversion</subject><subject>Energy Systems</subject><subject>Gas chromatography</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Mass spectrometry</subject><subject>Nanochemistry</subject><subject>Nanotechnology and Microengineering</subject><subject>Original Article</subject><subject>Sulfur</subject><subject>Thiophenes</subject><issn>2190-5525</issn><issn>2190-5525</issn><issn>2190-5533</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><sourceid>C6C</sourceid><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp1kMtKAzEUhoMoWGofwN2AGzejuTSTZCnFGxTcVFyGNHNip06Tmsws2qc3w7goggnhJOT7DocfoWuC7wjG4j4RRjErMeH5kKo8nqEJJQqXnFN-fnK_RLOUtjgvLpQScoI-Vhso9hBdiDvjLRTBFWvwR_CQ-tYF39jC2KYurOlMe0hdEXzRZce0X4fWdE1-ZqXbNGG_gYEetD5eoQtn2gSz3zpF70-Pq8VLuXx7fl08LEvLKO1KWtfMAti5dEKtHXNSCikwI1xyxtfW8jyloyCEccJwRVQ9x8LKGirBGOVsim7HvvsYvntInd41yULbGg-hT5pInDfDQmX05g-6DX30eTpNRP6fV6oimSIjZWNIKYLT-9jsTDxogvWQth7T1jltPaStj9mho5My6z8hnnT-V_oBu0uCXA</recordid><startdate>20160301</startdate><enddate>20160301</enddate><creator>Shen, Zhibing</creator><creator>Zhang, Juntao</creator><creator>Ren, Tao</creator><creator>Liang, Shengrong</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>C6C</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AEUYN</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>BHPHI</scope><scope>BKSAR</scope><scope>CCPQU</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>L6V</scope><scope>M7S</scope><scope>PCBAR</scope><scope>PIMPY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PTHSS</scope><scope>7TB</scope><scope>8FD</scope><scope>FR3</scope><scope>KR7</scope></search><sort><creationdate>20160301</creationdate><title>The performance of benzenesulfonic acid catalyst on the alkylation of thiophenic sulfur</title><author>Shen, Zhibing ; 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The alkylates were confirmed by gas chromatography–mass spectrometry technique. The reaction conditions were optimized as follows: temperature is 85 °C, catalyst/feed weight ratio is 10 % and time is 80 min. Under the conditions, the conversion of thiophene was nearly 73 %. The catalyst exhibited some recycle-use performance. The catalytic activity could be maintained by addition of the fresh catalyst periodically and quantitatively.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s13203-015-0116-z</doi><tpages>6</tpages><oa>free_for_read</oa></addata></record> |
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| subjects | Alkylates Alkylation Catalysis Catalysts Catalytic activity Chemistry Chemistry and Materials Science Conversion Energy Systems Gas chromatography Industrial Chemistry/Chemical Engineering Mass spectrometry Nanochemistry Nanotechnology and Microengineering Original Article Sulfur Thiophenes |
| title | The performance of benzenesulfonic acid catalyst on the alkylation of thiophenic sulfur |
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