Dodenuclear [Mn(III)(8)Ln(III)(4)] clusters with 2-(hydroxymethyl)pyridine: syntheses, structures, and magnetic properties

A new family of isostructural Mn/Ln dodenuclear clusters: [Mn8Ln4(O)8(hmp)4(O2CPh)12(NO3)4(PhCO2H)(C2H5OH)] [Ln = La (1), Pr (2), Nd (3), Gd (4), Dy(5), hmpH = 2-(hydroxymethyl)pyridine] have been synthesized by the reaction of Mn(NO3)2 and Ln(NO3)3·6H2O with hmpH and benzoic acid as co-ligands. Com...

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Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2015-01, Vol.44 (48), p.20964-20971
Hauptverfasser:	Sun, Lei, Chen, Hui, Ma, Chengbing, Chen, Changneng
Format:	Artikel
Sprache:	eng
Schlagworte:	Clusters Cubane Displays Entropy Ferromagnetism Magnetic permeability Magnetic properties Manganese
Online-Zugang:	Volltext
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