Vapor pressure and sublimation thermodynamics of aminobenzoic acid, nicotinic acid, and related amido-derivatives
The inert gas transpiration technique was used for measuring the vapor pressures of the following biologically active compounds: 4-aminobenzoic acid, nicotinic acid, 4-aminobenzamide, 4-pyridinecarboxamide, N -(2-chloro-3-pyridinyl)-benzenesulfonamide, 4-nitro- N -2-thiazolyl-benzenesulfonamide, and...
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| Veröffentlicht in: | Journal of thermal analysis and calorimetry 2016-01, Vol.123 (1), p.841-849 |
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| container_title | Journal of thermal analysis and calorimetry |
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| creator | Volkova, Tatyana V. Blokhina, Svetlana V. Ryzhakov, Alex M. Sharapova, Angelica V. Ol’khovich, Marina V. Perlovich, German L. |
| description | The inert gas transpiration technique was used for measuring the vapor pressures of the following biologically active compounds: 4-aminobenzoic acid, nicotinic acid, 4-aminobenzamide, 4-pyridinecarboxamide,
N
-(2-chloro-3-pyridinyl)-benzenesulfonamide, 4-nitro-
N
-2-thiazolyl-benzenesulfonamide, and 4-amino-
N
-(5-methyl-3-isoxazolyl)-benzenesulfon-amide in the appropriate temperature ranges. Differential scanning calorimetric analysis was applied to obtain the temperature and molar enthalpy of melting of the compounds studied. Standard molar enthalpies, entropies, and Gibbs energies of sublimation were derived at
T
= 298.15 K from the temperature dependences of the vapor pressure of the compounds. The obtained results allowed the estimation of the relationship between the sublimation thermodynamic parameters and the thermophysical properties of the substances. Correlation equations were used for calculating the saturated vapor pressures on the basis of the melting temperatures, sublimation enthalpies, and physicochemical HYBOT descriptors. |
| doi_str_mv | 10.1007/s10973-015-4969-2 |
| format | Article |
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N
-(2-chloro-3-pyridinyl)-benzenesulfonamide, 4-nitro-
N
-2-thiazolyl-benzenesulfonamide, and 4-amino-
N
-(5-methyl-3-isoxazolyl)-benzenesulfon-amide in the appropriate temperature ranges. Differential scanning calorimetric analysis was applied to obtain the temperature and molar enthalpy of melting of the compounds studied. Standard molar enthalpies, entropies, and Gibbs energies of sublimation were derived at
T
= 298.15 K from the temperature dependences of the vapor pressure of the compounds. The obtained results allowed the estimation of the relationship between the sublimation thermodynamic parameters and the thermophysical properties of the substances. Correlation equations were used for calculating the saturated vapor pressures on the basis of the melting temperatures, sublimation enthalpies, and physicochemical HYBOT descriptors.</description><identifier>ISSN: 1388-6150</identifier><identifier>EISSN: 1588-2926</identifier><identifier>EISSN: 1572-8943</identifier><identifier>DOI: 10.1007/s10973-015-4969-2</identifier><language>eng</language><publisher>Dordrecht: Springer Netherlands</publisher><subject>Analysis ; Analytical Chemistry ; Calorimetry ; Chemistry ; Chemistry and Materials Science ; Enthalpy ; Inorganic Chemistry ; Mathematical analysis ; Measurement Science and Instrumentation ; Melting ; Niacin ; Nicotinic acid ; Physical Chemistry ; Polymer Sciences ; Pyridine ; Sublimation ; Thermodynamics ; Vapor pressure</subject><ispartof>Journal of thermal analysis and calorimetry, 2016-01, Vol.123 (1), p.841-849</ispartof><rights>Akadémiai Kiadó, Budapest, Hungary 2015</rights><rights>COPYRIGHT 2016 Springer</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c529t-447ef21ef23ca6cdbe89d02ea254d4e6950d1922758c7c250611c9f0a244fabe3</citedby><cites>FETCH-LOGICAL-c529t-447ef21ef23ca6cdbe89d02ea254d4e6950d1922758c7c250611c9f0a244fabe3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10973-015-4969-2$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10973-015-4969-2$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Volkova, Tatyana V.</creatorcontrib><creatorcontrib>Blokhina, Svetlana V.</creatorcontrib><creatorcontrib>Ryzhakov, Alex M.</creatorcontrib><creatorcontrib>Sharapova, Angelica V.</creatorcontrib><creatorcontrib>Ol’khovich, Marina V.</creatorcontrib><creatorcontrib>Perlovich, German L.</creatorcontrib><title>Vapor pressure and sublimation thermodynamics of aminobenzoic acid, nicotinic acid, and related amido-derivatives</title><title>Journal of thermal analysis and calorimetry</title><addtitle>J Therm Anal Calorim</addtitle><description>The inert gas transpiration technique was used for measuring the vapor pressures of the following biologically active compounds: 4-aminobenzoic acid, nicotinic acid, 4-aminobenzamide, 4-pyridinecarboxamide,
N
-(2-chloro-3-pyridinyl)-benzenesulfonamide, 4-nitro-
N
-2-thiazolyl-benzenesulfonamide, and 4-amino-
N
-(5-methyl-3-isoxazolyl)-benzenesulfon-amide in the appropriate temperature ranges. Differential scanning calorimetric analysis was applied to obtain the temperature and molar enthalpy of melting of the compounds studied. Standard molar enthalpies, entropies, and Gibbs energies of sublimation were derived at
T
= 298.15 K from the temperature dependences of the vapor pressure of the compounds. The obtained results allowed the estimation of the relationship between the sublimation thermodynamic parameters and the thermophysical properties of the substances. Correlation equations were used for calculating the saturated vapor pressures on the basis of the melting temperatures, sublimation enthalpies, and physicochemical HYBOT descriptors.</description><subject>Analysis</subject><subject>Analytical Chemistry</subject><subject>Calorimetry</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Enthalpy</subject><subject>Inorganic Chemistry</subject><subject>Mathematical analysis</subject><subject>Measurement Science and Instrumentation</subject><subject>Melting</subject><subject>Niacin</subject><subject>Nicotinic acid</subject><subject>Physical Chemistry</subject><subject>Polymer Sciences</subject><subject>Pyridine</subject><subject>Sublimation</subject><subject>Thermodynamics</subject><subject>Vapor pressure</subject><issn>1388-6150</issn><issn>1588-2926</issn><issn>1572-8943</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNp9kU9LHTEUxYfSQq3tB-huwI2CozeZZCZZimgVhEL9sw15yZ1nZF7yTDJS_fTNMFJ4UEoIOTf8zlncU1XfCZwQgP40EZB92wDhDZOdbOiHao9wIRoqafex6LbojnD4XH1J6QkApASyVz0_6G2I9TZiSlPEWntbp2k1uo3OLvg6P2LcBPvq9caZVIehLsKHFfq34EytjbPHtXcmZOf_znNIxFFntDNuQ2MxupeS-ILpa_Vp0GPCb-_vfnV_eXF3ftXc_PxxfX520xhOZW4Y63GgpNzW6M7YFQppgaKmnFmGneRgiaS058L0hnLoCDFyAE0ZG_QK2_3qcMndxvA8Ycpq45LBcdQew5QUESCgbwUlBT1Y0LUeUTk_hBy1mXF1xhgVsuVcFOrkH1Q5FstugsfBlf8dw9GOoTAZf-e1nlJS17e_dlmysCaGlCIOahtLB_FVEVBzw2ppWJWG1dywosVDF08qrF9jVE9hir4s9T-mP597qKY</recordid><startdate>20160101</startdate><enddate>20160101</enddate><creator>Volkova, Tatyana V.</creator><creator>Blokhina, Svetlana V.</creator><creator>Ryzhakov, Alex M.</creator><creator>Sharapova, Angelica V.</creator><creator>Ol’khovich, Marina V.</creator><creator>Perlovich, German L.</creator><general>Springer Netherlands</general><general>Springer</general><scope>AAYXX</scope><scope>CITATION</scope><scope>ISR</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20160101</creationdate><title>Vapor pressure and sublimation thermodynamics of aminobenzoic acid, nicotinic acid, and related amido-derivatives</title><author>Volkova, Tatyana V. ; Blokhina, Svetlana V. ; Ryzhakov, Alex M. ; Sharapova, Angelica V. ; Ol’khovich, Marina V. ; Perlovich, German L.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c529t-447ef21ef23ca6cdbe89d02ea254d4e6950d1922758c7c250611c9f0a244fabe3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Analysis</topic><topic>Analytical Chemistry</topic><topic>Calorimetry</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Enthalpy</topic><topic>Inorganic Chemistry</topic><topic>Mathematical analysis</topic><topic>Measurement Science and Instrumentation</topic><topic>Melting</topic><topic>Niacin</topic><topic>Nicotinic acid</topic><topic>Physical Chemistry</topic><topic>Polymer Sciences</topic><topic>Pyridine</topic><topic>Sublimation</topic><topic>Thermodynamics</topic><topic>Vapor pressure</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Volkova, Tatyana V.</creatorcontrib><creatorcontrib>Blokhina, Svetlana V.</creatorcontrib><creatorcontrib>Ryzhakov, Alex M.</creatorcontrib><creatorcontrib>Sharapova, Angelica V.</creatorcontrib><creatorcontrib>Ol’khovich, Marina V.</creatorcontrib><creatorcontrib>Perlovich, German L.</creatorcontrib><collection>CrossRef</collection><collection>Gale In Context: Science</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Journal of thermal analysis and calorimetry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Volkova, Tatyana V.</au><au>Blokhina, Svetlana V.</au><au>Ryzhakov, Alex M.</au><au>Sharapova, Angelica V.</au><au>Ol’khovich, Marina V.</au><au>Perlovich, German L.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Vapor pressure and sublimation thermodynamics of aminobenzoic acid, nicotinic acid, and related amido-derivatives</atitle><jtitle>Journal of thermal analysis and calorimetry</jtitle><stitle>J Therm Anal Calorim</stitle><date>2016-01-01</date><risdate>2016</risdate><volume>123</volume><issue>1</issue><spage>841</spage><epage>849</epage><pages>841-849</pages><issn>1388-6150</issn><eissn>1588-2926</eissn><eissn>1572-8943</eissn><abstract>The inert gas transpiration technique was used for measuring the vapor pressures of the following biologically active compounds: 4-aminobenzoic acid, nicotinic acid, 4-aminobenzamide, 4-pyridinecarboxamide,
N
-(2-chloro-3-pyridinyl)-benzenesulfonamide, 4-nitro-
N
-2-thiazolyl-benzenesulfonamide, and 4-amino-
N
-(5-methyl-3-isoxazolyl)-benzenesulfon-amide in the appropriate temperature ranges. Differential scanning calorimetric analysis was applied to obtain the temperature and molar enthalpy of melting of the compounds studied. Standard molar enthalpies, entropies, and Gibbs energies of sublimation were derived at
T
= 298.15 K from the temperature dependences of the vapor pressure of the compounds. The obtained results allowed the estimation of the relationship between the sublimation thermodynamic parameters and the thermophysical properties of the substances. Correlation equations were used for calculating the saturated vapor pressures on the basis of the melting temperatures, sublimation enthalpies, and physicochemical HYBOT descriptors.</abstract><cop>Dordrecht</cop><pub>Springer Netherlands</pub><doi>10.1007/s10973-015-4969-2</doi><tpages>9</tpages></addata></record> |
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| subjects | Analysis Analytical Chemistry Calorimetry Chemistry Chemistry and Materials Science Enthalpy Inorganic Chemistry Mathematical analysis Measurement Science and Instrumentation Melting Niacin Nicotinic acid Physical Chemistry Polymer Sciences Pyridine Sublimation Thermodynamics Vapor pressure |
| title | Vapor pressure and sublimation thermodynamics of aminobenzoic acid, nicotinic acid, and related amido-derivatives |
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