Synthesis, characterization and thermal behavior of copper(II) complexes with pyridoxal thiosemi (PLTSC)- and S-methylisothiosemicarbazone (PLITSC)
The syntheses of complexes of Cu(II) with biological active ligand, pyridoxal thiosemicarbazone (PLTSC) and its derivative, pyridoxal S -methylisothiosemicarbazone, are described. All coordination compounds were characterized by elemental analysis, molar conductivity and infrared spectra. The crysta...
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| Veröffentlicht in: | Journal of thermal analysis and calorimetry 2016-03, Vol.123 (3), p.2069-2079 |
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| container_title | Journal of thermal analysis and calorimetry |
| container_volume | 123 |
| creator | Vojinović-Ješić, Ljiljana S. Rodić, Marko V. Barta Holló, Berta Ivković, Sonja A. Leovac, Vukadin M. Mészáros Szécsényi, Katalin |
| description | The syntheses of complexes of Cu(II) with biological active ligand, pyridoxal thiosemicarbazone (PLTSC) and its derivative, pyridoxal
S
-methylisothiosemicarbazone, are described. All coordination compounds were characterized by elemental analysis, molar conductivity and infrared spectra. The crystal and molecular structure of complexes [{Cu(μ-PLTSC)(H
2
O)}
2
](SO
4
)
2
·6H
2
O (
2
) and [{Cu(μ-PLTSC)(H
2
O)}
2
](SO
4
)
2
·2H
2
O (
2a
) is determined by single-crystal X-ray crystallography, too. The thermal decomposition of all the ligands and complexes was determined by simultaneous TG/DSC measurements. The decomposition mechanisms were compared and analyzed from the aspects of the relationships between the structures of the compounds and their thermal decomposition pattern. |
| doi_str_mv | 10.1007/s10973-015-4891-7 |
| format | Article |
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S
-methylisothiosemicarbazone, are described. All coordination compounds were characterized by elemental analysis, molar conductivity and infrared spectra. The crystal and molecular structure of complexes [{Cu(μ-PLTSC)(H
2
O)}
2
](SO
4
)
2
·6H
2
O (
2
) and [{Cu(μ-PLTSC)(H
2
O)}
2
](SO
4
)
2
·2H
2
O (
2a
) is determined by single-crystal X-ray crystallography, too. The thermal decomposition of all the ligands and complexes was determined by simultaneous TG/DSC measurements. The decomposition mechanisms were compared and analyzed from the aspects of the relationships between the structures of the compounds and their thermal decomposition pattern.</description><identifier>ISSN: 1388-6150</identifier><identifier>EISSN: 1588-2926</identifier><identifier>EISSN: 1572-8943</identifier><identifier>DOI: 10.1007/s10973-015-4891-7</identifier><language>eng</language><publisher>Dordrecht: Springer Netherlands</publisher><subject>Analytical Chemistry ; Chemistry ; Chemistry and Materials Science ; Coordination compounds ; Crystal structure ; Derivatives ; Inorganic Chemistry ; Ligands ; Measurement Science and Instrumentation ; Molecular structure ; Physical Chemistry ; Polymer Sciences ; Thermal decomposition ; Thermal properties ; X-rays</subject><ispartof>Journal of thermal analysis and calorimetry, 2016-03, Vol.123 (3), p.2069-2079</ispartof><rights>Akadémiai Kiadó, Budapest, Hungary 2015</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c428t-64c78e19d2485bf44edc128149f157ee087910dfff6700bc49f85853ee81a10b3</citedby><cites>FETCH-LOGICAL-c428t-64c78e19d2485bf44edc128149f157ee087910dfff6700bc49f85853ee81a10b3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10973-015-4891-7$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10973-015-4891-7$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Vojinović-Ješić, Ljiljana S.</creatorcontrib><creatorcontrib>Rodić, Marko V.</creatorcontrib><creatorcontrib>Barta Holló, Berta</creatorcontrib><creatorcontrib>Ivković, Sonja A.</creatorcontrib><creatorcontrib>Leovac, Vukadin M.</creatorcontrib><creatorcontrib>Mészáros Szécsényi, Katalin</creatorcontrib><title>Synthesis, characterization and thermal behavior of copper(II) complexes with pyridoxal thiosemi (PLTSC)- and S-methylisothiosemicarbazone (PLITSC)</title><title>Journal of thermal analysis and calorimetry</title><addtitle>J Therm Anal Calorim</addtitle><description>The syntheses of complexes of Cu(II) with biological active ligand, pyridoxal thiosemicarbazone (PLTSC) and its derivative, pyridoxal
S
-methylisothiosemicarbazone, are described. All coordination compounds were characterized by elemental analysis, molar conductivity and infrared spectra. The crystal and molecular structure of complexes [{Cu(μ-PLTSC)(H
2
O)}
2
](SO
4
)
2
·6H
2
O (
2
) and [{Cu(μ-PLTSC)(H
2
O)}
2
](SO
4
)
2
·2H
2
O (
2a
) is determined by single-crystal X-ray crystallography, too. The thermal decomposition of all the ligands and complexes was determined by simultaneous TG/DSC measurements. The decomposition mechanisms were compared and analyzed from the aspects of the relationships between the structures of the compounds and their thermal decomposition pattern.</description><subject>Analytical Chemistry</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Coordination compounds</subject><subject>Crystal structure</subject><subject>Derivatives</subject><subject>Inorganic Chemistry</subject><subject>Ligands</subject><subject>Measurement Science and Instrumentation</subject><subject>Molecular structure</subject><subject>Physical Chemistry</subject><subject>Polymer Sciences</subject><subject>Thermal decomposition</subject><subject>Thermal properties</subject><subject>X-rays</subject><issn>1388-6150</issn><issn>1588-2926</issn><issn>1572-8943</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNp9kc1u2zAQhIWiAeqmeYDceHSAMt3VH6ljYTSJAQMt4ORMUNQqoiGJCik3cV6jLxw6bq897WD3mwEWkySXCNcIIL4FhEpkHLDguayQiw_JAgspeVql5ceos6hLLOBT8jmEHQBUFeAi-bM9jHNHwYavzHTaazOTt696tm5kemxYPPpB96ymTv-2zjPXMuOmifxyvb6Kcph6eqHAnu3csengbeNeIj931gUaLFv-2txvV1f8PW3LB5q7Q2-D-wcY7Wv96kY6kusj-iU5a3Uf6OLvPE8ebn7cr-745uftevV9w02eypmXuRGSsGrSXBZ1m-fUGEwl5lWLhSACKSqEpm3bUgDUJu5lIYuMSKJGqLPzZHnKnbx72lOY1WCDob7XI7l9UChBgsiKMo8onlDjXQieWjV5O2h_UAjqWIA6FaBiAepYgBLRk548IbLjI3m1c3s_xo_-Y3oDSZmKMg</recordid><startdate>20160301</startdate><enddate>20160301</enddate><creator>Vojinović-Ješić, Ljiljana S.</creator><creator>Rodić, Marko V.</creator><creator>Barta Holló, Berta</creator><creator>Ivković, Sonja A.</creator><creator>Leovac, Vukadin M.</creator><creator>Mészáros Szécsényi, Katalin</creator><general>Springer Netherlands</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20160301</creationdate><title>Synthesis, characterization and thermal behavior of copper(II) complexes with pyridoxal thiosemi (PLTSC)- and S-methylisothiosemicarbazone (PLITSC)</title><author>Vojinović-Ješić, Ljiljana S. ; Rodić, Marko V. ; Barta Holló, Berta ; Ivković, Sonja A. ; Leovac, Vukadin M. ; Mészáros Szécsényi, Katalin</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c428t-64c78e19d2485bf44edc128149f157ee087910dfff6700bc49f85853ee81a10b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Analytical Chemistry</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Coordination compounds</topic><topic>Crystal structure</topic><topic>Derivatives</topic><topic>Inorganic Chemistry</topic><topic>Ligands</topic><topic>Measurement Science and Instrumentation</topic><topic>Molecular structure</topic><topic>Physical Chemistry</topic><topic>Polymer Sciences</topic><topic>Thermal decomposition</topic><topic>Thermal properties</topic><topic>X-rays</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Vojinović-Ješić, Ljiljana S.</creatorcontrib><creatorcontrib>Rodić, Marko V.</creatorcontrib><creatorcontrib>Barta Holló, Berta</creatorcontrib><creatorcontrib>Ivković, Sonja A.</creatorcontrib><creatorcontrib>Leovac, Vukadin M.</creatorcontrib><creatorcontrib>Mészáros Szécsényi, Katalin</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Journal of thermal analysis and calorimetry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Vojinović-Ješić, Ljiljana S.</au><au>Rodić, Marko V.</au><au>Barta Holló, Berta</au><au>Ivković, Sonja A.</au><au>Leovac, Vukadin M.</au><au>Mészáros Szécsényi, Katalin</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis, characterization and thermal behavior of copper(II) complexes with pyridoxal thiosemi (PLTSC)- and S-methylisothiosemicarbazone (PLITSC)</atitle><jtitle>Journal of thermal analysis and calorimetry</jtitle><stitle>J Therm Anal Calorim</stitle><date>2016-03-01</date><risdate>2016</risdate><volume>123</volume><issue>3</issue><spage>2069</spage><epage>2079</epage><pages>2069-2079</pages><issn>1388-6150</issn><eissn>1588-2926</eissn><eissn>1572-8943</eissn><abstract>The syntheses of complexes of Cu(II) with biological active ligand, pyridoxal thiosemicarbazone (PLTSC) and its derivative, pyridoxal
S
-methylisothiosemicarbazone, are described. All coordination compounds were characterized by elemental analysis, molar conductivity and infrared spectra. The crystal and molecular structure of complexes [{Cu(μ-PLTSC)(H
2
O)}
2
](SO
4
)
2
·6H
2
O (
2
) and [{Cu(μ-PLTSC)(H
2
O)}
2
](SO
4
)
2
·2H
2
O (
2a
) is determined by single-crystal X-ray crystallography, too. The thermal decomposition of all the ligands and complexes was determined by simultaneous TG/DSC measurements. The decomposition mechanisms were compared and analyzed from the aspects of the relationships between the structures of the compounds and their thermal decomposition pattern.</abstract><cop>Dordrecht</cop><pub>Springer Netherlands</pub><doi>10.1007/s10973-015-4891-7</doi><tpages>11</tpages></addata></record> |
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| language | eng |
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| subjects | Analytical Chemistry Chemistry Chemistry and Materials Science Coordination compounds Crystal structure Derivatives Inorganic Chemistry Ligands Measurement Science and Instrumentation Molecular structure Physical Chemistry Polymer Sciences Thermal decomposition Thermal properties X-rays |
| title | Synthesis, characterization and thermal behavior of copper(II) complexes with pyridoxal thiosemi (PLTSC)- and S-methylisothiosemicarbazone (PLITSC) |
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