Ethynide-stabilized high-nuclearity silver() sulfido molecular clusters assembled using organic sulfide precursors
Inexpensive 1,1′-thiocarbonyldiimidazole and di(2-pyridyl) thionocarbonate have been used as respective sulfide precursors to assemble unprecedented high-nuclearity ethynide-stabilized silver( i ) sulfido molecular clusters [Ag 9 S 6 @Ag 36 (C&z.tbd;C t Bu) 32 (H 2 O) 2 ] [Ag(imidazole)(CH 3 OH)...
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2016-01, Vol.52 (36), p.6119-6122 |
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| creator | Chen, Zi-Yi Tam, Dennis Y. S Mak, Thomas C. W |
| description | Inexpensive 1,1′-thiocarbonyldiimidazole and di(2-pyridyl) thionocarbonate have been used as respective sulfide precursors to assemble unprecedented high-nuclearity ethynide-stabilized silver(
i
) sulfido molecular clusters [Ag
9
S
6
@Ag
36
(C&z.tbd;C
t
Bu)
32
(H
2
O)
2
] [Ag(imidazole)(CH
3
OH)(H
2
O)](BF
4
)
2
·8H
2
O·2CH
3
OH (
1
) and [Ag
120
S
24
(PhC&z.tbd;C)
52
Cl
4
(2-pyridone)
10
(H
2
O)
8
](H
3
O)
4
(SiF
6
)
8
(BF
4
)
4
·CH
3
OH·22H
2
O (
2
), the latter being the largest isolated silver(
i
) ethynide cluster reported to date.
Two unprecedented molecular clusters bearing Ag
9
S
6
@Ag
36
and Ag
120
S
24
cores stabilized by surface ethynide ligands are assembled using novel organic sulfide precursors and structurally characterized by single-crystal X-ray analysis. The figure shows the Ag
120
S
24
(PhC&z.tbd;C)
52
core unit of the latter cluster. |
| doi_str_mv | 10.1039/c6cc02631a |
| format | Article |
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i
) sulfido molecular clusters [Ag
9
S
6
@Ag
36
(C&z.tbd;C
t
Bu)
32
(H
2
O)
2
] [Ag(imidazole)(CH
3
OH)(H
2
O)](BF
4
)
2
·8H
2
O·2CH
3
OH (
1
) and [Ag
120
S
24
(PhC&z.tbd;C)
52
Cl
4
(2-pyridone)
10
(H
2
O)
8
](H
3
O)
4
(SiF
6
)
8
(BF
4
)
4
·CH
3
OH·22H
2
O (
2
), the latter being the largest isolated silver(
i
) ethynide cluster reported to date.
Two unprecedented molecular clusters bearing Ag
9
S
6
@Ag
36
and Ag
120
S
24
cores stabilized by surface ethynide ligands are assembled using novel organic sulfide precursors and structurally characterized by single-crystal X-ray analysis. The figure shows the Ag
120
S
24
(PhC&z.tbd;C)
52
core unit of the latter cluster.</description><identifier>ISSN: 1359-7345</identifier><identifier>EISSN: 1364-548X</identifier><identifier>DOI: 10.1039/c6cc02631a</identifier><identifier>PMID: 27071972</identifier><language>eng</language><publisher>England</publisher><subject>Clusters ; Molecular clusters ; Precursors ; Sulfides</subject><ispartof>Chemical communications (Cambridge, England), 2016-01, Vol.52 (36), p.6119-6122</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c342t-7d72fe181772f0fd50db67a4b5cfb94c20fb3450211cb1b175a571773fbc8a973</citedby><cites>FETCH-LOGICAL-c342t-7d72fe181772f0fd50db67a4b5cfb94c20fb3450211cb1b175a571773fbc8a973</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/27071972$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Chen, Zi-Yi</creatorcontrib><creatorcontrib>Tam, Dennis Y. S</creatorcontrib><creatorcontrib>Mak, Thomas C. W</creatorcontrib><title>Ethynide-stabilized high-nuclearity silver() sulfido molecular clusters assembled using organic sulfide precursors</title><title>Chemical communications (Cambridge, England)</title><addtitle>Chem Commun (Camb)</addtitle><description>Inexpensive 1,1′-thiocarbonyldiimidazole and di(2-pyridyl) thionocarbonate have been used as respective sulfide precursors to assemble unprecedented high-nuclearity ethynide-stabilized silver(
i
) sulfido molecular clusters [Ag
9
S
6
@Ag
36
(C&z.tbd;C
t
Bu)
32
(H
2
O)
2
] [Ag(imidazole)(CH
3
OH)(H
2
O)](BF
4
)
2
·8H
2
O·2CH
3
OH (
1
) and [Ag
120
S
24
(PhC&z.tbd;C)
52
Cl
4
(2-pyridone)
10
(H
2
O)
8
](H
3
O)
4
(SiF
6
)
8
(BF
4
)
4
·CH
3
OH·22H
2
O (
2
), the latter being the largest isolated silver(
i
) ethynide cluster reported to date.
Two unprecedented molecular clusters bearing Ag
9
S
6
@Ag
36
and Ag
120
S
24
cores stabilized by surface ethynide ligands are assembled using novel organic sulfide precursors and structurally characterized by single-crystal X-ray analysis. The figure shows the Ag
120
S
24
(PhC&z.tbd;C)
52
core unit of the latter cluster.</description><subject>Clusters</subject><subject>Molecular clusters</subject><subject>Precursors</subject><subject>Sulfides</subject><issn>1359-7345</issn><issn>1364-548X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNqNkc9LwzAUx4Mobk4v3pUcp1BN2rRpj6PMHzDwouCtJGmyRdJ25rXC_OvN3NSr7_J98D7fB-99ETqn5IaSpLhVmVIkzhIqDtCYJhmLUpa_Hm77tIh4wtIROgF4I6Fomh-jUcwJpwWPx8jP-9WmtbWOoBfSOvupa7yyy1XUDspp4W2_wWDdh_bTKwyDM7bucNM5rQYnPFZugF57wAJAN9IF9wC2XeLOL0Vr1d6i8doHh4fOwyk6MsKBPtvrBL3czZ_Lh2jxdP9YzhaRSljcR7zmsdE0pzwoMXVKaplxwWSqjCyYiomR4TQSU6oklZSnIuUBToxUuSh4MkHT3d61794HDX3VWFDaOdHqboCK5iQnnBT8HyjPGWdFeFpAr3eo8h2A16Zae9sIv6koqbZxVGVWlt9xzAJ8ud87yEbXv-jP_wNwsQM8qN_pX57JF9IakRg</recordid><startdate>20160101</startdate><enddate>20160101</enddate><creator>Chen, Zi-Yi</creator><creator>Tam, Dennis Y. S</creator><creator>Mak, Thomas C. W</creator><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20160101</creationdate><title>Ethynide-stabilized high-nuclearity silver() sulfido molecular clusters assembled using organic sulfide precursors</title><author>Chen, Zi-Yi ; Tam, Dennis Y. S ; Mak, Thomas C. W</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c342t-7d72fe181772f0fd50db67a4b5cfb94c20fb3450211cb1b175a571773fbc8a973</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Clusters</topic><topic>Molecular clusters</topic><topic>Precursors</topic><topic>Sulfides</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Chen, Zi-Yi</creatorcontrib><creatorcontrib>Tam, Dennis Y. S</creatorcontrib><creatorcontrib>Mak, Thomas C. W</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Chemical communications (Cambridge, England)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Chen, Zi-Yi</au><au>Tam, Dennis Y. S</au><au>Mak, Thomas C. W</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Ethynide-stabilized high-nuclearity silver() sulfido molecular clusters assembled using organic sulfide precursors</atitle><jtitle>Chemical communications (Cambridge, England)</jtitle><addtitle>Chem Commun (Camb)</addtitle><date>2016-01-01</date><risdate>2016</risdate><volume>52</volume><issue>36</issue><spage>6119</spage><epage>6122</epage><pages>6119-6122</pages><issn>1359-7345</issn><eissn>1364-548X</eissn><abstract>Inexpensive 1,1′-thiocarbonyldiimidazole and di(2-pyridyl) thionocarbonate have been used as respective sulfide precursors to assemble unprecedented high-nuclearity ethynide-stabilized silver(
i
) sulfido molecular clusters [Ag
9
S
6
@Ag
36
(C&z.tbd;C
t
Bu)
32
(H
2
O)
2
] [Ag(imidazole)(CH
3
OH)(H
2
O)](BF
4
)
2
·8H
2
O·2CH
3
OH (
1
) and [Ag
120
S
24
(PhC&z.tbd;C)
52
Cl
4
(2-pyridone)
10
(H
2
O)
8
](H
3
O)
4
(SiF
6
)
8
(BF
4
)
4
·CH
3
OH·22H
2
O (
2
), the latter being the largest isolated silver(
i
) ethynide cluster reported to date.
Two unprecedented molecular clusters bearing Ag
9
S
6
@Ag
36
and Ag
120
S
24
cores stabilized by surface ethynide ligands are assembled using novel organic sulfide precursors and structurally characterized by single-crystal X-ray analysis. The figure shows the Ag
120
S
24
(PhC&z.tbd;C)
52
core unit of the latter cluster.</abstract><cop>England</cop><pmid>27071972</pmid><doi>10.1039/c6cc02631a</doi><tpages>4</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1359-7345 |
| ispartof | Chemical communications (Cambridge, England), 2016-01, Vol.52 (36), p.6119-6122 |
| issn | 1359-7345 1364-548X |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1808070977 |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Clusters Molecular clusters Precursors Sulfides |
| title | Ethynide-stabilized high-nuclearity silver() sulfido molecular clusters assembled using organic sulfide precursors |
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